Korean Journal of Environmental Agriculture (한국환경농학회지)

The Korean Society of Environmental Agriculture (한국환경농학회)
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Multiresidue Analysis Method for Determination of Unregistered Organophosphorus Pesticides in Korea for Imported Agri-Food

국내 미등록 유기인계 농약의 수입 농식품에 대한 다성분 잔류분석법

  • Jeon, Young-Hwan (School of Applied Biosciences, Kyungpook National University) ;
  • Hwang, Jeong-In (School of Applied Biosciences, Kyungpook National University) ;
  • Ahn, Ji-Woon (School of Applied Biosciences, Kyungpook National University) ;
  • Kim, Hyo-Young (School of Applied Biosciences, Kyungpook National University) ;
  • Do, Jung-Ah (National Institute of Food and Drug Safety Evaluation) ;
  • Oh, Jae-Ho (National Institute of Food and Drug Safety Evaluation) ;
  • Hwang, In-Gyun (National Institute of Food and Drug Safety Evaluation) ;
  • Im, Moo-Hyeog (Korea Food and Drug Administration) ;
  • Lee, Joong-Keun (Korea Health Industry Development Institute) ;
  • Lee, Young-Deuk (Division of Life and Environmental Science, Daegu University) ;
  • Kim, Jang-Eok (School of Applied Biosciences, Kyungpook National University)
  • Received : 2012.09.07
  • Accepted : 2012.09.21
  • Published : 2012.09.30
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Abstract

BACKGROUND: For safety evaluation of imported agri-food in Korea, the multiresidue analysis method was establised for unregistered organophosphorus pesticides, aspon, chlorthion, chlorthiophos, crotoxyphos, demeton-O, demeton-S, demeton-S-methyl, dioxathion, heptenophos, iodofenphos, leptophos, methyl-trithion, propetamphos and sulfotep. METHODS AND RESULTS: The used method for multiresidue analysis in brown rice and orange used as representative samples of imported agri-food was the official method of Korean Food and Drug Administration. The results of validation test of 13 organophosphorus pesticides except crotoxyphos for multiresidue analysis method are compared to the criteria such as specificity, linearity, accuracy, precision and limit of quantification. CONCLUSION: The used method for multiresidue analysis of unregistered 13 organophosphorus pesticides except crotoxyphos in Korea can surely be used as an official method for routine analysis of imported agri-food.

외국으로부터 수입되는 농식품에 대하여 국내에 미등록 된 유기인계 농약 aspon, chlorthion, chlorthiophos, crotoxyphos, demeton-O, demeton-S, demeton-S-methyl, dioxathion, heptenophos, iodofenphos, leptophos, methyl-trithion, propetamphos 및 sulfotep 등 14종에 대한 안전성 평가를 위하여 다성분 잔류분석법을 확립하고자 하였다. 잔류분석법은 식품의약품안전청에서 고시한 다종농약다성분 동시분석법-제2법에 잘 적용되었다. 수입 농산물의 대표 시료로 선정된 현미와 오렌지에 대한 유기인계 농약 14종 대한 잔류분석법의 밸리데이션을 실시한 결과 특이성, 직선성, 정확성, 정밀성 및 정량한계 수준을 만족시키는 것으로 나타났다. 단지 crotoxyphos의 경우는 기기상의 정량한계가 낮아서 저농도에서의 회수율은 좋지 않은 결과를 나타내었다. 따라서 본 연구에서 확립된 다성분 잔류분석법은 수입 농산물 중 crotoxyphos를 제외한 aspon 외 12종의 유기인계 농약에 대해 적용 가능한 것으로 나타났다.

