Particle and aerosol research (한국입자에어로졸학회지)

Korean Association for Particle and Aerosol Research (한국입자에어로졸학회)
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Carbonic Anhydrase Mimicry for Carbon Dioxide Fixation and Calcium Carbonate Mineralization

탄산탈수효소 모사를 이용한 이산화탄소 고정화 및 탄산칼슘 합성

  • Sahoo, Prakash C. (CO2 sequestration research department, Korea Institute of Geosciences and Mineral Resources) ;
  • Jang, Young Nam (CO2 sequestration research department, Korea Institute of Geosciences and Mineral Resources) ;
  • Chae, Soo Chun (CO2 sequestration research department, Korea Institute of Geosciences and Mineral Resources) ;
  • Lee, Seung Woo (CO2 sequestration research department, Korea Institute of Geosciences and Mineral Resources)
  • 프라카쉬 챈드라 사후 (한국지질자원연구원 지구환경연구본부 CO2 처분연구실) ;
  • 장영남 (한국지질자원연구원 지구환경연구본부 CO2 처분연구실) ;
  • 채수천 (한국지질자원연구원 지구환경연구본부 CO2 처분연구실) ;
  • 이승우 (한국지질자원연구원 지구환경연구본부 CO2 처분연구실)
  • Received : 2013.10.31
  • Accepted : 2013.12.16
  • Published : 2013.12.30
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Abstract

Copper (II) and Nickel (II) mimic complexes of enzyme carbonic anhydrase were evaluated under ambient condition for carbon dioxide capture and conversion process. The synthesized complexes were characterized by ATR-FTIR and UV-DR spectroscopy. It was found that all the complexes have biomimetic activity towards $CO_2$ using para-nitrophenyl acetate (p-NPA) hydrolysis as the model reaction. Interestingly, the proper geometry obtained by the restricted orientation of tripodal N atoms in Cu (II) complex of 2,6-bis(2-benzimidazolyl) pyridine showed the highest activity (1.14 au) compared to others. The $CO_2$ bio-mineralization to $CaCO_3$ was carried out via in-vitro crystallization approach. Results indicate that the biomimetic complexes have a role in determining $CaCO_3$ morphology. The present observations establish a qualitative insight for the design of improved small-molecule catalysts for carbon capture.

Keywords

References

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