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뫼스바우어 분광법과 색도 분석에 의한 고대 고려청자의 발색메카니즘 연구

Systematic Study on Colorative Mechanism of Ancient Goryeo Celadon Glaze by Mossbauer Spectroscopy and Chromaticity Analysis

  • 전아영 (한국세라믹기술원 이천분원 도자세라믹센터) ;
  • 노형구 (한국세라믹기술원 이천분원 도자세라믹센터) ;
  • 김응수 (한국세라믹기술원 이천분원 도자세라믹센터) ;
  • 조우석 (한국세라믹기술원 이천분원 도자세라믹센터) ;
  • 김경자 (한국세라믹기술원 이천분원 도자세라믹센터) ;
  • 김종영 (한국세라믹기술원 이천분원 도자세라믹센터) ;
  • 김진모 (국민대학교 물리학과) ;
  • 김철성 (국민대학교 물리학과) ;
  • 강경인 (단국대학교 도예과)
  • Jeon, A-Young (Korea Institute of Ceramic Engineering and Technology, Icheon Branch) ;
  • No, Hyung-Goo (Korea Institute of Ceramic Engineering and Technology, Icheon Branch) ;
  • Kim, Ung-Soo (Korea Institute of Ceramic Engineering and Technology, Icheon Branch) ;
  • Cho, Woo-Seok (Korea Institute of Ceramic Engineering and Technology, Icheon Branch) ;
  • Kim, Kyung-Ja (Korea Institute of Ceramic Engineering and Technology, Icheon Branch) ;
  • Kim, Jong-Young (Korea Institute of Ceramic Engineering and Technology, Icheon Branch) ;
  • Kim, Chin-Mo (Department of Physics, Kookmin University) ;
  • Kim, Chul-Sung (Department of Physics, Kookmin University) ;
  • Kang, Gyung-In (Danguk University)
  • 투고 : 2011.10.05
  • 심사 : 2011.12.19
  • 발행 : 2012.01.31

초록

In ancient Goryeo celadon, the effect of the chemical composition and ionic state of Fe on the color was evaluated by Mossbauer spectroscopy and Design of Experiment (DOE) analysis. The ancient celadon pieces excavated from the kiln sites in GangJin and Buan areas were analyzed by Mssbauer spectroscopy, chromaticity, and DOE analysis. The color of celadon was found to be mainly determined by that of glaze since variations of $L^*$, $a^*$, and $b^*$ values for the body were much smaller than those for the glaze. As $Fe^{2+}$/$Fe^{3+}$ in glaze increases, $L^*$ value increases, whereas $a^*$/$b^*$ value decreases, which is well consistent with the result on the synthetic glaze. As the amount of titanium increases in the glaze, the $a^*$ and $b^*$ values decrease; on the other hand, the $L^*$ value increases, which is well consistent with the result on the synthetic glaze.

키워드

참고문헌

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피인용 문헌

  1. on the Color Generation in Celadon Glaze vol.51, pp.3, 2014, https://doi.org/10.4191/kcers.2014.51.3.150
  2. A Preliminary Study on the Roles of Fe Content and Neoformed Ca-rich Minerals in the Coloration of Ceramic Glazes vol.36, pp.4, 2012, https://doi.org/10.12654/jcs.2020.36.4.05