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Trace elements in the rainwater runoff of the urban catchment of Guwahati, India

  • Devi, Upama (Department of Chemistry, Gauhati University) ;
  • Bhattacharyya, Krishna G. (Department of Chemistry, Gauhati University)
  • Received : 2012.10.23
  • Accepted : 2013.03.15
  • Published : 2013.06.25

Abstract

Rainwater runoff has been identified as a significant source of contaminants having tremendous impact on the receiving aquatic environment. In the present study, trace element transport by the surface runoff in the predominantly urban catchment of Guwahati city, India was monitored with a view to determine the chemical denudation rates of the land surface. A number of trace metals, namely Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn were measured in the runoff after 70 major rain events within the city. Cadmium was found to be the least abundant metal and Iron was the most abundant metal in the runoff. The results are interpreted on the basis of temporal and spatial variations in their concentrations. These variations are quite large in some of the events and reflect changes in the local environmental setting, differences in water utilization, variations in runoff volume, gradient and quality.

Keywords

References

  1. Adriano, D.C. (1989), Trace Elements in the Terrestrial Environment, (2nd Edition), Springer-Verlag, New York.
  2. APHA (1995), American Public Health Association, Standard Methods for the Examination of Water and Wastewater, (19th Edition), Washington, D.C.
  3. Avudainayagam, S., Megharaj, M., Owens, G., Kookana, R.S., Cittleborough, D. and Naidu, R. (2003), "Chemistry of chromium in soils with emphasis on tannery waste sites", Rev. Environ. Contaminat. Toxicol., 178, 53-91.
  4. Brown, G.H., Sharp, M. and Tranter, M. (1996), "Experimental investigations of the weathering of suspended sediment by Alpine glacier meltware", Hydrol. Process., 10, 579-597. https://doi.org/10.1002/(SICI)1099-1085(199604)10:4<579::AID-HYP393>3.0.CO;2-D
  5. Cezary, K. and Singh B.R. (2001), "Fractionation and mobility of copper, lead, and zinc in soil profiles in the vicinity of a copper smelter", J. Environ. Qual., 30(2), 485-492. https://doi.org/10.2134/jeq2001.302485x
  6. Charlson, R.J. and Rodhe, R. (1982), "Factors controlling the acidity of natural rainwater", Nature, 295, 683-685. https://doi.org/10.1038/295683a0
  7. Dasch, J.M. and Wolff, G.T. (1989), "Trace inorganic species in precipitation and their potential use in source apportionment studies", Water, Air, Soil Pollut., 43(3-4), 401-412.
  8. Davis, B. and Birch, G. (2010), "Comparison of heavy metal loads in stormwater runoff from major and minor urban roads using pollutant yield rating curves", Environ. Pollut., 158(8), 2541- 2545. https://doi.org/10.1016/j.envpol.2010.05.021
  9. Davis, A.P. and Shokouhian, M. (2001), "Loading estimates of lead, copper, cadmium, and zinc in urban runoff from specific sources", Chemosphere, 44(5), 997-1009. https://doi.org/10.1016/S0045-6535(00)00561-0
  10. Davis, B. and Birch, G. (2010), "Comparison of heavy metal loads in stormwater runoff from major and minor urban roads using pollutant yield rating curves", Environ. Pollut., 158, 2541- 2545. https://doi.org/10.1016/j.envpol.2010.05.021
  11. Dorchin, A. and Shanas, U. (2010), "Assessment of pollution in road runoff using a Bufo viridis biological assay", Environ. Pollut., 158, 3626-3633. https://doi.org/10.1016/j.envpol.2010.08.004
