한국염색가공학회지 (Textile Coloration and Finishing)

  • 제24권1호
  • /
  • Pages.33-38
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  • 2012
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  • 1229-0033(pISSN)
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  • 2234-036X(eISSN)
한국염색가공학회 (The Korean Society of Dyers and Finishers)
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DOI QR코드

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PET 말단에 대한 인계난연제의 라디칼계 부가반응 (1) - 비스페놀에이비스다이페닐포스페이트의 반응 -

Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) -

  • 김민관 (경북대학교 기능물질공학과) ;
  • 김한도 (경북대학교 기능물질공학과)
  • Kim, Min-Kwan (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University) ;
  • Ghim, Han-Do (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University)
  • 투고 : 2011.12.23
  • 심사 : 2012.02.27
  • 발행 : 2012.03.27
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초록

In this study, to increase flame retardation of poly(ethylene terephthalate) (PET) in burning, bisphenol A bis(diphenyl phosphate) (BDP), a well known flame retardant containing phosphorous, was reacted on end groups of PET by radical pathway. End-capping mechanism of PET with BDP was suggested and confirmed by spectroscopic and thermal analysis. From 400 MHz $^{31}P$ solid state FT-NMR spectrum of end-capped PET (PET-BDP), phosphorus spectra peak in BDP was found at ca. -20 ppm. Furthermore, P-C bond stretching vibration peaks were found ca. $600cm^{-1}$ in FT-IR spectrums of PET-BDP. These results showed that BDP can be chemically added on end groups of PET by our method. Thermal characteristics of pure PET (pPET) and PET-BDP were measured and evaluated by TGA analysis. There was not significant changes in thermal characteristics of PET-BDP compared to that of pPET.

