Advances in environmental research

  • 제1권2호
  • /
  • Pages.167-179
  • /
  • 2012
  • /
  • 2234-1722(pISSN)
  • /
  • 2234-1730(eISSN)
테크노프레스 (Techno-Press)
권호 표지
DOI QR코드

DOI QR Code

Removal of hexavalent chromium using modified pistachio shell

  • Parlayici-Karatas, S. (Department of Chemical Engineering, Selcuk University) ;
  • Pehlivan, E. (Department of Chemical Engineering, Selcuk University)
  • 투고 : 2012.05.06
  • 심사 : 2012.08.07
  • 발행 : 2012.06.25
⟨ 이전 논문 다음 논문 ⟩

초록

Pistachio shell (Pistacia vera) (PS), a low-cost material, has been utilized for the removal of the Cr(VI) ions after treatment with citric acid. Batch experimental steps were applied to obtain Cr(VI) ion adsorption details for the equilibrium between Cr(VI) and modified pistachio shell (MPS). The influences of contact time, pH, adsorbent dose and initial chromium concentration on the adsorption performance of MPS was investigated in detail. The results displayed that adsorption of Cr(VI) by MPS reached to equilibrium after 2 h and after that a little change of Cr(VI) removal efficiency was observed. The sorption percent is higher at lower pH and lower chromium concentration. Two possible mechanisms for reduction of Cr(VI) to Cr(III) can be suggested in Cr(VI) removal. In the first mechanism, Cr(VI) is reduced to Cr(III) by surface electron-donor groups of the adsorbent and the reduced Cr(III) forms complexes with adsorbent or remains in the solution. This Cr(III) is not adsorbed by adsorbent at pH 1.8. But in second mechanism, the adsorption-coupled reduction of Cr(VI) to Cr(III) occurred on the adsorbent sites. The equilibrium sorption capacity of Cr(VI) ion after 2 h was 64.35 mg/g for MPS.

