DOI QR코드

DOI QR Code

활성탄 충진 3D 복극전기분해조를 이용한 ETA 처리

Treatment of ETA wastewater using GAC as particle electrodes in three-dimensional electrode reactor

  • 김란 (한양대학교 건설환경공학과) ;
  • 김유진 (한양대학교 건설환경공학과) ;
  • 신자원 (한양대학교 건설환경공학과) ;
  • 김정주 (한양대학교 건설환경공학과) ;
  • 박주양 (한양대학교 건설환경공학과)
  • 투고 : 2013.01.17
  • 심사 : 2013.04.12
  • 발행 : 2013.04.15

초록

Ethanolamine (ETA) is widely used for alkalinization of water in steam cycles of nuclear power plants with pressurized water reactor. When ETA contained wastewater was released, it could increase COD and T-N. The treatment of the COD and T-N from ETA wastewater was investigated using the GAC as particle electrodes in three-dimensional electrode reactor (TDE). This study evaluated the effectiveness of GAC as particle electrode using different packing ratio at 300 V. The results showed that GAC-TDE could reduce ETA much more efficiently than ZVI-TDE at the mass ratio of GAC to insulator, 1:2. Additionally, The effect of applied electric potential to COD and T-N reduction was investigated. The results showed the high COD, T-N reduction and current efficiency at the low electric potential. Using the GAC-TDE will provide a better ETA reduction with reducing electrical potential dissipation.