Keywords

References

  1. Borras, E., Sanchez, P., Munoz, A., Tortajada-Genaro L.A., 2011. Development of a gas chromatographymass spectrometry method for the determination of pesticides in gaseous and particulate phases in the atmosphere, Analytica. Chimica. Acta. 699, 57-65. https://doi.org/10.1016/j.aca.2011.05.009
  2. Breen, J.L., 2007. International trade implications of pesticide residues in food, Kor. J. Pesti. Sci. 58-64.
  3. Cooke, C.M., Shaw, G., Lester, J.N., Collins, C.D., 2004. Determination of solid-liquid partition coefficients (Kd) for diazinon, propetamphos and cis-permethrin, Science of The Total Environment 329(1-3), 197-213. https://doi.org/10.1016/j.scitotenv.2004.02.021
  4. Fenoll, J., Hellin, P., Martinez, C.M., Miguel, M., Flores, P., 2007. Multiresidue method for analysis of pesticides in pepper and tomato by gas chromatography with nitrogen-phosphorus detection, Food Chem. 105(2), 711-719. https://doi.org/10.1016/j.foodchem.2006.12.060
  5. Jeon, Y.H., Kim, H.Y.. Hwang, J.I., Kim, J.H., Do, J.A., Im, M.H., Oh, J.H., Kwon, K.S., Lee, J.K., Lee, Y.D., Kim, J.E., 2011. Application of multiresidue analysis method of unregistered pesticides in Korea for imported food, Korean J. Environ. Agric. 30(3), 339-345. https://doi.org/10.5338/KJEA.2011.30.3.339
  6. Lee, E.M., Lee, H.R., Riu, M.J., Park, H.W., Na, Y.R., Song, H.H., Keum, Y.S., Zhu, Y., Kim, J.H., 2009. Establishment of analytical method of prochloraz in cabbage, apple, mandarin, pepper and hulled rice with GC-ECD, Korean J. Environ. Agri. 28(4), 427-434. https://doi.org/10.5338/KJEA.2009.28.4.427
  7. Lehotay, S.J., Kok, A., Hiemstra, M., Bodegraven, P., 2005. Validation of a fast and easy method for the determination of residues from 229 pesticides in fruits and vegetables using gas and liquid chromatography and mass spectrometric detection, J. AOAC Int. 88(2), 595-614.
  8. Pareja, L., Fernandez-Alba, A.R., Cesio, V., Heinzen, H., 2011. Analytical methods for pesticide residues in rice, Trends in Analytical Chemistry 30(2), 270-291. https://doi.org/10.1016/j.trac.2010.12.001
  9. Park, J.H., Kim, T.K., Oh, C.H., Kim, J.H., Lee, Y.D., Kim, J.E., 2004. Analysis of multiple pesticide residues in apples and pears using gas-liquid chromatography, Korean J. Environ. Agri. 23(3), 148-157. https://doi.org/10.5338/KJEA.2004.23.3.148
  10. Park, S.H., 2008. Safety management system of GM food, Food Sci. Indust. 41(2), 5-15.
  11. Qu, L.J., Zhang, H., Zhu, J.H., Yang, G.S., Aboul-Enein, H.Y., 2010. Rapid determination of organophosphorous pesticides in leeks by gas chromatography-triple quadrupole mass spectrometry, Food Chem. 122(1), 327-332. https://doi.org/10.1016/j.foodchem.2010.02.038
  12. Tarbah, F.A., Mahler, H., Temme, O., Daldrup, T,. 2001. An analytical method for the rapid screening of organophosphate pesticides in human biological samples and foodstuffs, Forensic Science International 121(1-2), 126-133. https://doi.org/10.1016/S0379-0738(01)00462-5
  13. Tolosa, I., Douy, B., Carvalho, F.P., 1999. Pesticide residue analysis in foodstuffs applying capillary gas chromatography with mass spectrometric detection, J. Chromatogr. A . 864(1), 121-136. https://doi.org/10.1016/S0021-9673(99)00989-9
  14. Tomlin, C.D.S., 2006. The Pesticide Manual (14th), BCPC, Hampshire, UK, pp. 232-233, 800-801, 870-871, 881-882, 1109, 1129.
  15. Yang, X., Zhang, H., Liu, Y., Wang, J., Zhang, Y.C., Dong, A.J., Zhao, H.T., Sun, C.H., Cui, J., 2011. Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography-mass spectrometry: Determination of 88 pesticides in berries using SPE and GC-MS, Food Chem. 127(2), 855-865. https://doi.org/10.1016/j.foodchem.2011.01.024
  16. Zhao, Y.G., Shen, H.Y., Shi, J.W., Chen, X.H., Jin, M.C., 2011. Preparation and characterization of amino functionalized nano-composite material and its application for multi-residue analysis of pesticides in cabbage by gas chromatography-.triple quadrupole mass spectrometry, J. Chromatogr. A. 1218(33), 5568-5580. https://doi.org/10.1016/j.chroma.2011.06.090

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