키워드

참고문헌

  1. Altun, T. and Pehlivan, E. (2012), "Removal of Cr(VI) from aqueous solutions by modified walnut shells", Food Chem., 132, 693-700. https://doi.org/10.1016/j.foodchem.2011.10.099
  2. Apaydin-Varol, E., Putun, E. and Putun, E.A. (2007), "Slow pyrolysis of pistachioshell", Fuel, 86(12-13), 1892-1899. https://doi.org/10.1016/j.fuel.2006.11.041
  3. Arslan, G. and Pehlivan, E. (2007), "Batch removal of Cr(VI) from aqueous solution by Turkish Brown coals", Bioresource Technol., 98(15), 2836-2845. https://doi.org/10.1016/j.biortech.2006.09.041
  4. Aoyama, M. and Tsuda, M. (2001), "Removal of Cr(VI) from aqueous solutions by larch bark", Wood Sci. Technol., 35(5), 425-434. https://doi.org/10.1007/s002260100103
  5. Blazquez, G., Hernainz, F., Calero, M., Martin-Lara, M.A. and Tenorio, G. (2009), "The effect of pH on the biosorption of Cr(III) and Cr(VI) with olive stone", Chem. Eng. J., 148(2-3), 473-479. https://doi.org/10.1016/j.cej.2008.09.026
  6. Chong, K.H. and Volesky, B. (1995), "Description of two metal biosorption equilibria by Langmuir-type models", Biotechnol. Bioeng., 47(4), 451-460. https://doi.org/10.1002/bit.260470406
  7. Chen, J.P. and Lim, L.L. (2002), "Key factors in chemical reduction by hydrazine for recovery of precious metals", Chemosphere, 49(4), 363-370. https://doi.org/10.1016/S0045-6535(02)00305-3
  8. Dakiky, M., Khamis, M., Manassra, A. and Mer'eb, M. (2002), "Selective adsorption of chromium VI in industrial wastewater using low-cost abundantly available adsorbents", Adv. Environ. Res., 6(4), 533-540. https://doi.org/10.1016/S1093-0191(01)00079-X
  9. Demirbas, E., Kobya, M. and Konukman, A.E.S. (2008), "Error analysis of equilibrium studies for the almond shell activated carbon adsorption of Cr(VI) from aqueous solution", J. Hazard. Mater., 154(1-3), 787-794. https://doi.org/10.1016/j.jhazmat.2007.10.094
  10. Donmez, G. and Aksu, Z. (2002), "Removal of chromium (VI) from saline wastewaters by Dunaliella species", Process Biochem., 38(5), 751-762. https://doi.org/10.1016/S0032-9592(02)00204-2
  11. Fiol, N., Villaescusa, I., Martinez, M., Miralles, N., Poch, J. and Serarols, J. (2003), "Bioadsorption of Cr(VI) using low cost sorbents", Environ. Chem. Lett., 1(2), 135-139. https://doi.org/10.1007/s10311-003-0027-6
  12. Gupta, V.K., Shrivastava, A.K. and Jain, N. (2001), "Biosorption of chromium (VI) from aqueous solutions by green algae Spirogyra species", Water Res., 35(17), 4079-4085. https://doi.org/10.1016/S0043-1354(01)00138-5
  13. Hashem, A., Abdel-Halim, E.S., El-Tahlawy, K.F. and Hebeish, A. (2005), "Enhancement of adsorption of Co(II) and Ni(II) ions onto peanut hulls though esterification using citric acid", Adsorpt. Sci. Technol., 23(5), 367-380. https://doi.org/10.1260/026361705774355478
  14. Jain, M., Garg, V.K. and Kadirvelu, K. (2010), "Adsorption of hexavalent chromium from aqueous medium onto carbonaceous adsorbents prepared from waste biomass", J. Environ. Manage., 91(4), 949-957. https://doi.org/10.1016/j.jenvman.2009.12.002
  15. Karthikeyan, T., Rajgopal, S. and Miranda, L.R. (2005), "Chromium (VI) adsorption from aqueous solution by Hevea Brasilinesis sawdust activated carbon", J. Hazard. Mater., 124(1-3), 192-199. https://doi.org/10.1016/j.jhazmat.2005.05.003
  16. Kobya, M. (2004), "Adsorption, kinetic and equilibrium studies of Cr (VI) by hazelnut shell activated carbon", Adsorpt. Sci. Technol., 22(1), 51-64. https://doi.org/10.1260/026361704323150999
  17. Kohler, S.J., Cubillas, P., Rodriguez-Blanco, J.D., Bauer, C. and Prieto, M. (2007), "Removal of cadmium from wastewaters by aragonite shells and the influence of other divalent cations", Environ. Sci. Technol., 41(1), 112-118. https://doi.org/10.1021/es060756j
  18. Low, K.S., Lee, C.K. and Mak, S.M. (2004), "Sorption of copper and lead by citric acid modified wood", Wood Sci. Technol., 38(8), 629-640. https://doi.org/10.1007/s00226-003-0201-9