키워드

참고문헌

  1. Ahmad , A.A. and Hameed, B.H. (2009) Reduction of COD and color of dyeing effluent from a cotton textile mill by adsorption onto bamboo-based activated carbon, Journal of Hazardous Materials, 172(2-3), pp.1538-1543. https://doi.org/10.1016/j.jhazmat.2009.08.025
  2. Ban, A ., Schafer, A. and Wendt, H. (1998) Fundamentals of electrosorption on activated carbon for wastewater treatment of industrial effluents, Journal of Applied Electrochemistry, 28(3), pp.227-236. https://doi.org/10.1023/A:1003247229049
  3. Bandosz T. J. (2006) Activated carbon surfaces in environmental remediation, pp. 169-178, Elsevier, New York.
  4. Benezeth, P., Wesolowski, D.J., Palmer, D.A. and MacHesky, M.L. (2009) Effect of amines on the surface charge properties of iron oxides, Journal of Solution Chemistry, 38(7), pp.925-945. https://doi.org/10.1007/s10953-009-9419-y
  5. Chi, S. and Rochelle, G.T. (2002) Oxidative Degradation of Monoethanolamine, Industrial & Engineering Chemistry Research, 41(17), pp.4178-4186. https://doi.org/10.1021/ie010697c
  6. Comninellis, C. and Nerini, A. (1995) Anodic oxidation of phenol in the presence of NaCl for wastewater treatment, Journal of Applied Electrochemistry, 25(1), pp.23-28.
  7. Foo, K .Y. and Hameed, B.H. (2009) A short review of activated carbon assisted electrosorption process: An overview, current stage and future prospects, Journal of Hazardous Materials, 170(2-3), pp.552-559. https://doi.org/10.1016/j.jhazmat.2009.05.057
  8. Francis, R (2012) Utilization of Nitrogen from Surface and Subsurface Applied Wastewater, Master's Thesis, Texas Tech University.
  9. Frackowiak, E. and Beguin, F. (2001) Carbon materials for the electrochemical storage of energy in capacitors, Carbon, 39(6), pp.937-950. https://doi.org/10.1016/S0008-6223(00)00183-4
  10. Harimurti, S., Dutta, B.K., Ariff, I.F.B.M., Chakrabarti, S. and Vione, D. (2010) Degradation of monoethanolamine in aqueous Solution by Fenton's reagent with Biological post-treatment, Water, Air, and Soil Pollution, 211(1-4), pp.273-286. https://doi.org/10.1007/s11270-009-0298-z
  11. Hawthorne, S.B., Kubatova, A., Gallagher, J.R., Sorensen, J.A. and Miller, D.J. (2005) Persistence and Biodegradation of Monoethanolamine and 2-Propanolamine at an Abandoned Industrial Site, Environmental Science & Technology, 39(10), pp.3639-3645. https://doi.org/10.1021/es040556c
  12. Jeong, J.-Y., Kim, H.-K., Kim, J.-H. and Park, J.-Y. (2012) Electrochemical removal of nitrate using ZVI packed bed bipolar electrolytic cell, Chemosphere, 89(2), pp.172-178. https://doi.org/10.1016/j.chemosphere.2012.05.104
  13. Kim, D .-J., Lim, Y., Cho, D. and Rhee, I. (2010) Biodegradation of monoethanolamine in aerobic and anoxic conditions, Korean Journal of Chemical Engineering, 27(5), pp.1521-1526. https://doi.org/10.1007/s11814-010-0285-5
  14. Kim, H ., Kusakabe, K., Hokazono, S., Morooka, S. and Kato, Y. (1987) Electro-oxidation rate ofp-tert-butyltoluene in a bipolar packed-bed electrode cell, Journal of Applied Electrochemistry, 17(6), pp.1213-1222. https://doi.org/10.1007/BF01023605
  15. Kong, W., Wang, B., Ma, H. and Gu, L. (2006) Electrochemical treatment of anionic surfactants in synthetic wastewater with three-dimensional electrodes, Journal of Hazardous Materials, 137(3), pp.1532-1537. https://doi.org/10.1016/j.jhazmat.2006.04.037
  16. Mrklas , O., Lunn, S. R. D. and Chu, A. (2001) Laboratory investigations of aerobic and anaerobic monoethanolamine biodegradation studies, Journal of Environmental Monitor, 5, pp.336-340.
  17. Monda l, P., Balomajumder, C. and Mohanty, B. (2007) A laboratory study for the treatment of arsenic, iron, and manganese bearing ground water using $Fe^{3+}$ impregnated activated carbon: Effects of shaking time, pH and temperature, Journal of Hazardous Materials, 144(1-2), pp.420-426. https://doi.org/10.1016/j.jhazmat.2006.10.078
  18. Nagesw ara Rao, N., Rohit, M., Nitin, G., Parameswaran, P.N. and Astik, J.K. (2009) Kinetics of electrooxidation of landfill leachate in a three-dimensional carbon bed electrochemical reactor, Chemosphere, 76(9), pp.1206-1212. https://doi.org/10.1016/j.chemosphere.2009.06.009
  19. Ndegw a, A.W., Wong, R.C.K., Chu, A., Bentley, L.R. and Lunn, S.R.D. (2004) Degradation of monoethanolamine in soil, Journal of Environmental Engineering and Science. 3(2), pp.137-145. https://doi.org/10.1139/s03-074
  20. Niedbal , J., Budniok, A. and Matyja, P. (1994) Electro-oxidation of ethanolamine on modified layers of Cu-Ni alloys in alkaline environment, Thin Solid Films, 237(1-2), pp.148-154. https://doi.org/10.1016/0040-6090(94)90252-6
  21. Obreja , V.V.N. (2008) On the performance of supercapacitors with electrodes based on carbon nanotubes and carbon activated material-A review, Physica E: Low-dimensional Systems and Nanostructures, 40(7), pp.2596-2605. https://doi.org/10.1016/j.physe.2007.09.044
  22. Puttaswamy, Vaz, N. and Made Gowda, N.M. (2001) Oxidation of ethanolamines by sodium N-bromobenzenesulfonamide in alkaline buffer medium: A kinetic and mechanistic study, International Journal of Chemical Kinetics, 33(8), pp.480-490. https://doi.org/10.1002/kin.1045
  23. Qu, D. and Shi, H. (1998) Studies of activated carbons used in double-layer capacitors, Journal of Power Sources, 74(1), pp.99-107. https://doi.org/10.1016/S0378-7753(98)00038-X
  24. Racz, L ., Datta, T. and Goel, R. (2010) Effect of organic carbon on ammonia oxidizing bacteria in a mixed culture. Bioresource Technology, 101(16), pp.6454-6460. https://doi.org/10.1016/j.biortech.2010.03.058
  25. Raught D. P., Foutch. G. L. and Apblett. A. (2005) Ion exchange resin fouling by organic amines in secondary systems at U.S. nuclear power plants, Power Plant Chemistry, 7(12), pp.741-747.
  26. Van Hege, K., Verhaege, M. and Verstraete, W. (2004) Electro-oxidative abatement of low-salinity reverse osmosis membrane concentrates, Water Research, 38(6), pp.1550-1558. https://doi.org/10.1016/j.watres.2003.12.023
  27. Wang, L., Fu, J., Qiao, Q. and Zhao, Y. (2007) Kinetic modeling of electrochemical degradation of phenol in a three-dimension electrode process, Journal of Hazardous Materials, 144(1-2), pp.118-125. https://doi.org/10.1016/j.jhazmat.2006.09.091
  28. Xiong, Y., Strunk, P.J., Xia, H., Zhu, X. and Karlsson, H.T. (2001) Treatment of dye wastewater containing acid orange II using a cell with three-phase three-dimensional electrode, Water Research, 35(17), pp.4226-4230. https://doi.org/10.1016/S0043-1354(01)00147-6
  29. Xiong, Y. and Karlsson, H.T. (2002) An experimental investigation of chemical oxygen demand removal from the wastewater containing oxalic acid using three-phase three-dimensional electrode reactor, Advances in Environmental Research, 7(1), pp.139-145. https://doi.org/10.1016/S1093-0191(01)00124-1
  30. Xiong, Y., He, C., Karlsson, H.T. and Zhu, X. (2003) Performance of three-phase threedimensional electrode reactor for the reduction of COD in simulated wastewatercontaining phenol, Chemosphere, 50(1), pp.131-136. https://doi.org/10.1016/S0045-6535(02)00609-4
  31. Xu, L. , Zhao, H., Shi, S., Zhang, G. and Ni, J. (2008) Electrolytic treatment of C.I. Acid Orange 7 in aqueous solution using a three-dimensional electrode reactor, Dyes and Pigments, 77(1), pp.158-164. https://doi.org/10.1016/j.dyepig.2007.04.004
  32. Yeon, K.-H., Song, J.-H., Shim, J., Moon, S.-H., Jeong, Y.-U. and Joo, H.-Y. (2007) Integrating electrochemical processes with electrodialysis reversal and electro-oxidation to minimize COD and T-N at wastewater treatment facilities of power plants, Desalination, 202(1-3), pp.400-410. https://doi.org/10.1016/j.desal.2005.12.080
  33. Zhu, X ., Ni, J., Xing, X., Li, H. and Jiang, Y. (2011) Synergies between electrochemical oxidation and activated carbon adsorption in three-dimensional boron-doped diamond anode system, Electrochimica Acta, 56(3), pp.1270-1274. https://doi.org/10.1016/j.electacta.2010.10.073

피인용 문헌

  1. Synergy optimization for the removal of dye and pesticides from drinking water using granular activated carbon particles in a 3D electrochemical reactor vol.27, pp.18, 2020, https://doi.org/10.1007/s11356-020-08022-w