Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Hydrothermal Synthesis, Crystal Structure of Four Novel Complexes Based on Thiabendazole Ligand

  • Wei, Shui-Qiang (College of Chemistry and Chemical Engineering, Guangxi University) ;
  • Lin, Cui-Wu (College of Chemistry and Chemical Engineering, Guangxi University) ;
  • Yin, Xian-Hong (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities) ;
  • Huang, Yue-Jiao (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities) ;
  • Luo, Pei-Qi (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
  • Received : 2012.05.15
  • Accepted : 2012.06.01
  • Published : 2012.09.20
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Abstract

Four novel metal-organic complexes $[Cd_2(IP)_2(TBZ)_2(H_2O)_2]{\cdot}(H_2O)$ (1), $[Zn_4(IP)_4(TBZ)_4]{\cdot}2(H_2O)$ (2), $[Zn_2(BTC)(TBZ)_2(CO_2H)]$ (3), [Co(PDC)(TBZ)] (4) (where IP = isophthalate; TBZ = thiabendazole; BTC = 1,3,5-benzenetricarboxylate; PDC = pyridine-3,4-dicarboxylate) have been prepared and characterized by IR spectrum, elemental analysis, thermogravimetric analysis, and single-crystal X-ray diffraction. X-ray structure analysis reveals that 1, 2, and 3 are one-dimensional chain polymers, while 4 is a two-dimensional network polymer. The TBZ acts as a typical chelating ligand coordinated to the metal center in all complexes. The 1D chain architecture of 1 is constructed from isophthalates and cadmium atoms. A simultaneous presence of chelating, monodentate and bidentate coordination modes of IP ligands is observed in complex 2. In complex 3, the 16-membered rings are alternately arranged forming an infinite 1D double-chain structure. The 2D skeleton of 4 is formed by cobalt ions as nodes and PDC dianions as spacers, through coordination bonds. The hydrogen bonds and ${\pi}-{\pi}$ stacking play important roles in affecting the final structure where complexes 1 and 3 have 2D supramolecular networks, while complexes 2 and 4 have 3D supramolecular architectures.

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References

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