Korean Journal of Metals and Materials (대한금속재료학회지)

The Korean Institute of Metals and Materials (대한금속재료학회)
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Tribological Behavior Analysis of CrMoN Coating by XPS

XPS 분석을 통한 CrMoN 코팅의 마찰마모 거동 연구

  • Yang, Young-Hwan (Engineering Ceramic Center, KICET) ;
  • Lyo, In-Woong (CAE & Materials Research Team, Central Advanced Research & Engineering Institute, Hyundai & Kia Corporate Research & Development Division) ;
  • Park, Sang-Jin (Hyundai Hysco, Research and Development team) ;
  • Lim, Dea-soon (Department of Materials Science and Engineering) ;
  • Oh, Yoon-Suk (Engineering Ceramic Center, KICET)
  • 양영환 (한국세라믹기술원 이천분원 엔지니어링세라믹센터) ;
  • 여인웅 (현대.기아 연구개발총괄본부 중앙연구소 기반기술연구팀) ;
  • 박상진 (현대하이스코 연구개발팀) ;
  • 임대순 (고려대학교 신소재공학과) ;
  • 오윤석 (한국세라믹기술원 이천분원 엔지니어링세라믹센터)
  • Received : 2012.03.05
  • Published : 2012.08.25
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Abstract

The tribological behavior of CrMoN films with respect to surface chemistry was investigated by using X-ray photoelectron spectroscopy (XPS). All of the films were prepared from a hybrid PVD system consisting of DC unbalanced magnetron (UBM) sputtering and arc ion plating (AIP) sources. The tribological property of the films was evaluated by a friction coefficient using a Ball-on-disk type tribometer. The chemistry of wear track was analyzed by energy dispersive spectroscopy (EDS) and XPS. The friction coefficient was measured to be 0.4 for the CrMoN film, which is lower than that of a monolithic CrN film. EDS and XPS results imply the formation of an oxide layer on the coating surface, which was identified as molybdenum oxide phases, known to be a solid lubricant during the wear test.

Keywords

Acknowledgement

Supported by : 현대기아

References

  1. R. A. Koshy, M. E. Graham, and L. D Marks, Surf. Coat. Technol. 202, 1123 (2007). https://doi.org/10.1016/j.surfcoat.2007.07.090
  2. M. Kobayashi and Y. Doi, Thin Soild Films 24, 67 (1978).
  3. S. PalDey and S. C. Deevi, Mater. Sci. Eng. A 342, 58 (2003). https://doi.org/10.1016/S0921-5093(02)00259-9
  4. W. D. Munz, J. Vac. Sci. Technol. A 4, 2717 (1986). https://doi.org/10.1116/1.573713
  5. K. Bobzin, N. Bagcivan, P. Immich, C. Warnke, F. Klocke, C. Zeppenfeld, and P. Mattfeld, Surf. Coat. Technol. 203, 3184 (2009). https://doi.org/10.1016/j.surfcoat.2009.03.053
  6. Z. P. Huang, Y. Sun, and T. Bell, Wear 173, 13 (1994). https://doi.org/10.1016/0043-1648(94)90252-6
  7. W. Y Ho, D. H. Huang, L. T. Huang, C. H. Hsu, and D. Y. Wang, Surf. Coat. Technol. 177, 172 (2004).
  8. D. E. Richardson, Trans. ASME 122, 506 (2000).
  9. C. P. Mulligan, T. A. Blanchet, and D. Gall, Surf. Coat. Technol. 203, 584 (2008). https://doi.org/10.1016/j.surfcoat.2008.06.052
  10. A. Thobor-Keck, F. Lapostolle, A. S. Dehlinger, D. Pilloud, J. F. Pierson, and C. Coddet, Surf. Coat. Technol. 200, 264 (2005). https://doi.org/10.1016/j.surfcoat.2005.02.029
  11. Q. Yang and L. R. Zhao, Surf. Coat. Technol. 200, 1709 (2005). https://doi.org/10.1016/j.surfcoat.2005.08.087
  12. O. A. Abu-Zeid and R. I. Bates, Surf. Coat. Technol. 86, 526 (1996).
  13. M. Bielawski, Surf. Coat. Technol. 179, 10 (2004). https://doi.org/10.1016/S0257-8972(03)00796-5
  14. E. Y. Choi, M. C. Kang, D. H. Kwon, D. W. Shin, and K. H. Kim, J. Mater. Process. Technol. 187, 566 (2007).
  15. K. H. Kim, E. Y. Choi, S. G. Hong, B. G. Park, J. H. Yoon, and J. H. Yong, Surf. Coat. Technol. 201, 4068 (2006). https://doi.org/10.1016/j.surfcoat.2006.08.098
  16. J. L. Mo and M. H. Zhu, Tribol. Int. 42, 1758 (2009). https://doi.org/10.1016/j.triboint.2009.04.026
  17. Y. H. Yang, I. W. Lyo, S. J. Park, D. S. Lim, and Y. S. Oh, J. Kor. Inst. Surf. Eng. 44, 269 (2011). https://doi.org/10.5695/JKISE.2011.44.6.269
  18. H. S. Ahn and O. K. Kwon, Wear 225, 814 (1999).
  19. K. N. Kim, B. S. Kim, G. S. Shin, M. C. Park, D. H. Lee, and S. J. Kim, Met. Mater. Int. 17, 587 (2011). https://doi.org/10.1007/s12540-011-0809-5
  20. J. Singh and A. T. Alpas, Wear 181, 302 (1995).
  21. A. Lippitz and Tu. Hubert, Surf. Coat. Technol. 200, 250 (2005). https://doi.org/10.1016/j.surfcoat.2005.02.091
  22. NIST data base, http://srdata.nist.gov/xps/.
  23. LaSurface data base, http://www.lasurface.com/.
  24. Y. Wang and R. Y. Lin, Mater. Sci. Eng. B 112, 42 (2004). https://doi.org/10.1016/j.mseb.2004.05.010
  25. G. T. Kim, T. K. Park, H. S. Chung, Y. T. Kim, M. H. Kwon, and J. G. Choi, Appl. Surf. Sci. 152, 35 (1999). https://doi.org/10.1016/S0169-4332(99)00293-7