Korean Journal of Metals and Materials (대한금속재료학회지)

The Korean Institute of Metals and Materials (대한금속재료학회)
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Nanotubular Structure Formation on Ti-6Al-4V and Ti-Ta Alloy Surfaces by Electrochemical Methods

  • Lee, Kang (Department of Dental Materials, Research Center of Nano-Interface Activation for Biomaterials & Research Center for Oral Disease Regulation of the Aged, School of Dentistry, Chosun University) ;
  • Choe, Han-Cheol (Department of Dental Materials, Research Center of Nano-Interface Activation for Biomaterials & Research Center for Oral Disease Regulation of the Aged, School of Dentistry, Chosun University) ;
  • Ko, Yeong-Mu (Department of Dental Materials, Research Center of Nano-Interface Activation for Biomaterials & Research Center for Oral Disease Regulation of the Aged, School of Dentistry, Chosun University) ;
  • Brantley, W.A. (Department of Restorative, College of Dentistry, Ohio State University)
  • Received : 2011.07.28
  • Published : 2012.02.25
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Abstract

Nanotubular structure formation on the Ti-6Al-4V and Ti-Ta alloy surfaces by electrochemical methods has been studied using the anodizing method. A nanotube layer was formed on Ti alloys in 1.0 M $H_3PO_4$ electrolyte with small additions of $F^-$ ions. The nanotube nucleation and growth of the ${\alpha}$-phase and ${\beta}$-phase appeared differently, and showed different morphology for Cp-Ti, Ti-6Al-4V and Ti-Ta alloys. In the ${\alpha}$-phase of Cp-Ti and martensite ${\alpha}^{\prime}$ and in the ${\alpha}^{{\prime}{\prime}}$ and ${\beta}$-phase of the Ti-Ta alloy, the nanotube showed a clearly highly ordered $TiO_2$ layer. In the case of the Ti-Ta alloy, the pore size of the nanotube was smaller than that of the Cp-Ti due to the ${\beta}$-stabilizing Ta element. In the case of the Ti-6Al-4V alloy, the ${\alpha}$-phase showed a stable porous structure; the ${\beta}$-phase was dissolved entirely. The nanotube with two-size scale and high order showed itself on Ti-Ta alloys with increasing Ta content.

Keywords

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