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New Donor Materials Based on Thiazole and Triphenylamine for Photovoltaic Devices

  • Ro, Tak-Kyun (Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Hong, Jong-In (Department of Chemistry, College of Natural Sciences, Seoul National University)
  • 투고 : 2012.04.13
  • 심사 : 2012.05.26
  • 발행 : 2012.09.20

초록

New photovoltaic donor materials, 4,4'-(2,2'-bithiazole-5,5'-diyl)bis(N,N-diphenylbenzenamine) (BDT) and 4-(2,2'-bithiazol-5-yl)-N,N-diphenylbenzenamine (BT), were synthesized. A solution processable triphenylamine-containing bithiazole (BDT and BT) was blended with a [6,6]-phenyl $C_{61}$ butyric acid methyl ester (PCBM) acceptor to study the performance of small-molecule-based bulk heterojunction (BHJ) photovoltaic devices. Optimum device performance was achieved after annealing, for device with a BDT/PCBM ratio of 1:4. The open-circuit voltage, short-circuit current, and power conversion efficiency of the device with the aforementioned BDT/PCBM ratio were 0.51 V, 4.10 $mA\;cm^{-2}$, and 0.68%, respectively, under simulated AM 1.5 solar irradiation (100 $mW\;cm^{-2}$).

키워드

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