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시멘트 페이스트 수용액의 칼슘이온을 이용한 $CO_2$ 가스 고정화에 관한 실험적 연구

Experimental Study on the $CO_2$ Gas Fixation Method Using the Cement-Paste Solution's Calcium Ion

  • 곽재석 (한양대학교 일반대학원) ;
  • 강창수 (한양대학교 일반대학원) ;
  • 이한승 (한양대학교 ERICA 캠퍼스 건축학부)
  • 투고 : 2012.04.05
  • 발행 : 2012.07.25

초록

The Purpose of this study is to provide experimental material which could be valuable help for the recycling of the cement hydration dissolution ingredient and the reduction of carbon dioxide, those are an issue that gives rise to enormous controversy. The way of the experiment in chemistry is to inject carbon dioxide into aqueous solution made by calcium hydroxide using the Pressure Reactor. Before conducting the experiment, the existing studies based on the material, the mechanism of hydration reaction, carbonation and the solidification were considered. As a result, it was measured how much carbon dioxide is absorbed by the aqueous solution and it was confirmed how much calcium carbonate is produced. Therefore, the amount of carbon dioxide absorption in the cement hydration dissolution ingredient was quantitatively predicted. In addition, the crystal structure and the degree of purity of calcium carbonate were analyzed by FE-SEM, EDS and XRD. It could be an fundamental data to decrease both carbon dioxide and cement hydration dissolution ingredient. In the near future, the cement industry is to switch to sustainable construction materials industry and it would be a higher value-added business.

키워드

과제정보

연구 과제 주관 기관 : 교육과학기술부, 한국연구재단

참고문헌

  1. C. S. Kang, J. S. Kwack, H. S. Lee, A Study on the Freezing of CO2 and the Production of CaCO3 by the Wet Carbonating Reaction of Cement-saturated Solution, ICETI, 2011
  2. 한국지질자원연구원, 광물탄산화법에 의한 이산화탄소 고정화 기반기술 연구, 지식경제부, 2009
  3. Klaus S. Lackner, A Guide to $CO_2$ Sequestration, 2003
  4. 안지환, 유강석, 폐콘크리트 미분말 및 무기 폐부산물을 이용한 $CO_2$고형화 방법, 한국자원리싸이클링학회, 2009
  5. 황정우, 이융, 이동현, 기포탑 반응기에서 반응 속도에 따른 침강성 탄산칼슘의 모폴로지 변화, 한국화학공학회, 2009
  6. 김형석 외 4인, 광물탄산화에 의한 $CO_2$ 고정화 기술, 한국광물학회, 2009
  7. 이한승 외 4인, $CO_2$ 배출량 및 흡수량을 중심으로 한 콘크리트의 친환경성능 평가에 관한 문헌적 연구, 한국콘크리트학회, 2006
  8. 안지환, 유강석, 폐콘크리트 미분말 및 무기 폐부산물을 이용한 $CO_2$고형화 방법, 한국자원리싸이클링학회, 2009
  9. 최진영, 이한승, 이상현, 경제운, 양내원, 이산화탄소 흡수량 정량분석을 통한 콘크리트의 친환경성능에 관한 실험적 연구, 한국생태환경건축학회, 2007
  10. Vagelis G. Papadakis, Michael N. Fardis and Costas G. Vayenas, Physical and Chemical characteristics affecting the durability of concrete, ACI Materials Journal, 1991
  11. Mihee Lim, Gi-chun Han, Ji-Whan Ahn, Kwang-Suk You, Environmental Remediation and Conversion of Carbon Dioxide ($CO_2$) into Useful Green Products by Accelerated Carbonation Technology, Journal of Environmental, 2010