Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Charge Transport Properties of Polyaniline-gold/graphite Oxide Composite Films

  • Basavaraja, C. (Department of Chemistry and Institute of Basic Science, Inje University) ;
  • Kim, Won-Jung (Department of Chemistry and Institute of Basic Science, Inje University) ;
  • Thinh, P.X. (Department of Chemistry and Institute of Basic Science, Inje University) ;
  • Huh, Do-Sung (Department of Chemistry and Institute of Basic Science, Inje University)
  • Received : 2011.09.23
  • Accepted : 2011.11.29
  • Published : 2012.02.20
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Abstract

A polyaniline-gold composite was prepared via the polymerization of aniline hydrochloride with or without water-soluble graphite oxide using auric acid as an oxidant. The reaction products were characterized using Xray photoelectron spectroscopy. The thermal stability and embedded crystallinity of the composites were also investigated using thermogravimetric and X-ray diffraction analyses. The electrical properties of the composites were examined using cyclic voltammetric measurements at room temperature and temperature-dependent DC conductivity within 300-500 K. Compared to pure graphene oxide and polyaniline-gold composite, the polyaniline-gold-graphene composite exhibited higher crystallinity and thermal stability, and higher current density response under equivalent conditions.

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