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참고문헌

  1. S. V. Levchik and E. D. Weil, Review Flame Retardancy of Thermoplastic Polyesters-a Review of the Recent Literature, Polym. Int., 54, 11-35(2005). https://doi.org/10.1002/pi.1663
  2. Y. Choi, K. Bae, Y. Kim, E. Park, and Y. Hong, Application of Deep Black Color on Polyester Fabrics by Color Matching, Textile Coloration and Finishing (J. of Korean Soc. Dyers & Finishers), 22, 28-36(2010). https://doi.org/10.5764/TCF.2010.22.1.028
  3. Y. Kim, S. Lee, and Y. Son, Dyeing Properties of Acid and Reactive Dye for Super Soft Angora /PET, Nylon Blended Fabric, Textile Coloration and Finishing(J. of Korean Soc. Dyers & Finishers), 22, 332-340(2010). https://doi.org/10.5764/TCF.2010.22.4.332
  4. L. Yu, S. Zhang, W. Liu, X. Zhu, X. Chen, and X. Chen, Improving the Flame Retardancy of PET Fabric by Photo-induced Grafting, Polym. Deg. Stab., 95, 1934-1942(2010). https://doi.org/10.1016/j.polymdegradstab.2010.04.005
  5. H. A. Lecomte and J. J. Liggat, Commercial Fire-Retarded PET Formulation- Relationship Between Thermal Degradation Behaviour and Fire-retardant Action, Polym. Deg. Stab., 93, 498-506(2008). https://doi.org/10.1016/j.polymdegradstab.2007.11.005
  6. K. H. Pawlowski and B. Schartel, Flame Retardancy Mechanisms of Triphenyl Phosphate, Resorcinol Bis(Diphenyl Phosphate) and Bisphenol A bis (Diphenyl Phosphate) in Polycarbonate/Acrylonitrile- Butadiene-Styrene blends, Polym. Int., 56, 1404-1414(2007). https://doi.org/10.1002/pi.2290
  7. S. Liu and G. Sun, Functional Modification of Poly (Ethylene Terephthalate) With an Allyl Monomer: Chemistry and Structure Characterization, Polymer, 49, 5225-5232(2008). https://doi.org/10.1016/j.polymer.2008.09.054
  8. S. Y. Lu and I. Hamerton, Recent Developments in the Chemistry of Halogen-Free Flame Retardant Polymers, Prog. Polym. Sci., 27, 1661-1712(2002). https://doi.org/10.1016/S0079-6700(02)00018-7
  9. G. Xue, Orientation Studies of Poly(Ethylene Terephthalate) Film and Fiber Surfaces Using FT-IR Diffuse Reflectance Optics, Makromol. Chem. Rapid Commun., 6, 811-814(1985). https://doi.org/10.1002/marc.1985.030061204
  10. G. Socrates, "Infrared and Raman Characteristic Group Frequencie, 3rd ed.", John Wiley & Sons, NY, pp.229-240, 2001.
  11. A. I. Balabanovich, Poly(butylene terephthalate) Fire Retarded by Bisphenol A bis(diphenyl phosphate), J. Anal. Appl. Pyrolysis, 72, 229-233(2004). https://doi.org/10.1016/j.jaap.2004.07.001
  12. U. Braun, V. Wachtendorf, A. Geburtig, H. Bahr, and B. Schartel, Weathering Resistance of Halogen-Free Flame Retardance in Thermoplastics, Polym. Deg. Stab., 95, 2421-2429(2010). https://doi.org/10.1016/j.polymdegradstab.2010.08.020
  13. A. Karrasch, E. Wawrzyn, B. Schartel, and C. Jager, Solid-state NMR on Thermal and Fire Residues of Bisphenol A Polycarbonate/Silicone Acrylate Rubber/ Bisphenol A Bis(Diphenyl-Phosphate)/(PC/SiR/BDP) and PC/SiR/BDP/zinc Borate (PC/SiR/BDP/ZnB) -Part 1: PC Charring and the Impact of BDP and ZnB, Polym. Deg. Stab., 95, 2525-2533(2010). https://doi.org/10.1016/j.polymdegradstab.2010.07.034
  14. K. H. Pawlowski, B. Schartel, M. A. Fichera, and C. Jager, Flame Retardancy Mechanisms of Bisphenol A bis(diphenyl phosphate) in Combination with Zinc Borate in Bisphenol A polycarbonate/ acrylonitrile-butadiene-styrene Blends, Thermochimica Acta, 498, 92-99(2010). https://doi.org/10.1016/j.tca.2009.10.007
  15. B. J. Holland and J. N. Hay, The Thermal Degradation of PET and Analogous Polyesters Measured by Thermal Analysis-Fourier Transform Infrared Spectroscopy, Polymer, 43, 1835-1847(2001). https://doi.org/10.1016/S0032-3861(01)00775-3
  16. S. V. Levchik, D. A. Bright, P. Moy, and S. Dashevsky, New Developments in Fire Retardant Non-Halogen Aromatic Phosphates, J. Vin. Add. Technol., 6, 123-128(2000). https://doi.org/10.1002/vnl.10238
  17. B. Perret, K. H. Pawlowski, and B. Schartel, Fire Retardancy Mechanisms of Arylphosphates in Polycarbonate(PC) and PC/Acrylonitrile-Butadiene-Styrene, J. Therm. Anal. Calorim., 97, 949-958(2009). https://doi.org/10.1007/s10973-009-0379-7
  18. B. N. Jang, I. Jung, and J. Choi, Study of a Novel Halogen-Free Flame Retardant System through TGA and Structure Analysis of Polymers, J. Appl. Polym. Sci., 112, 2669-2675(2009). https://doi.org/10.1002/app.29803
  19. Q. He, L. Song, Y. Hu, and S. Zhou, Synergistic Effects of Polyhedral Oligomeric Silsesquioxane (POSS) and Oligomeric Bisphenyl A Bis(Diphenyl Phosphate) (BDP) on Thermal and Flame Retardant Properties of Polycarbonate, J. Mater. Sci., 44, 1308-1316(2009). https://doi.org/10.1007/s10853-009-3266-5

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