  19. Marshall, W.E., Chatters, A.Z., Wartelle, L.H. and McAloon, A. (2001), "Optimization and estimated production cost of a citric acid-modified soybean hull ion exchanger", Ind. Crop. Prod., 14(3), 191-199. https://doi.org/10.1016/S0926-6690(01)00084-X
  20. Marshall, W.E. and Wartella, L.H. (2003), "Acid recycling to optimize citric acid-modified soybean hull production", Ind. Crop. Prod., 18(2), 177-182. https://doi.org/10.1016/S0926-6690(03)00060-8
  21. Ozsin, G. (2011), "Production and characterization of activated carbon from pistachio-nut shell", MSc Thesis, Natural and Applied Sciences of the Middle East Technical University, Turkey.
  22. Park, D., Yun, Y. S. and Park, J.M. (2005a), "Studies on hexavalent chromium biosorption by chemically-treated biomass of Ecklonia sp.", Chemosphere, 60(10), 1356-1364. https://doi.org/10.1016/j.chemosphere.2005.02.020
  23. Park, D., Yun, Y.S., Jo, J.H. and Park, J.M. (2005b), "Mechanism of hexavalent chromium removal by dead fungal biomass of Aspergillus niger", Water Res., 39(4), 533-540. https://doi.org/10.1016/j.watres.2004.11.002
  24. Park, D., Yun, Y., Jo, J.H. and Park, J.M. (2006), "Biosorption process for treatment of electroplating wastewater containing Cr (VI): laboratory-scale feasibility test", Ind. Eng. Chem. Res., 45(14), 5059-5065. https://doi.org/10.1021/ie060002d
  25. Pehlivan, E. and Altun, T. (2008), "Bioadsorption of chromium(VI) ion from aqueous solutions using walnut, hazelnut and almond shell", J. Hazard. Mater., 155(1-2), 378-384. https://doi.org/10.1016/j.jhazmat.2007.11.071
  26. Pehlivan, E., Pehlivan, E. and Kahraman, H. (2012), "Hexavalent chromium removal by Osage Orange", Food Chem., 133(4), 1478-1484. https://doi.org/10.1016/j.foodchem.2012.02.037
  27. Semerjian, L. (2010), "Equilibrium and kinetics of cadmium adsorption from aqueous solutions using untreated Pinus halepensis sawdust", J. Hazard. Mater., 173(1-3), 236-242. https://doi.org/10.1016/j.jhazmat.2009.08.074
  28. Qureshi, I., Memon, S. and Yilmaz, M. (2009), "Estimation of chromium(VI) adsorption efficiency of novel regenerable p-tert-butylcalix[8]areneoctamide impregnated Amberlite XAD-4 Resin", J. Hazard. Mater., 164(2-3), 675-682. https://doi.org/10.1016/j.jhazmat.2008.08.076
  29. Verma, A., Chakraborty, S. and Basu, J.K. (2006), "Adsorption study of hexavalent chromium using tamarind hull-based adsorbents", Sep. Purif. Technol., 50(3), 336-341. https://doi.org/10.1016/j.seppur.2005.12.007
  30. Volesky, B. (1990), "Removal and recovery of heavy metals by biosorption, in: B. Volesky (Edition), Biosorption of Heavy Metals", CRC Press, Inc., Boca Raton, FL, USA.
  31. Wang, X.S., Li, Z.Z. and Tao, S.R. (2009), "Removal of chromium (VI) from aqueous solution using walnut hull", J. Environ. Manage., 90(2), 721-729. https://doi.org/10.1016/j.jenvman.2008.01.011
  32. Yeganeh, M.M., Kaghazchi, T., Soleimani, M. (2006), "Effect of raw materials on properties of activated carbons", Chem. Eng. Technol., 29(10), 1247-1251. https://doi.org/10.1002/ceat.200500298
  33. Zhu, B., Fan, T. and Zhang, D. (2008), "Adsorption of copper ions from aqueous solution by citric acid modified soybean straw", J. Hazard. Mater., 153(1-2), 300-308. https://doi.org/10.1016/j.jhazmat.2007.08.050
  34. Zinkus, G.A., Byers, W.D. and Doerr W.W. (1998), "Identify appropriate water reclamation technologies", Chem. Eng. Prog., 94(5), 19-31.
  35. Zouboulis, A.I., Kydros, K.A. and Matis, K.A. (1995), "Removal of hexavalent chromium anions from solutions by pyrite fines", Water Res., 29(7), 1755-1760. https://doi.org/10.1016/0043-1354(94)00319-3

피인용 문헌

  1. Valorization of swine manure into low cost activated carbons capable of Cr(VI) removal vol.6, pp.2, 2012, https://doi.org/10.12989/aer.2017.6.2.095