Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Photopatternable Conducting Polymer Nanocomposite with Incorporated Gold Nanoparticles for Use in Organic Field Effect Transistors

  • Huh, Sung (Department of Chemistry, Pohang University of Science and Technology) ;
  • Choi, Hyun-Ho (Department of Chemical Engineering, Pohang University of Science and Technology) ;
  • Cho, Kil-Won (Department of Chemical Engineering, Pohang University of Science and Technology) ;
  • Kim, Seung-Bin (Department of Chemistry, Pohang University of Science and Technology)
  • Received : 2011.08.10
  • Accepted : 2011.12.19
  • Published : 2012.04.20
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Abstract

We investigated a new method for patterning organic field-effect transistors (OFETs) using a photopatternable conducting polymer nanocomposite, consisting of poly(3-hexylthiophene) (P3HT)-coated gold nanoparticles (AuNPs) that had been modified with a photoreactive cinnamate group, to form P3HT-AuNP-CI. We found that the addition of the cinnamate group to the nanoparticle surface assisted the preparation of a solvent-resistive semiconducting film and preserved the P3HT ordering, which was interrupted by Au-P3HT interactions, as well as provided UV-controllable electrical properties. The P3HT-AuNPs-CI films could be microscale-patterned via a UV crosslinking photoreaction, represented as a promising photopatternable semiconductor material for use in advanced applications, with tunable electrical properties for fabrication of sub-micron and microscale electronic devices.

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