DOI QR코드

DOI QR Code

Antimicrobial Properties of PET/(Nano-TiO2) Composite Films Prepared by Photocatalytic Deposition of Silver

나노 은을 광증착시킨 폴리(에틸렌 테레프탈레이트)/나노-TiO2 복합체의 항균특성 연구

  • Jo, Seong-Min (Department of Materials Design Engineering, Kumoh National Institute of Technology) ;
  • Jhee, Kwang Hwan (Department of Applied Chemistry, Kumoh National Institute of Technology) ;
  • Kim, Jung Hyun (Department of Applied Chemistry, Kumoh National Institute of Technology) ;
  • Kwon, Oh Kyung (B.S.G. Co.) ;
  • Lim, Sang Kyoo (Daegu Gyeongbuk Institute of Science and Technology) ;
  • Min, Byung Gil (Department of Materials Design Engineering, Kumoh National Institute of Technology)
  • 조성민 (금오공과대학교 소재디자인공학과) ;
  • 지광환 (금오공과대학교 응용화학과) ;
  • 김정현 (금오공과대학교 응용화학과) ;
  • 권오경 ((주)비에스지) ;
  • 임상규 (대구경북과학기술원) ;
  • 민병길 (금오공과대학교 소재디자인공학과)
  • Received : 2012.11.08
  • Accepted : 2012.12.02
  • Published : 2012.12.31

Abstract

Nanocomposite films of poly(ethylene terephthalate)(PET) and nano titania($TiO_2$) were prepared by melt compounding with a twin-screw extruder followed by hot pressing for the purpose of investigating antibacterial activity. FE-SEM, EDS and XRD measurements confirmed that nano $TiO_2$ was successfully dispersed at the level of individual particles in the PET matrix. Silver was introduced through photocatalytic reduction by nano $TiO_2$ under UV (254 nm) irradiation to the nanocomposite films after being immersed in aqueous solution $AgNO_3$ (100 ppm Ag ion). Even at 1 wt% of $TiO_2$ content, the nanocomposite with silver photodeposition exhibited strong antimicrobial activity against Klebsiella pneumoniae and Staphylococcus aureus in measurement by shaking flask method.

