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Korean Carbon Society (한국탄소학회)
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A New Model and Equation Derived From Surface Tension and Cohesive Energy Density of Coagulation Bath Solvents for Effective Precipitation Polymerization of Acrylonitrile

  • Zhou, You (State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology) ;
  • Xue, Liwei (State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology) ;
  • Yi, Kai (State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology) ;
  • Zhang, Li (State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology) ;
  • Ryu, Seung Kon (Jeonju Institute of Machinery and Carbon Composites) ;
  • Jin, Ri Guang (State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology)
  • Received : 2012.05.21
  • Accepted : 2012.06.05
  • Published : 2012.07.31
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Abstract

A new model and resultant equation for the coagulation of acrylonitrile monomers in precipitation polymerization are suggested in consideration of the surface tension (${\gamma}$) and cohesive energy density ($E_{CED}$). The equation was proven to be quite favorable by considering figure fittings from known surface tensions and cohesive energy densities of certain organic solvents. The relationship between scale value of surface tension (${\gamma}$/M) and cohesive energy density of monomers can be obtained by changing the coagulation bath component for effective precipitation polymerization of acrylonitrile in wet spinning.

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References

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