  12. Edwards, A.C. and Withers, P.J.A. (2008), "Transport and delivery of suspended solids, nitrogen and phosphorus from various sources to freshwaters in the UK", J. Hydrol., 350(3-4), 144-153. https://doi.org/10.1016/j.jhydrol.2007.10.053
  13. Facchinelli, A., Sacchi, E. and Mallen, L. (2001), "Multivariate statistical and GIS-based approach to identify heavy metal sources in soils", Environ. Pollut., 114(3), 313-324. https://doi.org/10.1016/S0269-7491(00)00243-8
  14. Farm, C. (2002), "Metal sorption to natural filter substrates for storm water treatment-column studies", Sci. Total Environ., 298(1-3), 17-24. https://doi.org/10.1016/S0048-9697(02)00142-0
  15. Forstner, U. and Wittmann, G. (1979), Metal Pollution in the Aquatic Environment, (2nd Revised Edition), Springer-Verlag Berlin, Heidelberg et New York, 486.
  16. Gikas, G.D. and Tsihrintzis, V.A. (2012), "Assessment of water quality of first-flush roof runoff and harvested rainwater", J. Hydrol., 466-467(12), 115-126. https://doi.org/10.1016/j.jhydrol.2012.08.020
  17. GMDA (2007), "Master plan for Guwahati Metropolitan Area-2025 (Draft)", Document: 20003139/UP/DFR/RI/
  18. Hesterberg, D., Bril, J. and Castilho, P.D. (1993), "Thermodynamic modelling of zinc, cadmium, and copper solubilities in manured acidic loamy-sand topsoil", J. Environ Qual, 22(4), 681-688.
  19. Hewitt, C.N. and Rashed, M.B. (1990), "An integrated budget for selected pollutants for a major rural highway", Sci. Total Environ., 93, 375-384. https://doi.org/10.1016/0048-9697(90)90128-H
  20. Johnson, J., Schewel, L. and Graedel, T.E. (2006), "The contemporary anthropogenic chromium cycle", Environ. Sci. Technol., 40(22), 7060-7069. https://doi.org/10.1021/es060061i
  21. Koljonen, T., Lahermo, P. and Garlson, L. (1976), "Origin mineralogy and geochemistry of manganese rocks and ferruginous precipitates found in sand gravel deposits in Finland", Bull. Geol. Soc., 48, 111-135.
  22. Lee, H., Lau, S.L., Kayhanian, M. and Stenstrom, M.K. (2004), "Seasonal first flush phenomenon of urban storm water discharges", Water Res., 38(19), 4153-4163. https://doi.org/10.1016/j.watres.2004.07.012
  23. Lind, C., Hem, J, and Roberson, C. (1987), "Reaction products of manganese-bearing waters", Chem. Qual. Water Hydrol. Cycle, 272-301.
  24. Longhurst, R.D., Roberts, A.H.C. and Waller, J.E. (2004), "Concentrations of arsenic, cadmium, copper, lead and zinc in New Zealand pastoral topsoils and herbage", New Zealand J. Agr. Res., 47(1), 23-32. https://doi.org/10.1080/00288233.2004.9513567
  25. McDowell, R.W. (2010), "Is cadmium loss in surface runoff significant for soil and surface water quality: A study of flood-irrigated pastures?", Water Air Soil Pollut., 209(1-4), 133-142. https://doi.org/10.1007/s11270-009-0186-6
  26. Melidis, P., Akratos, C., Tsihrintzis, V.A. and Trikoilidou, E. (2007), "Characterization of rain and roof drainage water quality in Xanthi, Greece", Environ. Monit. Assess., 127(1-3), 15-27. https://doi.org/10.1007/s10661-006-9254-1
  27. Mermut, A.R., Jain, J.C., Song, L., Kerrich, R., Kozak, L. and Jana, S. (1996), "Trace element concentration of selected soils and fertilizers in Saskatchewan, Canada", J. Environ. Qual., 25(4), 845-853
  28. Mitchell, A., Brown, G.H. and Fuge, R. (2001), "Minor and trace elements export from a glacierised Alpine headwater catchment, Haut Glacier d' Arolla, Switzerland", Hydrol. Process., 15(18), 3499-3524. https://doi.org/10.1002/hyp.1041
  29. Moore, J.W. (1991), Inorganic contaminants of surface water, Research and Monitoring Priorities, Springer-Verlag, New York, 98-108.
