DOI QR코드

DOI QR Code

The Interaction of CO to the Co(salen) Complex in to PEDOT:PSS Film and Sensor Application

  • Memarzadeh, Raheleh (Department of Materials Science & Engineering, Shiraz University) ;
  • Panahi, Farhad (Department of Chemistry, College of Sciences, Shiraz University) ;
  • Javadpour, Sirus (Department of Materials Science & Engineering, Shiraz University) ;
  • Ali, Khalafi-Nezhad (Department of Chemistry, College of Sciences, Shiraz University) ;
  • Noh, Hui-Bog (Department of Chemistry and Institute of BioPhysio Sensor Technology, Pusan National University) ;
  • Shim, Yoon-Bo (Department of Chemistry and Institute of BioPhysio Sensor Technology, Pusan National University)
  • 투고 : 2012.01.20
  • 심사 : 2012.01.27
  • 발행 : 2012.04.20

초록

The interaction between carbon monoxide (CO) and a cobalt-salen complex (Co(salen)) was studied and applied to detect CO. The metal complex doped PEDOT:PSS film exhibited good sensitivity to CO and differentiate CO from other gases. The response of the composite to CO was reversible (RSD < 5%) change in resistance upon removal of CO gas from the test chamber. The effects of adding Co(salen) in the probe film on the response of the sensor were investigated using AFM, XPS, and FT-IR spectroscopy. The sensitivity of the sensor increased as the Co(salen) concentration enhanced as it increased from 0.0 to 1.5 wt. %, where the highest sensitivity ($%{\Delta}R/R_o$) of $-25.0{\pm}0.05%$ was achieved with 1.0 wt. % Co(salen). The sensor containing probe exhibited a linear response ($R^2$ = 0.983) in the range of 0.5 to 10.0% CO (v/v) $N_2$, and the detection limit was 1.74% CO (v/v) in $N_2$.

