DOI QR코드

DOI QR Code

Model for simulating the effects of particle size distribution on the hydration process of cement

  • Chen, Changjiu (State Key Laboratory of Hydro science and Engineering, Tsinghua University) ;
  • An, Xuehui (State Key Laboratory of Hydro science and Engineering, Tsinghua University)
  • Received : 2010.11.04
  • Accepted : 2011.05.25
  • Published : 2012.03.25

Abstract

The hydration of cement contributes to the performance characteristics of concrete, such as strength and durability. In order to improve the utilization efficiency of cement and its early properties, the particle size distribution (PSD) of cement varies considerably, and the effects of the particle size distribution of cement on the hydration process should be considered. In order to evaluate effects of PSD separately, experiments testing the isothermal heat generated during the hydration of cements with different particle size distributions but the same chemical composition have been carried out. The measurable hydration depth for cement hydration was proposed and deduced based on the experimental results, and a PSD hydration model was developed in this paper for simulating the effects of particle size distribution on the hydration process of cement. First, a reference hydration rate was derived from the isothermal heat generated by the hydration of ordinary Portland cement. Then, the model was extended to take into account the effect of water-to-cement ratio, hereinafter which was referred to as PSD hydration model. Finally, the PSD hydration model was applied to simulate experiments measuring the isothermal heat generated by the hydration of cement with different particle size distributions at different water-to-cement ratios. This showed that the PSD hydration model had simulated the effects of particle size distribution and water-to-cement ratio on the hydration process of cement with satisfactory accuracy.

