Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Voltammetric Studies of Anion Transfer Reactions Across a Microhole Array-Water/PVC-NPOE Gel Interface

  • Hossain, Md. Mokarrom (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University) ;
  • Girault, Hubert H. (Laboratoire d'Electrochimie Physique et Analytique) ;
  • Lee, Hye-Jin (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
  • Received : 2011.12.18
  • Accepted : 2012.02.27
  • Published : 2012.05.20
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Abstract

Voltammetric characterization of hydrophilic anion transfer processes across a 66 microhole array interface between the water and polyvinylchloride-2-nitrophenyloctylether gel layer is demonstrated. Since the transfer of hydrophilic anions including $Br^-$, $NO_3{^-}$, $I^-$, $SCN^-$ and $ClO_4{^-}$ across the liquid/gel interface usually sets the potential window within a negative potential region, a highly hydrophobic organic electrolyte, tetraoctylammonium tetrakis(pentafluorophenyl)borate, providing a wider potential window was incorporated into the gel phase. The transfer reaction of perchlorate anions across the microhole-water/gel interface was first studied using cyclic voltammetry and differential pulse voltammetry. The full voltammetric response of perchlorate anion transfer was then used as a reference for evaluating the half-wave transfer potentials, the formal transfer potentials and the formal Gibbs transfer energies of more hydrophilic anions such as $Br^-$, $NO_3{^-}$, $I^-$, and $SCN^-$. The current response associated with the perchlorate anion transfer across the micro-water/gel interface versus the perchlorate concentration was also demonstrated for sensing applications.

Keywords

References

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