  30. Mugica, V. and Maubert, M. (2002), "Temporal and spatial variations of metal content in TSP and PM10 in Mexico City during 1996-1998", J. Aerosol Sci., 33(1), 91-102. https://doi.org/10.1016/S0021-8502(01)00151-3
  31. Nagpal, N.K. (2004), "Technical report - Water Quality Guidelines for Cobalt".
  32. Pellerin, C. and Booker, S.M. (2000), "Reflections on hexavalent chromium: Health hazards of an industrial heavyweight", Environ. Health Perspect., 108(9), 402-407. https://doi.org/10.1289/ehp.108-a402
  33. Poulton, S.W. and Raiswell, R. (2005), "Chemical and physical characteristics of iron oxides in riverine and glacier meltware sediments", Chem. Geol., 218(3-4), 203-221. https://doi.org/10.1016/j.chemgeo.2005.01.007
  34. Prendez, M. and Carrasco, M.A. (2003), "Elemental composition of surface waters in the Antarctic Peninsula and interactions with the environment", Environ. Geochem. Health, 25(3), 347-363. https://doi.org/10.1023/A:1024559809076
  35. Ramesh, R. and Anbu, M. (1996), Chemical Methods for Environmental Analysis - Water Sediment, Macmillan Publishers, London, 33-36.
  36. Sedlak, D.L., Phinney, J.N. and Bedsworth, W. (1997), "Strongly complexed Cu and Ni in wastewater effluents and surface runoff", Environ. Sci. Technol., 31(10), 3010-3016. https://doi.org/10.1021/es970271i
  37. Sharp, M., Tranter, M., Brown, G.H. and Skidmore, M. (1995), "Rates of chemical denudation and $CO_2$ drawdown in a glacier-covered alpine catchment", Geology, 23(1), 61-64. https://doi.org/10.1130/0091-7613(1995)023<0061:ROCDAC>2.3.CO;2
  38. Skidmore, M., Sharp, M. and Tranter, M. (2004), "Kinetic isotopic fractionation during carbonate dissolution in laboratory experiments: Implications for detection of microbial $CO_2$ signatures using d13C-DIC", Geochimica Cosmochimica Acta, 68(21), 4309-4317. https://doi.org/10.1016/j.gca.2003.09.024
  39. Tebbutt, T.H.Y. (1983), "Relation between natural water quality and health", Paris, UNESICO.
  40. Tranter, M., Sharp, M.J., Lamb, H.R., Brown, G.H., Hubbard, B.P. and Willis, I.C. (2002), "Geochemical weathering at the bed of Haut Glacier d' Arolla, Switzerland", Hydrol. Process., 16(5), 959-993. https://doi.org/10.1002/hyp.309
  41. Turer, D., Maynard, J.B. and Sansalone, J.J. (2001), "Heavy metal concentration in soils of urban highways: Comparison between runoff and soil concentrations at Cincinnati, Ohio", Water Air Soil Pollut., 132, 293-314. https://doi.org/10.1023/A:1013290130089
  42. Tsihrintzis, V.A. and Hamid, R. (1997), "Modelling and management of urban stormwater runoff quality: A review", Water Resour. Manag., 11(2), 137-164.
  43. Vijayaraghavan, K., Joshi, U.M. and Balasubramanian, R. (2012), "A field study to evaluate runoff quality from green roofs", Water Res., 46(4), 1337-1345. https://doi.org/10.1016/j.watres.2011.12.050
  44. Violante, A., Cozzolino, V., Perelomov, L., Caporale, A.G. and Pigna1, M. (2010), "Mobility and bioavailability of heavy metals and metalloids in soil environments", J. Soil Sci. Plant Nutr., 10(3), 268-292.
  45. Vuori, K.M. (1995), "Direct and indirect effects of iron on river ecosystem", Ann. Zool. Fennici, 32, 317-329.
  46. Zhao, H., Li, X., Wang, X. and Tian, D. (2010), "Grain size distribution of road-deposited sediment and its contribution to heavy metal pollution in urban runoff in Beijing, China", J. Hazard. Mater., 183(1-3), 203-210. https://doi.org/10.1016/j.jhazmat.2010.07.012

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