Keywords

Acknowledgement

Supported by : 금오공과대학교

References

  1. H. C. Cha and Y. H. Kim, "Dyeing Properties and Antibacterial Activities of Sulfadiazine Type Reactive Dyes", Text Sci Eng, 2008, 45(4), 214-219.
  2. D. S. Dimitrov, “Interactions of Antibody-conjugated Nanoparticles with Biological Surfaces”, Coll and Surf A, 2006, 282-283, 8-10. https://doi.org/10.1016/j.colsurfa.2005.11.001
  3. R. Dastjerdi and M. Montazer, “A Review on the Application of Inorganic Nano-structured Materials in the Modification of Textiles: Focus on Anti-microbial Properties”, Coll and Surf B, 2010, 79, 5-18. https://doi.org/10.1016/j.colsurfb.2010.03.029
  4. G. Fu, P. Vary, and C. T. Lin, "Anatase $TiO_{2}$ Nanocomposites for Antimicrobial Coatings", J Phys Chem, 2005, B109(18), 8889-8898.
  5. H. S. Bae, M. K. Lee, W. W. Kim, and C. K. Rhee, "Dispersion Properties of $TiO_{2}$ Nano-powder Synthesized by Homogeneous Precipitation Process at Low Temperatures", Coll and Surf A, 2003, 220, 169-177. https://doi.org/10.1016/S0927-7757(03)00077-3
  6. Y. Dong, Z. Bai, L. Zhang, R. Liu, and T. Zhu, "Finishing of Cotton Fabrics with Aqueous Nano-titanium Dioxide Dispersion and the Decomposition of Gaseous Ammonia by Ultraviolet Irradiation", J Appl Polym Sci, 2006, 99, 286-291. https://doi.org/10.1002/app.22476
  7. M. J. Uddin, F. Cesano, F. Bonino, S. G. Bordiga, D. Spoto, A. Scarano, and A. Zecchina, "Photoactive $TiO_{2}$ Films on Cellulose Fibres: Synthesis and Characterization", J Photochem Photobio A, 2007, 189, 286-294. https://doi.org/10.1016/j.jphotochem.2007.02.015
  8. T. Y. Tan, C. K. Yip, D. Beydoun, and R. Amal, "Effects of Nano-Ag Particles Loading on $TiO_{2}$ Photocatalytic Reduction of Selenate Ions", Chem Eng J, 2003, 95, 179-186. https://doi.org/10.1016/S1385-8947(03)00103-7
  9. M. Stamate and G. Lazar, "Application of Titanium Dioxide Photocatalysis to create Self-cleaning Materials", Rom Tech Sci Acad, 3, 2007, 280-285.
  10. H. Wang, J. Niu, X. Long, and Y. He, "Sonophotocatalytic Degradation of Methyl Orange by Nano-sized Ag/$TiO_{2}$ Particles in Aqueous Solutions", Ultrasonics Sonochem, 2008, 15, 386-392. https://doi.org/10.1016/j.ultsonch.2007.09.011
  11. K. Han and M. Yu, "Study of the Preparation and Properties of UV-blocking Fabrics of a PET/$TiO_{2}$ Nanocomposite Prepared by in situ Polycondensation", J Appl Polym Sci, 2006, 100, 1588-1593. https://doi.org/10.1002/app.23312
  12. S. Ikezawa, H. Homyara, T. Kubota, R. Suzuki, S. Koh, F. Mutuga, T. Yoshioka, A. Nishiwaki, Y. Ninomiya, M. Takahashi, K. Baba, K. Kida, T. Hara, and T. Famakinwa, "Applications of $TiO_{2}$ Film for Environmental Purification Deposited by Controlled Electron Beam-excited Plasma", Thin Solid Films, 2001, 386, 173-176. https://doi.org/10.1016/S0040-6090(00)01638-2
  13. D. J. Reidy, J. D. Holmes, and M. A. Morris, "Preparation of a Highly Thermally Stable Titania Anatase Phase by Addition of Mixed Zirconia and Silica Dopants", Ceram Int, 32 (2006) 235-239. https://doi.org/10.1016/j.ceramint.2005.02.009
  14. J. Jang and J.-A. Son, "Nano $TiO_{2}$ Coating of PET Fabrics by Sol-Gel Processing", Text Sci Eng, 2008, 45(4), 239-246.
  15. S. K. Lim, S.-K. Lee, S.-H. Hwang, and H. Kim, “Photocatalytic Deposition of Silver Nanoparticles onto Organic/Inorganic Composite Nanofibers”, Macromol Mater Eng, 2006, 291, 1265-1270 https://doi.org/10.1002/mame.200600264
  16. D. G. Yu, “Formation of Colloidal Silver Nanoparticles Stabilized by Na+poly(-glutamic acid)-silver Nitrate Complex Via Chemical Reduction Process”, Coll and Surf B, 2007, 59, 171-178. https://doi.org/10.1016/j.colsurfb.2007.05.007
  17. C. Nam, Y. H. Kim, and S. Ko, “Blend Fibers of Polyacrylonitrile and Water-soluble Chitosan Derivative Prepared from Sodium Thiocyanate Solution”, J Appl Polym Sci, 2001, 82, 1620-1629. https://doi.org/10.1002/app.2001
  18. W. Chen and D. D. Dionysiou, "$TiO_{2}$ Photocatalytic Films on Stainless Steel: The Role of Degussa P-25 in Modified Sol-gel Methods", Appl Catalyst B, 2006, 62, 255-264. https://doi.org/10.1016/j.apcatb.2005.07.017

Cited by

  1. Preparation and Antimicrobial Properties of Nylon 6/Nano-TiO2Nanohybrids vol.51, pp.4, 2014, https://doi.org/10.12772/TSE.2014.51.193