Journal of the Korean Society of Safety (한국안전학회지)

The Korean Society of Safety (한국안전학회)
권호 표지
DOI QR코드

DOI QR Code

Characteristics of Thermal Hazard in Methylthioisocyanate Synthesis Reaction Process

Methylthioisocyanate 합성반응 공정의 열적위험 특성

  • Han, In-Soo (Occupational Safety and Health Research Institute, KOSHA) ;
  • Lee, Keun-Won (Occupational Safety and Health Research Institute, KOSHA) ;
  • Lee, Joo-Yeob (Center for Chemical Accident Prevention, KOSHA)
  • 한인수 (한국산업안전보건공단 산업안전보건연구원) ;
  • 이근원 (한국산업안전보건공단 산업안전보건연구원) ;
  • 이주엽 (한국산업안전보건공단 경인지역본부)
  • Received : 2012.06.29
  • Accepted : 2012.10.04
  • Published : 2012.10.31
Download PDF
⟨ Previous Next ⟩

Abstract

Compared to a batch reactor, where all reactants are initially charged to the reactor, the semi-batch reactor presents serious advantages. The feed of at least one of the reactants provides an additional way of controlling the reaction course, which represents a safety factor and increases the constancy of the product quality. The aim of this study was to investigate the characteristics of thermal hazard such as a feed time, catalysis concentration and solvent concentration in methylthioisocyanate(MTI) synthesis reaction process. The experiments were carried out by the Multimax reactor system and Accelerating rate calorimeter(ARC). The MTI synthesis reaction process has many reaction factors and complicated reaction mechanism of multiphase reaction. Through this study, we can use as a tool for assessment of thermal hazard of other reaction processes by applying experiment method provided.

Keywords

References

  1. Francis Stoessel. Thermal safety of chemical processes, WILET-VCH Verlag CmbH & Co. KGaA, Weinheim; 2008.
  2. 이근원 등, "Multimax Reactor System을 이용한 안료제조시 중화공정의 열적위험성평가", 한국안전학회지, 23권, 6호, pp. 91-94, 2008.
  3. K. R. Westerterp and E. J. Molga, "Safety and Runaway Prevention in Batch and Semibatch Reactors - A Review", Chemical Engineering Research & Design. Vol. 84, Issue 7, pp. 543-552, 2006. https://doi.org/10.1205/cherd.05221
  4. 이근원 등, "시멘트 혼화제 제조시 에스테르화공정의 열 안정성 평가", 한국안전학회지, 24권, 4호, pp. 40-46, 2009.
  5. 이영순, "회분식 반응기의 사고예방 모델 개발", 연구원 2003-47-431, 한국산업안전공단 산업안전보건연구원, 2003.
  6. 김관응, "화학반응공정의 반응인자 및 열 거동 평가(I)", 연구원2005-95-567, 한국산업안전공단 산업안전보건연구원, 2005.
  7. 이근원, "회분식 공정에서의 발열반응에 의한 열적․반응 안전성 평가", 연구원 2008-131-1458, 한국산업안전공단 산업안전보건연구원, 2008.
  8. 이근원, "열량계를 이용한 화학제품 제조업의 폭주반응 위험성 평가", 연구원 2009-99-1309, 한국산업안전보건공단 산업안전보건연구원, 2009.
  9. 이근원, "화학반응공정에서 열적위험성 평가 기술 개발, 2010-연구원-1037, 한국산업안전보건공단 산업안전보건연구원, 2010.
  10. Andreas Zogg, Francis Stoessel, Ulrich Fischer, Konrad Hungerbuhler, "Isothermal Reaction Calorimetry as a Tool for Kinetic Analysis", Thermochimica Acta, Vol. 419, pp. 1-17, 2004. https://doi.org/10.1016/j.tca.2004.01.015
  11. O. Ubrich, B. Srinivasan, P. Lerena, D. Bonvin, F. Stoessel, "The Use of Calorimetry for On-line Optimization of Isothermal Semi-batch Reactors" Chemical Engineering Science, Vol. 56, pp. 5147-5156, 2001. https://doi.org/10.1016/S0009-2509(01)00183-X
  12. Francis Stoessel, "Planning Protection Measures Against Runaway Reactions using Criticality Classes", Process Safety and Environmental Protection, Vol. 87, pp. 105-112, 2009. https://doi.org/10.1016/j.psep.2008.08.003