Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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An Efficient Method for N-Formylation of Amines Using Natural HEU Zeolite at Room Temperature Under Solvent-Free Conditions

  • Bahari, Siavash (Department of Chemistry, Ahar Branch, Islamic Azad University) ;
  • Mohammadi-Aghdam, Babak (Department of Chemistry, Ahar Branch, Islamic Azad University) ;
  • Mohammad Sajadi, S. (Department of Petrolium Geoscience, Faculty of Sciences, University of Soran) ;
  • Zeidali, Fereshteh (Ilam petrochemical Complex)
  • Received : 2012.03.03
  • Accepted : 2012.04.02
  • Published : 2012.07.20
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Abstract

A rapid and practical green route for N-formylation of primary and secondary amines with formic acid at room temperature under the solvent-free conditions using HEU zeolite as a heterogeneous, reusable and highly efficient catalyst is described. The process is remarkably simple and environmentally benign. Excellent chemoselectivity was observed for the conversion of primary amines in the presence of secondary amines.

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References

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