DOI QR코드

DOI QR Code

다전극 산소 센서를 이용한 고분자 막의 산소 투과도 측정 장치 연구

A Study on the Apparatus for Measuring Oxygen-Permeability of Membranes with a Multi-Electrode Oxygen Sensor

  • 정일손 (수원대학교 화학공학과) ;
  • 정재칠 (수원대학교 화학공학과) ;
  • 김태진 (수원대학교 화학공학과)
  • Jeong, Il-Son (University of Suwon, Department of Chemical Engineering) ;
  • Jung, Jae-Chil (University of Suwon, Department of Chemical Engineering) ;
  • Kim, Tai-Jin (University of Suwon, Department of Chemical Engineering)
  • 투고 : 2012.01.28
  • 심사 : 2012.05.16
  • 발행 : 2012.05.31

초록

The existing permeability measurements based on pressure differential between the polymer membrane that is permeable to measure the amount of oxygen used, but these methods must be kept in a vacuum, and the measurement of the membrane with low permeability in the membrane is too time consuming. In recent years by using electrochemical method polymer membrane currents caused by the amount of oxygen is a measure of how much is used. In this study, apparatus consisting of one anode and six cathodes for multi-oxygen permeability tester used the same number of membranes produced by electrochemical oxygen permeation characteristics. In this study, one silver/silver chloride anode electrochemical method with a hexagonal sensor to put various kinds of polymer membranes with the six oxygen permeability for simultaneous measurement in real-time systems. Six cathodes (Pt), and one of the coil-shaped anode (Ag/AgCl) to form a hexagonal one of the polarographic oxygen sensor in a single measurement system by six sensors. Each sensor for making hexagonal specificity of the sensor to compensate for the conditions obtained in a pure nitrogen gas and pure oxygen gas conditions. With this study, self-developed hexagonal sensor capable of measuring sensors and oxygen permeability tester, for a multi-six different oxygen permeability characteristics of the membrane measured at the same time.

키워드

참고문헌

  1. Aiba, S. and Huang, S. Y. "Oxygen permeability and diffusivity in polymer membranes immersed in liquids", Chemical Engineering Science, vol. 24, pp. 1149-1159, 1969. https://doi.org/10.1016/0009-2509(69)80085-0
  2. Alway, B., Sangchantra, R., and Stewart, P.J "Modeling the dissolution of diazpam in lactose interactive mixtures", International journal of Pharmaceutics, vol. 130, no. 2, 1996.
  3. Berkenbosch, A. "Time course of resonse of the membrane-coverde oxygen electrode", Acta Physiol. Pharmacol. Neerl. vol. 14, pp. 300-316. 1967.
  4. Lazik, D. and Geistlinger. H., "A new method for membrane-based gas measurements", Sensors and Actuators A, vol. 117, pp. 241-251, 2005. https://doi.org/10.1016/j.sna.2004.06.015
  5. Minoura, N., Fujiwara, Y., and Nakagawa, T. "Permeability of synthetic poly($\alpha$-amino acid membranes to oxygen dissolved in water", Industrial Products Research Institute, Shimomaruko, Otaku, Tokyo 146, Japan ,1979.
  6. Pasternak, R. A., Christensen. M. V. and Heller, J., "Diffusion and permeation of oxygen, nitrogen, carbon dioxide, and nitrogen dioxide through polytetrafluoroethylene", Macromolecules, vol. 3, no. 3, p. 336, 1970.
  7. Qin, Zongyi, Wang. Pei-Nan, and Wang. Yujiang., "Enhanced sensing performance of the amperometric gas sensor by laser-patterning of the polymer membrane electrode", Sensors and Actuators B, vol. 107, pp. 805-811, 2005. https://doi.org/10.1016/j.snb.2004.12.021
  8. Tri, Ho. Q., Verlinden. Bert E., Verboven. Pieter, and Nicolaï. Bart M., "Gas diffusion properties at different positions in the pear", Postharvest Biology and Technology, vol. 41, pp. 113-120, 2006. https://doi.org/10.1016/j.postharvbio.2006.04.002
  9. Yong, Zhang., Junhua. Liu., Xin. Li. and Changchun. Zhu., "The structure optimization of carbon nanotube film cathode in the application of gas sensor", Sensors and Actuators A, vol. 128, pp. 278-289, 2006. https://doi.org/10.1016/j.sna.2006.01.027