Bulletin of the Korean Chemical Society

  • 제33권4호
  • /
  • Pages.1128-1134
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  • 2012
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Photopatternable Conducting Polymer Nanocomposite with Incorporated Gold Nanoparticles for Use in Organic Field Effect Transistors

  • Huh, Sung (Department of Chemistry, Pohang University of Science and Technology) ;
  • Choi, Hyun-Ho (Department of Chemical Engineering, Pohang University of Science and Technology) ;
  • Cho, Kil-Won (Department of Chemical Engineering, Pohang University of Science and Technology) ;
  • Kim, Seung-Bin (Department of Chemistry, Pohang University of Science and Technology)
  • 투고 : 2011.08.10
  • 심사 : 2011.12.19
  • 발행 : 2012.04.20
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초록

We investigated a new method for patterning organic field-effect transistors (OFETs) using a photopatternable conducting polymer nanocomposite, consisting of poly(3-hexylthiophene) (P3HT)-coated gold nanoparticles (AuNPs) that had been modified with a photoreactive cinnamate group, to form P3HT-AuNP-CI. We found that the addition of the cinnamate group to the nanoparticle surface assisted the preparation of a solvent-resistive semiconducting film and preserved the P3HT ordering, which was interrupted by Au-P3HT interactions, as well as provided UV-controllable electrical properties. The P3HT-AuNPs-CI films could be microscale-patterned via a UV crosslinking photoreaction, represented as a promising photopatternable semiconductor material for use in advanced applications, with tunable electrical properties for fabrication of sub-micron and microscale electronic devices.

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피인용 문헌

  1. Effect of gold nanoparticles on the structural and optical stability of poly (3-hexylthiophene) vol.123, pp.None, 2012, https://doi.org/10.1016/j.polymdegradstab.2015.11.006