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Korean Chemical Society (대한화학회)
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An Efficient Synthesis of Phospha-Morita-Baylis-Hillman Adducts via Michaelis-Arbuzov Reaction of the DABCO Salt of Morita-Baylis-Hillman Bromide

  • Kim, Sung Hwan (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Kim, Se Hee (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Lee, Hyun Seung (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Kim, Jae Nyoung (Department of Chemistry and Institute of Basic Science, Chonnam National University)
  • Received : 2012.10.03
  • Accepted : 2012.10.19
  • Published : 2013.01.20
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Abstract

An efficient synthesis of phospha-Morita-Baylis-Hillman adducts was carried out in good yields via the Michaelis-Arbuzov reaction of the DABCO salts of MBH bromides. Instead of a DABCO salt, a phosphonium salt could be effectively used for some substrates which showed some problems in the presence of DABCO.

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References

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