Keywords

References

  1. Arai, Y. (1984), "Chemistry of cement materials", Dai-nippon Tosho Publishing Co., Tokyo.
  2. Bentz, D.P. (1997), "Three-dimensional computer simulation of portland cement hydration and microstructure development", J. Am. Ceram. Soc., 80(1), 3-21. https://doi.org/10.1111/j.1151-2916.1997.tb02785.x
  3. Bentz, D.P. (2006), "Cement hydration: building bridges and dams at the microstructure level", Mater. Struct., 40(4), 397-404.
  4. Bentz, D.P., Garboczi, E.J., Haecker, C.J. and Jensen, O.M. (1999), "Effects of cement particle size distribution on performance properties of portland cement-based materials", Cement Concrete Res., 29(10), 1663-1671. https://doi.org/10.1016/S0008-8846(99)00163-5
  5. Bentz, D.P., Sant, G. and Weiss, W.J. (2008), "Early-age properties of cement-based materials-I: Influence of cement fineness", J. Mater. Civil Eng., 20(7), 502-508. https://doi.org/10.1061/(ASCE)0899-1561(2008)20:7(502)
  6. Bishnoi, S. and Scrivener, K.L. (2009), "${\mu}ic$: A new platform for modelling the hydration of cements", Cement Concrete Res., 39(4), 266-274. https://doi.org/10.1016/j.cemconres.2008.12.002
  7. Breugel, K.V. (1991), Simulation of hydration and formation of structure in hardening cement-based materials, PhD. thesis, Delft.
  8. Bullarda, J.W., Jenningsb, H.M., Livingstonc, R.A., George, W., Nonat, A., Jeffrey, S.S., Scrivenerg, K.L. and Thomash J.J. (2010), "Mechanisms of cement hydration", Cement Concrete Res., 41(12), 1208-1223.
  9. Celik, I.B. (2009). "The effects of particle size distribution and surface area upon cement strength development", Powder Technol., 188(3), 272-276. https://doi.org/10.1016/j.powtec.2008.05.007
  10. Cohen, M.D. (1981), PhD Dissertation, Stanford University, Stanford, California.
  11. Cohen, R.D. and Cohen, M.D. (1987), "Kinetics of depletion of a population of hydrating cement particles", J. Mater, Sci., 22(6), 2032-2036. https://doi.org/10.1007/BF01132935
  12. Feng Naiqian (2002), "The long-term performance of cement and concrete in bay and ocean structures", China Cement Concrete Products, 6, 11-14. (In Chinese)
  13. Frigioine, G. and Marra, S. (1976), "Relationship between particle size distribution and compressive strength in Portland cement", Cement Concrete Res., 6(1), 113-128. https://doi.org/10.1016/0008-8846(76)90056-9
  14. Knudsen, T. (1980), On particle size distribution in cement hydration, 7th int. conference on the chemistry of cement, Paris.
  15. Kondo, R. and Ueda, S. (1968), Kinetics and mechanisms of the hydraiton of cements, 5th int. Congress on the chemistry of cements, Tokyo.
  16. Lange, F., Mortel, H. and Rundert, V. (1997), "Dense packing of cement pastes and resulting consequences on mortar properties", Cement Concrete Res., 27(10), 1481-1488. https://doi.org/10.1016/S0008-8846(97)00189-0
  17. Maekawa K., Rajesh C. and Toshiharu, K. (1999), Modelling of concrete performance: hydration, microstructure formation and mass transport, E & FN Spon Press, London.
  18. Nagashima, M. (1992), "Hydration, setting and hardening", Cement Concrete, 544, 36-44.
  19. Odler Ivan (1998), Hydration, setting and hardening of Portland cement, in "Lea's chemistry of cement concrete (4th edition)", edit by Peter C. Hewlett, Reed Educational and Professional Publishing Ltd, London.
  20. Osbaeck, B. and Johansen, V. (1989), "Particle size distribution and rate of strength development of Portland cement", J. Am. Ceram. Soc., 72(2), 197-201. https://doi.org/10.1111/j.1151-2916.1989.tb06101.x
  21. Parrott, L.J. (1986), Modeling the development of microstructure, Proceedings of engineering foundation conference on research on manufacture and use of cements, Henniker, New York.
  22. Pommersheim, J.M. and Clifton, J.R. (1979), "Mathematical modeling of tricalcium silicate hydration", Cement Concrete Res., 9(6), 765-770. https://doi.org/10.1016/0008-8846(79)90072-3
  23. Pommersheim, J.M. and Clifton, J.R. (1982), "Mathematical modeling of tricalcium silicate hydration II. Submodels and the effect of model parameters", Cement Concrete Res., 12(6), 765-772. https://doi.org/10.1016/0008-8846(82)90040-0
  24. Pommersheim, J.M. and Clifton, J.R. (1986), "Kinetics of hydration of tricalcium aluminate", Cement Concrete Res., 16, 440. https://doi.org/10.1016/0008-8846(86)90120-1
  25. Powers, T.C. (1962), Physical properties of cement paste, Proceedings of the fourth international conference on the chemistry of cement, Washington, D.C.
  26. Qiao Lingshan (2004), "Effects of particle size distribution on cement's strength", Cement, 1, 1-6. (In Chinese)
  27. Shen Wei, Huang Wenxi and Min Panrong (1991), Cement technology, Wuhan University of Technology Press, Wuhan. (In Chinese)
  28. Sprung, S., Kuhlmann, K. and Ellerbrock, H.G. (1985), "Particle size distribution and properties of cement, Part II: water demand of Portland cement", ZKG Int., 9, 275-281.
  29. Suzuki, Y., Tsuji, Y., Maekawa, K. and Okamura, H. (1990), "Quantification of hydration-heat generation process of cement in concrete", Concrete Libr. JSCE, 16, 111-124.
  30. Taplin, J.H. (1968), Kinetics and mechanisms of the hydration of cements (Discussion), 5th int. Congress on the chemistry of cements, Tokyo.
  31. Taylor, H.F.W. (1997), Cement Chemistry (2d edition), Thomas Telford, London.
  32. Zhao Fei, Feng Xiuji (1992), "The effect of the particle size on the hydration and strength of cement", Bull. Chinese Ceram. Soc. Bull., 4, 10-14. (In Chinese)

Cited by

  1. Prediction of temperature distribution in hardening silica fume-blended concrete vol.13, pp.1, 2014, https://doi.org/10.12989/cac.2014.13.1.097