DOI QR코드

DOI QR Code

무인항공기용 경량화 직접메탄올연료전지 스택 개발을 위한 복합소재 분리판 제작 및 성능 평가 (I)

Evaluation and Fabrication of Composite Bipolar Plate to Develop a Light Weight Direct Methanol Fuel Cell Stack for Small-scale UAV Application (I)

  • 강경문 (인하대학교 기계공학과) ;
  • 박성현 (인하대학교 기계공학과) ;
  • 김진수 ((주) 일도에프엔씨 기술연구소) ;
  • 지현진 (국방과학기술연구소) ;
  • 주현철 (인하대학교 기계공학과)
  • 투고 : 2012.04.02
  • 심사 : 2012.04.27
  • 발행 : 2012.04.30

초록

A bipolar plate is a major component of a fuel cell stack, which occupies 50~60% of the total weight and over 50% of the total cost of a typical fuel cell stack. In this study, a composite bipolar plate is designed and fabricated to develop a compact and light-weight direct methanol fuel cell (DMFC) stack for a small-scale Unmanned Aerial Vehicle (UAV) application. The composite bipolar plates for DMFCs are prepared by a compression molding method using resole type phenol resin as a binder and natural graphite and carbon black as a conductor filler and tested in terms of electrical conductivity, mechanical strength and hydrogen permeability. The flexural strength of 63 MPa and the in-plane electrical conductivities of 191 S $cm^{-1}$ are achieved under the optimum bipolar plate composition of phenol : 18%; natural graphite : 82%; carbon black : 3%, indicating that the composite bipolar plates exhibit sufficient mechanical strength, electrical conductivity and hydrogen permeability to be applied in a DMFC stack. A DMFC with the composite bipolar plate is tested and shows a similar cell performance with a conventional DMFC with graphite-based bipolar plate.

키워드

참고문헌

  1. 권세진, 김태규 : "연료전지 무인기", KSAS 매거진 제 3권 제 2호, 2009, pp. 65-72.
  2. "Hydrogen fuel cells power Georgia Tech UAV", Fuel Cells Bulletin, Vol. 2006, Issue 10, 2006, pp. 9-10.
  3. "Blue Bird, Horizon unveil first commercial fuel cell UAV", Fuel Cells Bulletin, Vol. 2009, Issue 10, 2009, p. 6.
  4. "Energy Or fuel cell powered UAV reaches 10 h flight endurance", Fuel Cells Bulletin, Vol. 2011, Issue 9, 2011, pp. 4-5.
  5. T. Kim and S. Kwon, "Design and development of a fuel cell-powered small unmanned aircraft", Int J. Hydrogen Energy, Vol. 37, Issue 1, 2012, pp. 615-622. https://doi.org/10.1016/j.ijhydene.2011.09.051
  6. T. H. Bradley, B. A. Moffitt, D. N. Mavris and D. E. Parekh, "Development and experimental characterization of a fuel cell powered aircraft", J. Power Sources, Vol. 171, Issue 2, 2007, pp. 793-801. https://doi.org/10.1016/j.jpowsour.2007.06.215
  7. B.O. I, R. Kirchain, R. Roth, "Technical cost analysis for PEM fuel cells", J Power Sources, Vol. 109, 2002, pp. 71-75. https://doi.org/10.1016/S0378-7753(02)00062-9
  8. H. Tsuchiya, O. Kobayashi, "Mass production cost of PEMfuel cell by learning curve", Int J Hydrogen Energy, Vol. 29, 2004, pp. 985-990. https://doi.org/10.1016/j.ijhydene.2003.10.011
  9. 김정헌, "고분자연료전지용 분리판 상용화 기술개발", 한국수소 및 신에너지학회 논문집, 제 22권 3호, 2011, pp. 409-414.
  10. I. U. Hwang, H. N. Yu, S. S. Kim, D. G. Lee, J. D. Suh,S. H. Lee, B. K. Ahn, S. H. Kim, and T. W. Lim, "Bipolar plate made of carbon fiber epoxy composite for polymer electrolyte membrane fuel cells", J. Power Sources, Vol. 184, 2008, pp. 90-94. https://doi.org/10.1016/j.jpowsour.2008.05.088
  11. E. A. Cho, U. S. Jeon, S. A. Hong, I. H. Oh, and S. G. Kang, "Performance of a 1 kW-class PEMFC stack using TiN-coated 316 stainless steel bipolar plates", J. Power Sources, Vol. 142, 2005, pp. 177-183. https://doi.org/10.1016/j.jpowsour.2004.10.032
  12. J. Lee, Y. Jang, C. Hong, N. Kim, P. Li, H. Lee, "Effect of carbon fillers on properties of polymer composite bipolar plates of fuel cells", J. Power Source, Vol. 193, 2009, pp. 523-529. https://doi.org/10.1016/j.jpowsour.2009.04.029
  13. Priyanka H. Maheshwari, R.B. Mathur, T.L. Dhami, "Fabrication of high strength and a low weight composite bipolar plate for fuel cell applications", J. Power Source, Vol. 173, 2007, pp. 394-403. https://doi.org/10.1016/j.jpowsour.2007.04.049
  14. R.B. Mathur, S.R. Dhakate, D.K. Gupta, T.L. Dhami, R.K. Aggarwal, "Effect of different carbon fillers on the properties of graphite composite bipolar plate", J. materials processing technology, Vol. 203, 2008, pp. 184-192. https://doi.org/10.1016/j.jmatprotec.2007.10.044
  15. H. Wolf, M. Willert-Porada, "Electrically conductive LCP-carbon composite with low carbon content for bipolar plate application in polymer electrolyte membrane fuel cell", J. Power Sources, Vol. 153, 2006, pp. 41-46. https://doi.org/10.1016/j.jpowsour.2005.03.182
  16. Richard Blunk, Feng Zhong, John Owens, "Automotive composite fuel cell bipolar plates : Hydrogen permeation concerns", J. Power S ources, Vol. 159, 2006, pp. 533-542. https://doi.org/10.1016/j.jpowsour.2005.09.068
  17. K. Kang, G. Lee, G. Gwak, Y. Choi and H. Ju, "Development of an advanced MEA to use highconcentration methanol fuel in a direct methanol fuel cell system.", Int. J. Hydrogen Energy, Vol. 37, 2012, pp. 6285-6291. https://doi.org/10.1016/j.ijhydene.2011.06.114