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Characteristics of the Ammonium Diuranate Powders Prepared with Different Experimental Apparatus in Sol-gel Process

졸-겔 방법으로 제조된 Ammonium Diuranate 핵연료 분말의 공정장치 변수에 따른 특성

  • 김연구 (한국원자력연구원 차세대핵연료개발부) ;
  • 정경채 (한국원자력연구원 차세대핵연료개발부) ;
  • 엄성호 (한국원자력연구원 차세대핵연료개발부) ;
  • 조문성 (한국원자력연구원 차세대핵연료개발부)
  • Received : 2012.09.24
  • Accepted : 2012.10.23
  • Published : 2012.12.28

Abstract

This paper describes the spherical ammonium diuranate gel particles which are the intermediated material of the $UO_2$ microsphere for an VHTR(very high temperature reactor) nuclear fuel. The characteristics of the intermediate-ADU gel particles prepared by AWD(ageing, washing, and drying) and FB(fluidized-bed) apparatus were examined and compared in a sol-gel fabrication process. The electrical conductivity of washing filtrate from the FB treating and the surface area of dried-ADU gel particles were higher than those of AWD treating. Also, an internal pore volume in dried-ADU gel particles showed a more decrease in AWD treatment than FB treatment because of decomposition of PVA affected by the washing time. However, the internal microstructures of ADU gel particles were similar regardless of the process variation.

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