Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis, Crystal Structures and Properties of Two Binuclear Supramolecular Complexes Based on Biphenyl-2,2'-dicarboxylic Acid Ligand

  • Tang, Jin-Niu (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities) ;
  • Pan, Gang-Hong (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities) ;
  • Li, Long (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities) ;
  • Tian, Wei-Man (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities) ;
  • Huang, Zhong-Jing (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
  • Received : 2012.10.17
  • Accepted : 2012.11.03
  • Published : 2013.02.20
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Abstract

Two novel binuclear metal-organic coordination complexes [$Cd_2(Hdpa)_4(bpy)_2$] (1), [$Dy_2(dpa)_2(bpy)_2(NO_3)_2-(H_2O)_2$](bpy) (2) (where $H_2dpa$ = biphenyl-2,2'-dicarboxylic acid, bpy = 2,2'-bipyridine) have been synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction, spectral method (IR), elemental analysis (EA), powder X-ray diffraction (XRD), electronic spectra (UV-vis), fluorescent in the solid state and thermogravimetric analysis (TGA). Complexes 1-2 crystallizes isomorphously in the Triclinic space group P-1. The ${\pi}-{\pi}$ stacking interactions and hydrogen-bonds play a vital role in determining the crystal packing and construction of the extended 3-D supramolecular network.

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References

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