DOI QR코드

DOI QR Code

A study of plastic plateau disappearance in stress-strain curve of annealed polypropylene films during stretching

  • Lei, Caihong (School of Materials and Energy, Guangdong University of Technology) ;
  • Wu, Shuqiu (School of Materials and Energy, Guangdong University of Technology) ;
  • Xu, Ruijie (School of Materials and Energy, Guangdong University of Technology) ;
  • Xu, Yunqi (School of Materials and Energy, Guangdong University of Technology) ;
  • Peng, Xinlong (School of Materials and Energy, Guangdong University of Technology)
  • 투고 : 2012.06.21
  • 심사 : 2013.04.08
  • 발행 : 2013.06.25

초록

The changes of plastic plateau in the stress-strain curves of annealed polypropylene (PP) films during stretching under room temperature were followed and the corresponding melting properties and microstructure were characterized by differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). It was found that during stretching the plastic plateau disappeared progressively with the increase of drawing ratio. At the same time, the endotherm plateau in DSC curves also disappeared progressively. The presence of the plastic plateau was attributed to the stretching of unstable crystalline part which was formed by tie chains around initial row-nucleated lamellae structure during annealing. During stretching, the unstable part was stretched and converted to bridges connecting separated lamellae. There was direct relationship between the disappearance of plastic plateau and pore formation.

키워드

과제정보

연구 과제 주관 기관 : National Science Foundation of China

참고문헌

  1. Feng, Z, Keum, J.K. and Chen, X.M. (2007), "The role of interlamellar chain entanglement in deformation-induced structure changes during uniaxial stretching of isotactic polypropylene", Polym. J.,48(27), 6867-6880. https://doi.org/10.1016/j.polymer.2007.08.065
  2. Lei, C.H., Huang, W.L., Xu, R.J. and Xu, Y.Q. (2012), "The correlation between the lower temperature melting plateau endotherm and the stretching-induced pore formation in annealed polypropylene films", J. Plast Film Sheet., 28(2), 151-164. https://doi.org/10.1177/8756087911434186
  3. Nitta, K.H. and Takayanagi, M. (2000), "Tensile yield of isotactic polypropylene in terms of a lamellar-cluster model", J. Polym. Sci. Part B: Polym. Phys., 38(8), 1037-1044. https://doi.org/10.1002/(SICI)1099-0488(20000415)38:8<1037::AID-POLB4>3.0.CO;2-R
  4. Noether, H.D. and Hay, I.L. (1978), "Small-angle X-ray diffraction studies and morphology of microporous materials and their 'hard' elastic precursors", J. Appl. Cryst., 11, 546-547. https://doi.org/10.1107/S0021889878013849
  5. Rastogi, S., Lippits, D.R., Peters, G.W.M., Graf, R., Yao, Y. and Spiess, H.W. (2005), "Heterogeneity in polymer melts from melting of polymer crystals", Nat. Mater., 4, 635- 641. https://doi.org/10.1038/nmat1437
  6. Sadeghi, F., Ajji, A. and Carreau, P.J. (2007a), "Analysis of microporous membranes obtained from polypropylene films by stretching", J. Membr. Sci., 292(1-2), 62-71. https://doi.org/10.1016/j.memsci.2007.01.023
  7. Sadeghi, F., Ajji, A. and Carreau, P.J. (2007b), "Analysis of row nucleated lamellar structure of polypropylene obtained from cast film: Effect of melt rheology and process conditions", Polym. Eng. Sci., 47(7), 1170-1178. https://doi.org/10.1002/pen.20837
  8. Tabatabaei, S.H., Carreau, P.J. and Ajji, A. (2009), "Effect of processing on the crystalline orientation morphology and mechanical properties of polypropylene cast films and microporous membrane formation", Polym. J., 50(17), 4228-4240. https://doi.org/10.1016/j.polymer.2009.06.071

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