Experimental Study on Effects of Syngas Addition in Flame Propagation and Stability of DME-Air Premixed Flames

디메틸에테르-공기 예혼합화염의 화염전파와 화염안정성에 있어서 합성가스의 첨가효과에 관한 실험적 연구

  • 송원식 (부경대학교 기계공학과) ;
  • 박정 (부경대학교 기계공학과) ;
  • 권오붕 (부경대학교 기계공학과) ;
  • 윤진한 (한국기계연구원 그린환경기계연구본부) ;
  • 길상인 (한국기계연구원 그린환경기계연구본부)
  • Received : 2012.12.06
  • Accepted : 2012.12.07
  • Published : 2012.12.30

Abstract

The present study was conducted to investigate the flame instability(evaluated by Markstein length and cellular instability) and laminar burning velocity in a constant volume combustion chamber at room temperature and elevated pressure up to 0.3 MPa to suggest the possibility of utilizing mixtures of syngas added DME-air premixed flames in internal combustion engines. The experimentally measured laminar burning velocities were compared to predictions calculated the PREMIX code with Zhao reaction mechanism. Discussions were made on effects of syngas addition into DME-Air premixed flames through evaluating laminar burning velocity, Markstein length, and cellular instability. Particular concerns are focused on cellular instability caused by hydrodynamic instability and diffusive-thermal instability.

Keywords

References

  1. Metghalchi M, Keck JC, "Laminar burning velocity of propane-air mixtures at high temperature and pressure", Combust Flame, Vol. 38, 1980, pp. 143-154 https://doi.org/10.1016/0010-2180(80)90046-2
  2. Gu XJ, Haq MZ, Lawes M, Woolley R, "Laminar burning velocity and Markstein lengths of methaneair mixtures", Combust Flame, Vol. 121, 2000, pp. 41-58 https://doi.org/10.1016/S0010-2180(99)00142-X
  3. Aung KT, Hassan MI, Faeth GM, "Flame stretch interactions of laminar premixed hydrogen/air flames at normal temperature and pressure", Combust Flame, Vol. 109, 1997, pp.1-24 https://doi.org/10.1016/S0010-2180(96)00151-4
  4. Qiao L, Kim CH, Faeth GM, "Suppression effects of diluents on laminar premixed hydrogen/oxygen/ nitrogen flames", Combust Flame, Vol. 143, 2005, pp.79-96 https://doi.org/10.1016/j.combustflame.2005.05.004
  5. Vu TM, Park J, Kwon OB, Kim JS, "Effects of hydrocarbon addition on cellular instabilities in expanding syngas-air spherical premixed flames", Int J Hydrogen Energy, Vol. 34, 2009, pp.6961-6969 https://doi.org/10.1016/j.ijhydene.2009.06.067
  6. Vu TM, Park J, Kwon OB, Bae DS, Yun JH, Keel SI, "Effects of diluents on cellular instabilities in outwardly propagating spherical syngas-air premixed flames", Int J Hydrogen Energy, Vol. 35, 2010, pp.3868-3880 https://doi.org/10.1016/j.ijhydene.2010.01.091
  7. C. Prathap, A. Ray, M.R. Ravi, "Investigation of nitrogen dilution effects on the laminar burning velocity and flame stability of syngas fuel at atmospheric condition", Combust Flame, Vol. 155, 2008, pp. 145-160 https://doi.org/10.1016/j.combustflame.2008.04.005
  8. C. Prathap, A. Ray, M.R. Ravi, "Effects of dilution with carbon dioxide on the laminar burning velocity and flame stability of $H_2$-CO mixtures at atmospheric condition", Combust Flame, Vol. 159, 2012, pp. 482-492 https://doi.org/10.1016/j.combustflame.2011.08.006
  9. X. Qin, Y. Ju, "Measurements of burning velocities of dimethyl ether and air premixed flames at elevated pressure", Proc Combust Inst, Vol. 30, 2005, pp. 233-240 https://doi.org/10.1016/j.proci.2004.08.251
  10. C. A. Daly, J. M. Simmie, J. Wurmel, "Burning Velocities of Dimethyl Ether and Air", Combust Flame, Vol. 125, 2001, pp. 1329-1340 https://doi.org/10.1016/S0010-2180(01)00249-8
  11. Z. Chen, M. P. Burke, Y. Ju, "Effects of compression and stretch on the determination of laminar flame speeds using propagating spherical flames", Combust Theory Modell, Vol. 13, 2009, pp. 343-364. https://doi.org/10.1080/13647830802632192
  12. Z. Zhao, M. Chaos, A. Kazakov, F. L. Dryer, "Thermal Decomposition Reaction and a Comprehensive Kinetic Model of Dimethyl Ether", Int J Chem Kin, Vol 40, 2008, pp. 1-18. https://doi.org/10.1002/kin.20285
  13. X. D. Peng, A. W. Wang, B. A. Toseland, P. J. A. Tijm, "Single-Step Syngas-to-Dimethyl Ether Processes for Optimal Productivity, Minimal Emissions, and Natural Gas-Derived Syngas", Ind Eng Chem Res, Vol. 38, 1999, pp. 4381-4388. https://doi.org/10.1021/ie9901269
  14. A. T. Aguayo et al., "Kinetic Modeling of Dimethyl Ether Synthesis in a Single Step on a CuOZnO-$AI_2O_3$/${\gamma}-AI_2O_3$ Catalyst", Ind Eng Chem Res, Vol. 46, 2007, pp. 5522-5530. https://doi.org/10.1021/ie070269s
  15. M.S. Cha, P.D. Ronney, "Propagation rates of nonpremixed edge flames", Combust Flame, Vol. 146, 1006, pp. 312-328.
  16. G. P. Smith, D. M. Golden, M. Frenklach, N.W. Moriarty, B. Eiteneer, M. Goldenberg, C.T. Bowman, R.K. Hanson, S. Song, W.C. Gardiner Jr., V. Lissianski, Z. Qin, GRI-Mech Homepage, Gas Research Institute, Chicago, 1999. Available from: .