DOI QR코드

DOI QR Code

Preparation and characterization of nanoflake composite multi core-shell SrFe12O19/Fe3O4/PEG/PPy

  • Received : 2012.04.24
  • Accepted : 2012.06.24
  • Published : 2012.06.25

Abstract

Nanoflake composite multi core-shell $SrFe_{12}O_{19}/Fe_3O_4$/PEG/Polypyrrole was synthesized by in situ polymerization method. In this paper, the fabrication of $SrFe_{12}O_{19}$ nanoflake is as first core by solgel method. Then fabricated a shell layer from magnetic nanoparticles of $Fe_3O_4$, which synthesized by coprecipitation technique, onto the $SrFe_{12}O_{19}$ nanoflake. Polyethylene glycol (PEG) as a polymer layer and as second shell was coated onto the before core-shell. Than core-shell $SrFe_{12}O_{19}/Fe_3O_4$/PEG was used as template for the preparation of $SrFe_{12}O_{19}/Fe_3O_4$/PEG/Polypyrrole composite. Final composite has a conductive property among $4.23{\times}10^{-2}Scm^{-1}$ and magnetic property about $M_s$=2.99 emu/g. Also final composite in soluble at organic solvent such as DMF and DMSO and has a flake structure. Conductivity and magnetic property respectively determine by four-probe instrument and vibrant sample magnetometer (VSM), morphology and article size determined by FE-SEM, TEM and XRD.

Keywords

References

  1. Bereznev, S., Konovalov, I., Opik, A., Kois, J. and Mellikov, E. (2005), "Hybrid copper-indium disulfide/polypyrrole photovoltaic structures prepared by electrodeposition", Sol. Energ. Mat. Sol. C., 87(1-4), 197-206. https://doi.org/10.1016/j.solmat.2004.07.023
  2. Fu, W., Yang, H., Yu, Q., Xu, J., Pang, X. and Zou, G. (2007), "Preparation and magnetic properties of $SrFe_{12}O_{19}/SiO_2$ nanocomposites with core-shell structure", Mater. Lett., 61(11-12), 2187-2190. https://doi.org/10.1016/j.matlet.2006.08.059
  3. Hosseini, S.H., Mohseni, S.H., Asadnia, A. and Kerdari, H. (2010), "Synthesis and microwave absorbing properties of polyaniline/$MnFe_2O_4$ nanocomposite", J. Alloy. Comp., 509(14), 4682-4687.
  4. Li, Q., Zhang, C., Wang, Y. and Li, B. (2009), "Preparation and characterization of flake-like polypyrrole/$SrFe_{12}O_{19}$ composites with different surface active agents", Synthetic Met., 159(19-20), 2029-2033. https://doi.org/10.1016/j.synthmet.2009.07.025
  5. Ni, S., Lin, S., Pan, Q., Yang, F., Huang, K., Wang, X. and He, D. (2009), "Synthesis of core-shell ${\acute{a}}-Fe_2O_3$ hollow micro-spheres by a simple two-step process", J. Alloy. Comp., 478(1-2), 876-879. https://doi.org/10.1016/j.jallcom.2008.12.038
  6. Pan, F., Cheng, Q., Jia, H. and Jiang, Z. (2010), "Facile approach to polymer-inorganic nanocomposite membrane through a bio mineralization-inspired process", J. Membrane Sci., 357(1-2), 171-177. https://doi.org/10.1016/j.memsci.2010.04.017
  7. Phang, S.W., Tadokoro, M., Watanabe, J. and Kuramoto, N. (2008), "Microwave absorption behaviors of polyaniline nanocomposites containing $TiO_2$ nanoparticles", Curr. Appl. Phys., 8(3-4), 391-394. https://doi.org/10.1016/j.cap.2007.10.022
  8. Singh, K., Ohlan, A., Bakhshi, A.K. and Dhawan, S.K. (2010), "Synthesis of conducting ferromagnetic nanocomposite with improved microwave absorption properties", Mater. Chem. Phys., 119(1-2), 201-207. https://doi.org/10.1016/j.matchemphys.2009.08.060
  9. Wu, J., Li, Q., Fan, L., Lan, Z., Li, P., Lin, J. and Hao, S. (2008), "High-performance polypyrrole nanoparticles counter electrode for dye-sensitized solar cells", J. Power Sources, 181(1), 172-176. https://doi.org/10.1016/j.jpowsour.2008.03.029
  10. Yuvaraj, H., Woo, M.H., Park, E.J., Jeong, Y.T. and Lim, K.T. (2008), "Polypyrrole/${\gamma}-Fe_2O_3$ magnetic nanocomposites synthesized in supercritical fluid", Eur. Polym. J., 44(3), 637-644. https://doi.org/10.1016/j.eurpolymj.2008.01.007
  11. Zhang, L., Wang, W., Zhou, L., Shang, M. and Sun, S. (2009), "$Fe_3O_4$ coupled BiOCl: A highly efficient magnetic photocatalyst", Appl. Catal. B.-Environ., 90(3-4), 458-462. https://doi.org/10.1016/j.apcatb.2009.04.005
  12. Zhang, Z., Li, Q. and Ye, I. (2009), "Preparation and characterization of polypyrrole/nano-$SrFe_{12}O_{19}$ composites by in situ polymerization method", Synthetic Met., 159(11), 1008-1013. https://doi.org/10.1016/j.synthmet.2009.01.013

Cited by

  1. Preparation of nanofiber polythiophene layered on Ba x Sr1−x Fe12O19/Fe3O4/polyacrylic acid core–shell structure and its microwave absorption investigation vol.120, pp.3, 2015, https://doi.org/10.1007/s00339-015-9296-8
  2. Preparation of magnetic and conductive graphite nanoflakes/SrFe12O19/polythiophene nanofiber-nanocomposites and its radar absorbing application vol.17, pp.4, 2016, https://doi.org/10.1007/s12221-016-5669-7