Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of Silver Nanoparticles from the Decomposition of Silver(I) [bis(alkylthio)methylene]malonate Complexes

  • Lee, Euy-Jin (Department of Chemistry and GETRC, Kongju National University) ;
  • Piao, Longhai (Department of Chemistry and GETRC, Kongju National University) ;
  • Kim, Jin-Kwon (Department of Chemistry and GETRC, Kongju National University)
  • Received : 2011.09.16
  • Accepted : 2011.10.28
  • Published : 2012.01.20
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Abstract

Silver(I) [bis(alkylthio)methylene]malonates were synthesized from the reaction of silver nitrate and potassium [bis(alkylthio)methylene]malonates. The structures of the Ag complexes were characterized with nuclear magnetic resonance (NMR), inductively coupled plasma atomic emission spectrometry (ICP-AES) and elemental analysis. Ag nanoparticles (NPs) were obtained from the decomposition of the Ag complexes in 1,2-dichlorobenzene at $110^{\circ}C$ without an additional surfactant. The average sizes of the Ag NPs are in the range of 5.1-6.3 nm and could be controlled by varying the length of the alkyl chain. The optical properties, crystalline structure and surface composition of Ag NPs were characterized with ultraviolet-visible (UV-visible) spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), gas chromatography-mass spectrometry (GC-MS), X-ray Photoelectron Spectroscopy (XPS) and thermal gravimetric analysis (TGA).

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