Fashion & Textile Research Journal (한국의류산업학회지)

The Society of Fashion and Textile Industry (한국의류산업학회)
권호 표지
DOI QR코드

DOI QR Code

The Effects of Annealing Temperature on The Physical Properties and Fine Structure of Poly(trimethylene terephthalate)(PTT) Fibers

열처리 온도가 Poly(trimethylene terephthalate)(PTT) 섬유의 역학적 성질과 미세구조에 미치는 효과

  • Jeong, Kyung Hui (Dept. of Biomaterial Science, Pusan National University) ;
  • Lee, Eon Pil (Dept. of Biomaterial Science, Pusan National University) ;
  • Lee, Jae Ho (Dept. of Biomaterial Science, Pusan National University)
  • 정경희 (부산대학교 바이오소재과학과) ;
  • 이언필 (부산대학교 바이오소재과학과) ;
  • 이재호 (부산대학교 바이오소재과학과)
  • Received : 2013.03.25
  • Accepted : 2013.11.01
  • Published : 2013.12.31
Download PDF
⟨ Previous Next ⟩

Abstract

Polytrimethylene terephthalate(PTT) offers several advantageous properties such as good tensile strength, uniformity, stiffness, toughness, UV stability, resilience, stain resistance, outstanding elastic recovery, and dyeability. The effects of annealing temperature on physical properties and the structure of PTT filaments and yarn were investigated by measuring wide-angle X-ray diffraction (WAXD), density, optical birefringence, dynamic visco elasticity, and tensile testing. The intensity of maximum tan ${\delta}$ decreased and the temperature of maximum tan ${\delta}$ shifted to a higher temperature as the annealing temperature of filaments increased; however, it shifted to a lower temperature when the annealing temperature exceeded $130^{\circ}C$. In addition, crystallinity, density and D-spacing of (010) crystal face increased as the annealing temperature increased. Optical birefringence and specific stress were almost constant up to $100^{\circ}C$ and then decreased above $130^{\circ}C$. The shrinkage of PTT filament is 0 in boiling water when annealed above $130^{\circ}C$; consequently, the use of annealed fiber above $130^{\circ}C$ can remove thermal instability when dyeing PTT fiber. In the case of yarns, the thermal stability and physical properties of yarns showed the best effect when the ply number is less than 5, twist number is less than 400tpm, and the annealing time is 20minutes.

