Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Metal-Ion Interactions with Sugars. The Crystal Structure of CaCl2-Fructose Complex

  • Guo, Jianyu (Department of Chemistry, Shanghai Normal University) ;
  • Lu, Yan (School of Engineering and Innovation, Shanghai Institute of Technology) ;
  • Whiting, Roger (School of Applied Sciences, AUT University)
  • Received : 2012.01.30
  • Accepted : 2012.04.04
  • Published : 2012.06.20
Download PDF
⟨ Previous Next ⟩

Abstract

The single-crystal structure of $CaCl_2{\cdot}2C_6H_{12}O_6{\cdot}3H_2O$ was determined with Mr=525.34, a=16.054(7) ${\AA}$, b=7.864(4) ${\AA}$, c=10.909(5) ${\AA}$, ${\beta}=127.894(8)^{\circ}$, V=1086.9(9) ${\AA}^3$, C2, Z=2 and $R$=0.0227 for 1727 observed reflections. The fructose moiety of the complex exists as a ${\beta}$-D-pyranose. The calcium ion is surrounded by eight oxygen atoms, These are arranged in symmetry-related pairs derived from four sugar and two water molecules. Three nonvicinal hydroxyl groups of fructose are involved in calcium binding. All the hydroxyl groups and water molecules are involved in forming an extensive hydrogen-bond network.

Keywords

References

  1. Angyal, S. J. Tetrahedron 1974, 30, 1695.
  2. Vasela, A.; Lönnberg, H. Acta Chem. Scand. Ser. A 1981, 35, 123.
  3. Craig, D. C.; Stephenson, N. C.; Stevens, J. D. Carbohydr. Res. 1972, 22, 494. https://doi.org/10.1016/S0008-6215(00)81309-9
  4. Morel-Desrosiers, N.; Morel, J. P. J. Chem. Soc., Faraday Trans. 1989, 85, 3461. https://doi.org/10.1039/f19898503461
  5. Angyal, S. J. Pure Appl. Chem. 1973, 35, 131. https://doi.org/10.1351/pac197335020131
  6. Guo, J.; Zhang, X. Carbohydr. Res. 2004, 339, 1421. https://doi.org/10.1016/j.carres.2004.03.004
  7. Moore, C. L. Biochem. Biophys. Res. Commun. 1971, 42, 298. https://doi.org/10.1016/0006-291X(71)90102-1
  8. Smith, Q. T.; Lindenbaum, A. Calcif. Tissue Res. 1971, 7, 290. https://doi.org/10.1007/BF02062618
  9. Hamazaki, H. J. Biol. Chem. 1987, 262, 1456.
  10. Sharom, F. J.; Grant, C. W. M. Biochem. Biophys. Acta 1978, 507, 280. https://doi.org/10.1016/0005-2736(78)90423-6
  11. Weinbaum, G.; Burger, M. M. Nature 1973, 244, 510. https://doi.org/10.1038/244510a0
  12. Dheu-Andries, M. L.; Perez, S. Carbohydr. Res. 1983, 124, 324. https://doi.org/10.1016/0008-6215(83)88468-7
  13. Lu, Y.; Deng, G.; Miao, F.; Li, Z. J. Inorg. Biochem. 2003, 96, 487. https://doi.org/10.1016/S0162-0134(03)00251-4
  14. Craig, D. C.; Stephenson, N. C.; Stevens, J. D. Crystal. Struc. Commun. 1974, 3, 195.
  15. Kanters, J. A.; Roelofsen, G.; Alblas, B. P. Acta Cryst. 1977, B33, 665.

Cited by

  1. Non-linear optical properties of β-D-fructopyranose calcium chloride MOFs: an experimental and theoretical approach vol.50, pp.12, 2015, https://doi.org/10.1007/s10853-015-8985-1
  2. Interactions of alkali- and alkaline earth-halides with carbohydrates in the crystalline state – the overlooked salt and sugar cocrystals vol.18, pp.10, 2016, https://doi.org/10.1039/C6CE00218H
  3. Interaction of saccharides and sugar alcohols with well cement vol.28, pp.8, 2016, https://doi.org/10.1680/jadcr.16.00009
  4. Sucrose-calcium Complexation for the Durable Biomass Pellet vol.23, pp.3, 2018, https://doi.org/10.1007/s12257-018-0118-7
  5. Sugar-metal ion interaction: Crystal structure and spectroscopic study of potassium chloride complex with D-glucose, KCl·2C6H12O6 vol.1206, pp.None, 2012, https://doi.org/10.1016/j.molstruc.2019.127671