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Fabrication and Characterization of High-Performance Thin-Film Encapsulation for Organic Electronics

유기반도체용 고성능 박막 봉지재의 제조 및 평가

  • Kim, Nam-Su (Components and Materials Physics Research Center, Korea Electronics Technology Institute) ;
  • Graham, Samuel (Woodruff School of Mechanical Engineering, Georgia Institute of Technology)
  • 김남수 (전자부품연구원 부품소재물리연구센터) ;
  • Received : 2012.05.30
  • Accepted : 2012.08.13
  • Published : 2012.10.01

Abstract

Continued advancements in organic materials have led to the development of organic devices that are thin, flexible, and lightweight and that can potentially be used as low-cost energy-conversion devices. While these devices have many advantages, the environmentally induced degradation of the active materials and the low-work-function electrodes remain a valid concern. Hence, many vacuum deposition processes have been applied to develop low-permeation barrier coatings. In this work, we present the results pertaining to the developed thin-film encapsulation. Multilayer encapsulation involves the use of $SiO_x$ or $SiN_x$ with parylene. The effective water vapor transmission rates were investigated using a Ca-corrosion test. The integration of the developed barrier layers was demonstrated by encapsulating pentacene/$C_{60}$ solar cells, and the results are presented.

유기전자재료의 발전으로 박막화, 유연화, 경량화가 가능하면서, 저가의 생산비용으로 제조 될 수 있는 유기반도체의 개발 및 상용화에 대한 연구가 활발히 이루어지고 있다. 하지만, 유기반도체를 구성하는 유기재료 및 전극재료가 미량의 수분과 반응으로 성능이 저하되는 문제로 상용화의 큰 걸림돌이 되고 있다. 따라서 유기재료 및 전극을 동작환경의 수분으로부터 보호할 수 있는 고성능 투습 방지막 개발에 대한 연구가 많이 진행되고 있다. 본 연구에서는 $SiO_x$/parylene 및 $SiN_x$/parylene 구조를 이용한 다중 구조의 고성능 박막 봉지막을 개발하고, 개발된 박막을 Ca-corrosion test를 이용하여 수분투과율을 측정하였다. 또한 박막 봉지재를 유기태양전지에 적용하여 유기태양전지의 수명과 투습특성과의 관계를 확인하였다.

Keywords

References

  1. Tang, C. W. and Van Slyke, S. A., 1987, "Organic Electroluminescent Diodes," Appl. Phys. Lett., Vol. 51, pp. 183-185. https://doi.org/10.1063/1.98916
  2. Horowitz, G., 1998, "Organic Field-Effect Transistors," Adv. Mater., Vol. 10, pp. 365-377. https://doi.org/10.1002/(SICI)1521-4095(199803)10:5<365::AID-ADMA365>3.0.CO;2-U
  3. Bartzsch, M., Kempa, H., Otto, M. and Otto, M., 2007, Device and Circuit Simulation of Printed Polymer Electronics, Vol. 8, pp. 431-438. https://doi.org/10.1016/j.orgel.2007.02.005
  4. Luo, Y. C., Aziz, H., Popovic, Z. D. and Xu, G., 2007, "Degradation Mechanism in Orgnaic Light Emitting Devices: Metal Migration Model Versus Unstable Tris(8-Hydroxyquinoline) Aluminum Cathode Model," Journal of Applied Physics, Vol 101, Issue 3, pp. 34510-34513. https://doi.org/10.1063/1.2435070
  5. Aziz, H. and Popovic, Z. D., 2004, "Degradation Phenomena in Small-Molecule Organic Light-Emitting Devices," Chemistry of Materials, Vol.16, pp. 4522-4532. https://doi.org/10.1021/cm040081o
  6. Aziz, H., Popovic, Z. D., Hu, N. X., Hor, A. M. and Xu, G., 1999,"Degradation Mechanism of Small Molecule-Based Organic Light-Emitting Devices," Science, Vol. 283, Issue 5409, pp.1900-1902. https://doi.org/10.1126/science.283.5409.1900
  7. Lewi, J. S. and, Weaver, M. S., 2004, "Thin-Film Permeation Barrier Technology for Flexible Organic Light-Emitting Devices," IEEE Journal of Selected Topics in Quantum Electronics, Vol. 10, Issue 1, pp. 45-57. https://doi.org/10.1109/JSTQE.2004.824072
  8. Henry, B. M., Dinelli, F., Zhao, K. Y., Grovenor, C. R. Kolosov, M. O. V., Briggs, G. A. D., Roberts, A. P., Kumar, R. S. and Howson, R. P., 1999, "A Microstructural Study of Transparent Metal Oxide Gas Barrier Films," Thin Solid Films, Vol. 356, pp. 500-505. https://doi.org/10.1016/S0040-6090(99)00461-7
  9. Weaver, M. S., Michalski, L. A., Rajan, K., Rothman, M. A., Silvernail, J. A., Brown, J. J., Burrows, P. E., Graff, G. L., Gross, M. E., Martin, P. M., Hall, M., Mast, E., Bonham, C., Bennett, W. and Zumhoff, M., 2002, "Organic Light Emitting Devices with Extended Operating Lifetimes on Plastic Substrates," Applied Physics Letters, Vol. 81, Issue 16, pp. 2929-2931. https://doi.org/10.1063/1.1514831
  10. Dameron, A. A., Davidson, S. D., Burton, B. B., Carcia, P. F., McLean, R. S. and George, S. M., 2008, "Gas Diffusion Barrier on Polymers Using Multilayers Fabricated by Al2O3 and SiOx Atomic Layer Deposition," Journal of Physical Chemistry C, Vol. 112, Issue 12, pp. 4573-4580. https://doi.org/10.1021/jp076866+
  11. Kim, N., Potscavage, W. J. Jr., Domercq, B., Kippelen, B. and Graham, S., 2009, A Hybrid Encapsulation Method for Organic Electronics, Appl. Phys. Lett., Vol. 94, pp. 163308-01-03. https://doi.org/10.1063/1.3115144
  12. Kim, N., Potscavage, W. J. Jr., Sundaramoothi, A., Henderson, M. C., Kippelen, B. and Graham, S., 2012, A Correlation Study Between Barrier Layer Film Performance and Shelf Lifetime of Encapsulated Organic Solar Cells, Sol. Energ. Mat. Sol., Vol. 101, pp. 140-146. https://doi.org/10.1016/j.solmat.2012.02.002
  13. Paetzold, R., Winnacker, A., Henseler, D., Cesari, V. and Heuser, K., 2003, "Permeation Rate Measurements by Electrical Analysis of Calcium Corrosion," Review of Scientific Instruments, Vol. 74, pp. 5147-5150. https://doi.org/10.1063/1.1626015
  14. Yoo, S., Domercq, B. and Kippelen, B., 2004, "Efficient Thin-Film Organic Solar Cells Based on Pentacene/C-60 Heterojunctions," Applied Physics Letters, Vol. 85, Issue 22, pp. 5427-5429. https://doi.org/10.1063/1.1829777