Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Efficient and Facile Synthesis of α-Chloroenones Bearing β-Carbonates or β-Carbamates

  • Received : 2012.09.05
  • Accepted : 2012.10.04
  • Published : 2012.12.20
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Abstract

Efficient synthesis of ${\alpha}$-chloroenones bearing ${\beta}$-carbonates or ${\beta}$-carbamates was achieved by rhodium(II)-catalyzed reaction of cyclic diazodicarbonyl compounds with a variety of chloroformates or carbamyl chlorides in good yields. These reactions provided a useful and rapid route to ${\beta}$-substituted ${\alpha}$-haloenones.

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References

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