Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis, Optical and Electrical Studies of Nonlinear Optical Crystal: L-Arginine Semi-oxalate

  • Vasudevan, P. (Department of Physics, MIT Campus, Anna University) ;
  • Sankar, S. (Department of Physics, MIT Campus, Anna University) ;
  • Jayaraman, D. (Department of Physics, Presidency college)
  • Received : 2012.09.06
  • Accepted : 2012.10.17
  • Published : 2013.01.20
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Abstract

L-Arginine semi-oxalate (LASO) single crystal has been grown by solution growth technique at room temperature. The crystal structure and lattice parameters were determined for the grown crystal by single crystal X-ray diffraction studies. Photoluminescence studies confirm the violet fluorescence emission peak at 395 nm. Optical constants like band gap, refractive index, reflectance, extinction coefficient and electric susceptibility were determined from UV-VIS-NIR spectrum. The dielectric constant, dielectric loss and ac conductivity of the compound were calculated at different temperatures and frequencies to analyze the electrical properties. The solid state parameters such as plasma energy, Penn gap, Fermi energy and polarizability were calculated to analyze second harmonic generation (SHG). Nonlinear optical property was discussed to confirm the SHG efficiency of the grown crystal.

Keywords

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