DOI QR코드

DOI QR Code

Polymer Dielectrics and Orthogonal Solvent Effects for High-Performance Inkjet-Printed Top-Gated P-Channel Polymer Field-Effect Transistors

  • Baeg, Kang-Jun (Convergence Components and Materials Research Laboratory, ETRI) ;
  • Khim, Dong-Yoon (Heeger Center for Adv. Mater., Gwangju Institute of Science and Technology) ;
  • Jung, Soon-Won (Convergence Components and Materials Research Laboratory, ETRI) ;
  • Koo, Jae-Bon (Convergence Components and Materials Research Laboratory, ETRI) ;
  • You, In-Kyu (Convergence Components and Materials Research Laboratory, ETRI) ;
  • Nah, Yoon-Chae (School of Energy Materials Chemical Engineering, Korea University of Technology and Education) ;
  • Kim, Dong-Yu (Heeger Center for Adv. Mater., Gwangju Institute of Science and Technology) ;
  • Noh, Yong-Young (Department of Chemical Engineering, Hanbat National University)
  • Received : 2011.05.23
  • Accepted : 2011.09.06
  • Published : 2011.12.31

Abstract

We investigated the effects of a gate dielectric and its solvent on the characteristics of top-gated organic field-effect transistors (OFETs). Despite the rough top surface of the inkjet-printed active features, the charge transport in an OFET is still favorable, with no significant degradation in performance. Moreover, the characteristics of the OFETs showed a strong dependency on the gate dielectrics used and its orthogonal solvents. Poly(3-hexylthiophene) OFETs with a poly(methyl methacrylate) dielectric showed typical p-type OFET characteristics. The selection of gate dielectric and solvent is very important to achieve high-performance organic electronic circuits.

