Journal of the Optical Society of Korea

  • 제16권4호
  • /
  • Pages.414-417
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  • 2012
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  • 1226-4776(pISSN)
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  • 2093-6885(eISSN)
한국광학회 (Optical Society of Korea)
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The Effect of Cerium Reduction on Light Emission in Cerium-containing 20Y2O3-25Al2O3-55SiO2 Glass

  • Maeng, Jee-Hun (Division of Materials Science & Engineering, Hanyang University) ;
  • Choi, Sung-Churl (Division of Materials Science & Engineering, Hanyang University)
  • 투고 : 2012.06.11
  • 심사 : 2012.09.24
  • 발행 : 2012.12.25
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초록

The effect of cerium concentration and the addition of $Sb_2O_3$ on the light emission of cerium-contained glass were investigated. The glass matrix composition was $20Y_2O_3-25Al_2O_3-55SiO_2$, the $CeO_2$ concentration ranged from 0.05 to 0.5 mol%, and $Sb_2O_3$ was added at concentrations of 0.02 to 0.1 mol%. The $Ce^{3+}$ and $Ce^{4+}$ absorption bands were observed at approximately 330 nm and 240 nm, respectively. A broad emission band at 400 nm, due to the 4f-5d transition of the $Ce^{3+}$ ion, was observed under illumination by a UV light at 330 nm. The photoluminescence intensity of $Ce^{3+}$ had a maximum value at a $CeO_2$ concentration of 0.1 mol%. Adding $Sb_2O_3$ decreased the $Ce^{4+}$ absorption intensity and enhanced the light emission intensity of $Ce^{3+}$ by about 45%.

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참고문헌

  1. S. Fujita, S. Yoshihara, A. Sakamoto, S. Yamamoto, and S. Tanabe, "YAG glass-ceramic phosphor for white LED (I): background and development," Proc. SPIE 5941, 594111 (2005).
  2. Tanabe, "YAG glass-ceramic phosphor for white LED (II): luminescence characteristics," Proc. SPIE 5941, 594112 (2005).
  3. Z. J. Chao, C. Parent, G. L. Flem, and P. Hagenmuller, "White light emitting glasses," J. Solid. State. Chem. 93, 17-29 (1991). https://doi.org/10.1016/0022-4596(91)90269-N
  4. G. Liu and J. Heo, "Generation of white light from oxyfluoride nano-glass doped with $Ho^{3+}$, $Tm^{3+}$ and $Yb^{3+}$," Mater. Lett. 61, 3751-3754 (2007). https://doi.org/10.1016/j.matlet.2006.12.042
  5. C. Zhu, Y. Yang, X. Liang, S. Yuan, and G. Chen, "Rare earth ions doped full-color luminescence glasses for white LED," J. Lumin. 126, 707-710 (2007). https://doi.org/10.1016/j.jlumin.2006.10.028
  6. B. Blasse and B. C. Grabmaier, Luminescent Materials (Springer-Verlag, New York, USA, 1994).
  7. G. K. DasMohapatra, "A spectroscopic study of cerium in lithium-alumino-borate glass," Mater. Lett. 35, 120-125 (1998). https://doi.org/10.1016/S0167-577X(97)00232-2
  8. A. Kurita, T. Kushida, T. Izumitani, and M. Matsukawa, "Room-temperature persistent spectral hole burning in $Sm^{2+}$-doped fluoride glasses," Opt. Lett. 19, 314-316 (1994). https://doi.org/10.1364/OL.19.000314
  9. M. B. Volf, Chemical Approach to Glass (Elsevier, Amsterdam, Netherlands, 1984).
  10. R. Reisfeld, H. Minti, A. Patra, D. Ganguli, and M. Gaft, "Spectroscopic properties of cerium in glasses and their comparison with crystals," Spectrochim. Acta A 54, 2143- 2150 (1998). https://doi.org/10.1016/S1386-1425(98)00131-0
  11. J. S. Stroud, "Photoionization of $Ce^{3+}$ in glass," J. Chem. Phys. 35, 844-850 (1961). https://doi.org/10.1063/1.1701227
  12. J. A. Duffy and Ingram, "An interpretation of glass chemistry in terms of the optical basicity concept," J. Non-Cryst. Solids 21, 373-410 (1976). https://doi.org/10.1016/0022-3093(76)90027-2
  13. H. J. Kim and S. C. Choi, "Effect of $Sb_{2}O_{3}$and raw materials on the crystallisation of silver containing glasses," Phys. Chem. Glasses 41, 55-58 (2000).
  14. G. Chen, S. Baccaro, M. Nikl, A. Cecilia, Y. Y. Du, and E. Mihokova, "The red-shift of ultraviolet spectra and the relation to optical basicity of Ce-doped alkali rare-earth phosphate glasses," J. Am. Ceram. Soc. 87, 1378-1380 (2004) https://doi.org/10.1111/j.1151-2916.2004.tb07741.x
  15. S. H. M. Poort, J. W. h. van Krevel, R. Stomphorst, A. P. Vink, and G. Blasse, "Luminescence of $Eu^{2+}$ in host lattices with three alkaline earth ions in a row," J. Solid State Chem. 122, 432-435 (1996). https://doi.org/10.1006/jssc.1996.0137
  16. R. Reisfeld, "Spectra and energy transfer of rare-earths in inorganic glasses," Structure & Bonding 13, 53-98 (1973). https://doi.org/10.1007/3-540-06125-8_2

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