Keywords

References

  1. Bae, J. H., Kim, Y. H., & Kim, K. J. (1999). Intrinsic Birefringence of Poly(trimethylene Terphthalate). Proceedings of the Asian textile Conference, Kyoto, Japan, pp. 973-976.
  2. Brown, H. S., & Chuah, H. H. (1997). Texturing of textile filament yarns based on polytrimethylene terephthalate. Chemical Fibers International, 47(1), 72-74.
  3. Choi, H. (2003). Preparation and physical properties of Stretch fabrics using with poly(trimethylene terephthalate) fiber. Journal of the Korean Society for Clothing Industry, 5(1), 53-58.
  4. Choi, J. W., & Jang, B. S. (2006). A study on the tensile properties for poly(trimethylene terephthalate, PTT) 1${\times}$1 rib knitted fabrics. Journal of Korean Society Industrial Application, 9(4), 337-341.
  5. Chuah, H. H. (1996). Corterra poly(trimethylene terephthalate)-new polymeric fiber for carpets. Chemical Fibers International, 46(6), 424-428.
  6. Chung, H. G., Park, S. W., Kang, B. C., Song, M. H., Roh Y. H., & Yoon, H. S. (2005). Comparison of mechanical properties of warp knitted fabrics using PET and PTT yarn. Textile Science and Engineering, 42(5), 302-309.
  7. Dandurand, S. P., Perez, S., Revol, J. F., & Brisse, F. (1979). The crystal structure of poly(trimethylene terephthalate) by X-ray and electron diffraction. Polymer, 20(4), 419-426. https://doi.org/10.1016/0032-3861(79)90064-8
  8. Hong, S. H., Kim, R., Choi, C. N., Choi, H., Lee, W. E., & Cho, S. Y. (2003). Morphological structure of poly(trimethylene terephthalate) fibers annealed by passing on the plate heater. Polymer(Korea), 27(2), 106-112.
  9. Ji, B. C., Yoon, W. S., & Kim, S. Y. (1993). Structure and properties of zone-drawn PET film(I). Journal of the Korean Fiber Society, 30(4), 328-334.
  10. Kim, H. K., Kim, H. R., & Lee, J. J. (2008). Environmentally friendly dyeing of PTT with temporarily solubilized azo disperse dyes. Textile Science and Engineering, 45(4), 220-224.
  11. Kim, I. R. (2006). Change in physical properties of PTT and PET filament yarns due to heat treatment. Journal of the Korean Fiber Society, 43(4), 196-200.
  12. Kim. J. H., & Cho, H. H. (2005). Fine structure and physical properties of poly(ethylene 2,6-naphthalalene dicarboxylate) fibers with different thermal history. Journal of the Korean Fiber Society, 42(1), 21-28.
  13. Kim, N. H., Son, T. W., Jeong, M. G., Kim, Y. H., & Kim, D. S. (2003). Time dependent properties of partially oriented poly(trimethylene terephthalate)(PTT) fibers. Journal of the Korean Fiber Society, 40(3), 213-223.
  14. Kim, Y. H., Kim, K. J., & Lee, K. M. (1997). Melting and nonisothermal crystallization behaviors of poly(trimethylene terephthalate). Journal of the Korean Fiber Society, 34(12), 860-867.
  15. Lee, D. H., Jeong, D. S., Kim, H. J., & Lee, M. C. (2003). Dying of PTT fiber(2) -Effect of solvent treatment on the dyeing and physical properties of PTT fiber. Journal of the Korean Society of Dyers and Finishers, 15(4), 208-216.
  16. Lee, D. H., Jeong, D. S., & Lee, M. C. (2002). Dying of PTT fiber(1)-Effect of heat setting on the dyeing and physical properties of PTT fiber. Journal of the Korean Society of Dyers and Finishers, 14(9), 268-276.
  17. Lee, K. M., Lee, Kim, K. J., & Kim, Y. H. (1999). Isothermal crystallization behavior and some physical parameters of poly(trimethylene terephthalate). Polymer(Korea), 23(1), 56-65.
  18. Nakamae, K., Nishino, T., Hatra, K., Yokoyama, F., & Matsumoto, T. (1986). Elastic moduli of crystalline region of poly(trimethylene terephthalate). Zairyo, 35(396), 1066-1070.
  19. Oh, P. R., Kim, K. J., & Kim, Y. H. (1999). Dynamic mechanical analysis of drawn and annealed poly(trimethylene terephthalate) fiber. Journal of the Korean Fiber Society, 36(2), 132-139.
  20. Pyda, M., Boller, A., Grebowicz, J., Chuah, H., Lebedev, B. V., & Wunderlich, B. (1998). Heat capacity of poly(trimethylene terephthalate). Journal of Polymer Science Part B: Polymer Physics, 36(14), 2499-2511. https://doi.org/10.1002/(SICI)1099-0488(199810)36:14<2499::AID-POLB4>3.0.CO;2-O
  21. Seo, H. J., Kim, J. J., & Jeon, D. W. (2003). A study on the physical properties and subjective evaluation of the PTT(poly (trimethylene terephthalate)) fabric. Journal of Fashion Business, 7(4), 121-128.
  22. Sung, W. K. (2010). A study on the dyeing of PTT(polytrimethylene terephthalate)/ mixture fabrics with disperse dyes/acid dyes. Journal of the Korean Society for Clothing Industry, 12(1), 94-102. https://doi.org/10.5805/KSCI.2010.12.1.094