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Enhancement of Stability in Soluble Acene Thin-film Transistors by Using Polymer/Inorganic Hybrid Gate-dielectrics

고분자/무기 하이브리드 절연막을 이용한 용액공정용 저분자 박막트랜지스터의 안정성 향상 연구

  • Lee, Wi Hyoung (Department of Textile Engineering, Konkuk University)
  • 이위형 (건국대학교 섬유공학과)
  • Received : 2012.10.13
  • Accepted : 2012.12.09
  • Published : 2012.12.31

Abstract

Solution-processed small molecular semiconductors (soluble acenes) serve as ideal active materials for high-performance, printed organic thin-film transistors (OTFTs). However, device stability of soluble acene TFTs has not been intensively studied. Here, we showed that device stability of soluble acene TFTs can be significantly enhanced by the use of polymer/inorganic hybrid gate-dielectrics. Triethylsilylethynyl-anthradithiophene (TES-ADT) TFTs fabricated on polystyrene (PS)/$Al_2O_3$ hybrid gate dielectrics exhibited high performance such as high field-effect mobility ($0.6cm^2/Vs$) and on-off current ratio ($10^6$). In addition, transfer characteristic of the TFTs did not shift under the prolonged gate-bias (8000s). This outstanding device stability is due to the device structure which consists of highly crystalline TES-ADT crystals and trap-free PS/$Al_2O_3$ dielectric.

Keywords

Acknowledgement

Supported by : 건국대학교

References

  1. J. E. Anthony, J. S. Brooks, D. L. Eaton, and S. R. Parkin, “Functionalized Pentacene: Improved Electronic Properties from Control of Solid-state Order”, J Am Chem Soc, 2001, 123, 9482-9483. https://doi.org/10.1021/ja0162459
  2. M. M. Payne, S. R. Parkin, J. E. Anthony, C. C. Kuo, and T. N. Jackson, “Organic Field-effect Transistors from Solutiondeposited Functionalized Acenes with Mobilities as High as 1 cm(2)/V-s”, J Am Chem Soc, 2005, 127, 4986-4987. https://doi.org/10.1021/ja042353u
  3. S. Allard, M. Forster, B. Souharce, H. Thiem, and U. Scherf, “Organic Semiconductors for Solution-processable Fieldeffect Transistors (OFETs)”, Angew Chem Int Ed, 2008, 47, 4070-4098. https://doi.org/10.1002/anie.200701920
  4. D. H. Kim, D. Y. Lee, H. S. Lee, W. H. Lee, Y. H. Kim, J. I. Han, and K. Cho, “High-mobility Organic Transistors Based on Single-crystalline Microribbons of Triisopropylisilylethynl Pentacene via Solution-phase Self-assembly”, Adv Mater, 2007, 19, 678-682. https://doi.org/10.1002/adma.200601259
  5. J. A. Lim, H. S. Lee, W. H. Lee, and K. Cho, “Control of the Morphology and Structural Development of Solution- Processed Functionalized Acenes for High-Performance Organic Transistors”, Adv Funct Mater, 2009, 19, 1515- 1525. https://doi.org/10.1002/adfm.200801135
  6. W. H. Lee, J. A. Lim, D. H. Kim, J. H. Cho, Y. Jang, Y. H. Kim, J. I. Han, and K. Cho, “Room-temperature Selforganizing Characteristics of Soluble Acene Field-effect Transistors”, Adv Funct Mater, 2008, 18, 560-565. https://doi.org/10.1002/adfm.200701087
  7. W. H. Lee, D. H. Kim, Y. Jang, J. H. Cho, M. Hwang, Y. D. Park, Y. H. Kim, J. I. Han, and K. Cho, “Solution-processable Pentacene Microcrystal Arrays for High Performance Organic Field-effect Transistors”, Appl Phys Lett, 2007, 90, 132106-132108. https://doi.org/10.1063/1.2717087
  8. K. C. Dickey, J. E. Anthony, and Y.-L. Loo, “Improving Organic Thin-film Transistor Performance Through Solventvapor Annealing of Solution-processable Triethylsilylethynyl Anthradithiophene”, Adv Mater, 2006, 18, 1721-1726. https://doi.org/10.1002/adma.200600188
  9. W. H. Lee, J. A. Lim, D. Kwak, J. H. Cho, H. S. Lee, H. H. Choi, and K. Cho, “Semiconductor-Dielectric Blends: A Facile All Solution Route to Flexible All-Organic Transistors”, Adv Mater, 2009, 21, 4243-4248. https://doi.org/10.1002/adma.200900277
  10. H. Sirringhaus, “Device Physics of Solution-processed Organic Field-effect Transistors”, Adv Mater, 2005, 17, 2411-2425. https://doi.org/10.1002/adma.200501152
  11. S. J. Zilker, C. Detcheverry, E. Cantatore, and D. M. de Leeuw, “Bias Stress in Organic Thin-film Transistors and Logic Gates”, Appl Phys Lett, 2001, 79, 1124-1126. https://doi.org/10.1063/1.1394718
  12. M. Tello, M. Chiesa, C. M. Duffy, and H. Sirringhaus, “Charge Trapping in Intergrain Regions of Pentacene Thin Film Transistors”, Adv Funct Mater, 2008, 18, 3907-3913. https://doi.org/10.1002/adfm.200800009
  13. D. B. Rep, A. F. Morpurgo, W. G. Sloof, and T. M. Klapwijk, “Mobile Ionic Impurities in Organic Semiconductors”, J Appl Phys, 2003, 93, 2082-2090. https://doi.org/10.1063/1.1538338