키워드

참고문헌

  1. Fraden, J. Handbook of Modern Sensors-Physics, Designs and Applications, 3rd ed.; Springer-Verlag, Inc.: New York, U.S.A., 2004.
  2. Ionescu, R.; Vancu, A.; Buta, F. Sensor. Actuat. B-Chem. 1997, 43, 126. https://doi.org/10.1016/S0925-4005(97)00142-1
  3. Bittencourt, C.; Llobet, E.; Ivanox, P.; Correrg, X.; Vilanova, X.; Brezmes, J.; Hubalek, J.; Malysz, K.; Pireaux, J. J.; Calderer, J. Sensor. Actuat. B-Chem. 2004, 97, 67. https://doi.org/10.1016/S0925-4005(03)00648-8
  4. Rahman, Md. A.; Kumar, P.; Park, D.-S.; Shim, Y.-B. Sensors 2008, 8, 118. https://doi.org/10.3390/s8010118
  5. Blanchard, P.; Leriche, P.; Frere, P.; Roncali, J. Advanced Functional Polythiophene Based on Tailored Precursors. In Handbook of Conducting Polymers, 3rd ed.; Skotheim, T. A.; Reynolds, J. R., Eds.; CRC press: Florida, U.S.A., 2006; Chapter 9, 13.
  6. Jeffries-EL, M.; McCullough, R. D. Regioregular Polythiophene. In Handbook of Conducting Polymers, 3rd ed.; Skotheim, T. A.; Reynolds, J. R., Eds.; CRC press: Florida, U.S.A., 2006; Chapter 9.
  7. Li, B.; Santhanam, S.; Schultz, L.; Jeffries-EL. M.; Iovu, M. C.; Sauvéc, G.; Cooper, J.; Zhang, R.; Revelli, J. C.; Kusne, A. G.; Snyder J. L.; Kowalewski, T.; Weiss, L. E.; McCullough, R. D.; Fedder, G. K.; Lambeth, D. N. Sensor. Actuat. B-Chem. 2007, 123, 651. https://doi.org/10.1016/j.snb.2006.09.064
  8. Wang, F.; Gu, H.; Swager, T. M. J. Am. Chem. Soc. 2008, 130, 5392. https://doi.org/10.1021/ja710795k
  9. Shim, Y.-B.; Park, J.-H. J. Eletrcochem. Soc. 2000, 147, 381. https://doi.org/10.1149/1.1393204
  10. Lee, T.-Y.; Shim, Y.-B. Anal. Chem. 2001, 73, 5629. https://doi.org/10.1021/ac015572w
  11. Shiddiky, M. J. A.; Rahman, Md. A.; Shim, Y.-B. Anal. Chem. 2007, 79, 6886. https://doi.org/10.1021/ac0710127
  12. Rahman, Md. A.; Lee, K.-S.; Park, D.-S.; Won, M.-S.; Shim, Y.- B. Biosens. Bioelectron. 2008, 23, 857. https://doi.org/10.1016/j.bios.2007.09.005
  13. Groenendaal, L.; Zotti, G.; Aubert, P.-H.; Waybright, S. M.; Reynolds, J. R. Adv. Mater. 2003, 15, 855. https://doi.org/10.1002/adma.200300376
  14. Groenendaal, L.; Jonas, F.; Freitag, D.; Pielartzik, H.; Reynolds, J. R. Adv. Mater. 2000, 12, 481. https://doi.org/10.1002/(SICI)1521-4095(200004)12:7<481::AID-ADMA481>3.0.CO;2-C
  15. Lin, C.-Y.; Chen, J.-G.; Hu, C.-W.; Tunney, J. J.; Ho, K.-C. Sensor. Actuat. B-Chem. 2009, 140, 402. https://doi.org/10.1016/j.snb.2009.04.041
  16. Javadpour, S.; Gharavi, A.; Feizpour, A.; Khanehzara, A.; Panahi, F. Sensor. Actuat. B-Chem. 2009, 142, 152. https://doi.org/10.1016/j.snb.2009.07.051
  17. Yin, K.; Zhu, Z. Synth. Met. 2010, 160, 1115. https://doi.org/10.1016/j.synthmet.2010.01.030
  18. Wang, S.-J.; Park, H.-H. J. Electroceram. 2007, 18, 161. https://doi.org/10.1007/s10832-007-9019-4
  19. Sotzing, G. A.; Briglin, S. M.; Grubbs, R. H.; Lewis, N. S. Anal. Chem. 2000, 72, 3181. https://doi.org/10.1021/ac991079x
  20. Hatchett, D. W.; Josowicz, M. Chem. Rev. 2008, 108, 746. https://doi.org/10.1021/cr068112h
  21. Dixit, V.; Misra, S. C. K.; Sharma, B. S. Sensor. Actuat. B-Chem. 2005, 104, 90. https://doi.org/10.1016/j.snb.2004.05.001
  22. Ram, M. K.; Yavuz, O.; Lahsangah, V.; Aldissi, M. Sensor. Actuat. B-Chem. 2005, 106, 759.
  23. Paul, S.; Chavan, N. N.; Radhakrishnan, S. Synth. Met. 2009, 159, 415. https://doi.org/10.1016/j.synthmet.2008.10.013
  24. Lee, H.-J.; Song, J.-H.; Yoon, Y.-S.; Kim, T.-S.; Kim, K.-J.; Choi, W.-K. Sensor. Actuat. B-Chem. 2001, 79, 200. https://doi.org/10.1016/S0925-4005(01)00876-0
  25. Grillo, F.; Natile, M. M.; Glisenti, A. Appl. Catal. B-Environ. 2004, 48, 267. https://doi.org/10.1016/j.apcatb.2003.11.003
  26. Barbe, J.-M.; Canard, G.; Brandes, S.; Jerome, F.; Dubois, G.; Guilard, R. Dalton Trans. 2004, 1208.
  27. Jones, R. D.; Summervile, D. A.; Basolo, F. Chem. Rev. 1979, 79, 139. https://doi.org/10.1021/cr60318a002
  28. Burness, J. H.; Dillard, J. G.; Taylor, L. T. J. Am. Chem. Soc. 1975, 97, 6080. https://doi.org/10.1021/ja00854a021
  29. Crispin, X.; Marciniak, S.; Osikowicz, W.; Zotti, G.; Denier van der Gon, A. W.; Louwet, F.; Fahlman, M.; Groenendaal, L.; De Schryver, F.; Salaneck, W. R. J. Polym. Sci. Pt. B-Polym. Phys. 2003, 41, 2561. https://doi.org/10.1002/polb.10659
  30. Yang, Y.; Jiang, Y.; Xu, J.; Yu, J. Colloids and Surfaces A: Physicochem. Eng. Aspects 2007, 302, 157. https://doi.org/10.1016/j.colsurfa.2007.02.013
  31. Maia, F.; Mahata, N.; Jarrais, B.; Silva, A. R.; Pereira, M. F. R.; Freire, C.; Figueiredo, J. L. J. Mol. Catal. A-Chem. 2009, 305, 135. https://doi.org/10.1016/j.molcata.2008.10.045
  32. Ho, R.; Liebman, J.; Valentine, J. In Active Oxygen in Chemistry; Foote, C., Valentine, J., Greenberg, A., Liebman, J., Eds.; CRC Press: London, England, 1995; p 2.
  33. Tan, S.-F.; Ang, K.-P.; Ng, L.-H. Transit. Met. Chem. 1990, 15, 459. https://doi.org/10.1007/BF01040776
  34. Niederhoffer, E. C.; Timmons, J. H.; Martell, A. E. Chem. Rev. 1984, 84, 137. https://doi.org/10.1021/cr00060a003
  35. Estrade-Szwarckopf, H.; Rousseau, B.; Herold, C.; Lagrange, P. Mol. Cryst. Liq. Cryst. 1998, 310, 231. https://doi.org/10.1080/10587259808045341

피인용 문헌

  1. Carbon Monoxide Sensor Based on a B2HDDT-doped PEDOT:PSS Layer vol.34, pp.8, 2013, https://doi.org/10.5012/bkcs.2013.34.8.2291
  2. Plasma modification of poly(2-heptadecyl-4-vinylthieno[3,4-d]thiazole) low bandgap polymer and its application in solar cells vol.16, pp.48, 2014, https://doi.org/10.1039/C4CP03323J
  3. Application of PEDOT:PSS and Its Composites in Electrochemical and Electronic Chemosensors vol.9, pp.4, 2012, https://doi.org/10.3390/chemosensors9040079