Keywords

References

  1. H. Sirringhaus, "Device Physics of Solution-Processed Organic Field-Effect Transistors," Adv. Mater., vol. 17, no. 20, Oct. 2005, pp. 2411-2425. https://doi.org/10.1002/adma.200501152
  2. Y.-Y. Noh et al., "Downscaling of Self-Aligned, All-Printed Polymer Thin-Film Transistors," Nat. Nanotech., vol. 2, no. 12, Nov. 2007, pp. 784-789. https://doi.org/10.1038/nnano.2007.365
  3. G.H. Gelinck et al., "Flexible Active-Matrix Displays and Shift Registers Based on Solution-Processed Organic Transistors," Nat. Mater., vol. 3, Jan. 2004, pp. 106-110. https://doi.org/10.1038/nmat1061
  4. K. Sanderson, "Display of Flexibility," Nature, vol. 445, Jan. 2007, P. 473. https://doi.org/10.1038/445473a
  5. T. Sekitani et al., "Stretchable Active-Matrix Organic Light- Emitting Diode Display Using Printable Elastic Conductors," Nat. Mater., vol. 8, May 2009, pp. 494-499. https://doi.org/10.1038/nmat2459
  6. E. Cantatore et al., "A 13.56-MHz RFID System Based on Organic Transponders," IEEE J. Solid-State Circuits, vol. 42, no. 12, Dec. 2007, pp. 84-92. https://doi.org/10.1109/JSSC.2006.886556
  7. Y.-Y. Noh et al., "High-Photosensitivity p-Channel Organic Phototransistors Based on a Biphenyl End-Capped Fused Bithiophene Oligomer," Appl. Phys. Lett., vol. 86, no. 4, Jan. 2005, 043501:1-3.
  8. K.-J. Baeg et al., "Organic Non-Volatile Memory Based on Pentacene Field-Effect Transistors Using a Polymeric Gate Electret," Adv. Mater., vol. 18, no. 23, Dec. 2006, pp. 3179-3183. https://doi.org/10.1002/adma.200601434
  9. K.-J. Baeg et al., "Polarity Effects of Polymer Gate Electrets on Non-Volatile Organic Field-Effect Transistor Memory,"Adv. Funct. Mater., vol. 18, no. 22, Nov. 2008, pp. 3678-3685. https://doi.org/10.1002/adfm.200800378
  10. K.-J. Baeg et al., "Controllable Shifts in Threshold Voltage of Top-Gate Polymer Field-Effect Transistors for Applications in Organic Nano Floating Gate Memory," Adv. Funct. Mater., vol. 20, no. 2, Jan. 2010, pp. 224-230. https://doi.org/10.1002/adfm.200901677
  11. B.S. Ong et al., "High-Performance Semiconducting Polythiophenes for Organic Thin-Film Transistors," J. Am. Chem. Soc. vol. 126, no. 11, Mar. 2004, pp. 3378-3379. https://doi.org/10.1021/ja039772w
  12. I. McCulloch et al., "Liquid-Crystalline Semiconducting Polymers with High Charge-Carrier Mobility," Nat. Mater., vol. 5, Mar. 2006, pp. 328-333. https://doi.org/10.1038/nmat1612
  13. H. Yan et al., "A High-Mobility Electron-Transporting Polymer for Printed Transistors," Nature, vol. 457, Jan. 2009, pp. 679-686. https://doi.org/10.1038/nature07727
  14. C.D. Dimitrakopoulos et al., "Low-Voltage, High-Mobility Pentacene Transistors with Solution-Processed High Dielectric Constant Insulators," Adv. Mater., vol. 11, no. 16, Nov. 1999, pp. 1372-1375. https://doi.org/10.1002/(SICI)1521-4095(199911)11:16<1372::AID-ADMA1372>3.0.CO;2-V
  15. L.L. Chua et al., "General Observation of n-Type Field-Effect Behaviour in Organic Semiconductors," Nature, vol. 434, Mar. 2005, pp. 194-199. https://doi.org/10.1038/nature03376
  16. M.-H. Yoon et al., "Gate Dielectric Chemical Structure-Organic Field-Effect Transistor Performance Correlations for Electron, Hole, and Ambipolar Organic Semiconductors," J. Am. Chem. Soc., vol. 128, no. 39, Oct. 2006, pp. 12851-12869. https://doi.org/10.1021/ja063290d
  17. H. Sirringhaus et al., "High-Resolution Inkjet Printing of All- Polymer Transistor Circuits," Sci., vol. 290, no. 5499, Dec. 2000, pp. 2123-2126. https://doi.org/10.1126/science.290.5499.2123
  18. Y.-Y. Noh and H. Sirringhaus, "Ultra-thin Polymer Gate Dielectrics for Top-Gate Polymer Field-Effect Transistors," Org. Electron., vol. 10, no. 1, Feb. 2009, pp. 174-180. https://doi.org/10.1016/j.orgel.2008.10.021
  19. S.M. Sze et al., Physics of Semiconductor Devices, 3rd ed., New York: Wiley-Interscience, 2007.
  20. R.D. Deegan et al., "Capillary Flow as the Cause of Ring Stains from Dried Liquid Drops," Nature, vol. 389, Oct. 1997, pp. 827-829. https://doi.org/10.1038/39827
  21. H. Hu and R.G. Larson, "Marangoni Effect Reverses Coffee-Ring Depositions," J. Phys. Chem. B, vol. 110, no. 14, Apr. 2006, pp. 7090-7094. https://doi.org/10.1021/jp0609232
  22. E. Tekin et al., "Controlled Pattern Formation of Poly[2-Methoxy-5-(2′-Ethylhexyloxyl)-1,4-Phenylenevinylene] (MEH-PPV) by Ink-Jet Printing," Adv. Funct. Mater., vol. 17, no. 2, Jan. 2007, pp. 277-284. https://doi.org/10.1002/adfm.200600049
  23. J.A. Lim et al., "Self-Organization of Ink-jet-Printed Triisopropylsilylethynyl Pentacene via Evaporation-Induced Flows in a Drying Droplet," Adv. Funct. Mater., vol. 18, no. 2, Jan. 2008, pp. 229-234. https://doi.org/10.1002/adfm.200700859
  24. K.-J. Baeg et al., "High Speeds Complementary Integrated Circuits Fabricated with All-Printed Polymeric Semiconductors," J. Poly. Sci.: Poly. Phys., vol. 49, no. 1, Jan. 2011, pp. 62-67. https://doi.org/10.1002/polb.22148
  25. M. Manceaua et al., "The Mechanism of Photo- and Thermooxidation of Poly(3-Hexylthiophene) (P3HT) Reconsidered," Poly. Degradation and Stability, vol. 94, no. 6, June 2009, pp. 898-907. https://doi.org/10.1016/j.polymdegradstab.2009.03.005
  26. K.-J. Baeg et al., "High Mobility Top-Gated Poly(3-Hexylthiophene) Field-Effect Transistors with High Work-Function Pt Electrodes," Thin. Sol. Films., vol. 518, no. 14, May 2010, pp. 4024-4029. https://doi.org/10.1016/j.tsf.2010.01.026
  27. T. Richards and H. Sirringhaus, "Analysis of the Contact Resistance in Staggered, Top-Gate Organic Field-Effect Transistors," J. Appl. Phys., vol. 102, no. 9, Nov. 2007, 094510:1-6.
  28. J. Veres et al., "Gate Insulators in Organic Field-Effect Transistors," Chem. Mater., vol. 16, no. 23, Sept. 2004, pp. 4543-4555. https://doi.org/10.1021/cm049598q
  29. H. Sirringhaus et al., "Two-Dimensional Charge transport in Self-Organized, High-Mobility Conjugated Polymer," Nature, vol. 401, Oct. 1999, pp. 685-688. https://doi.org/10.1038/44359
  30. P.-Y. Lo et al., "Stable Polymer Dielectric Film for Polythiophene Thin Film Transistor on Modified Poly(vinyl phenol) with Polar Functional Group," Jpn. J. Appl. Phys., vol. 46, Apr. 2007, pp. 2714-2716. https://doi.org/10.1143/JJAP.46.2714
  31. F.-Y. Yang et al., "High-Performance Poly(3-Hexylthiophene) Transistors with Thermally Cured and Photo-Cured PVP Gate Dielectrics," J. Mater. Chem., vol. 18, no. 48, Nov. 2008, pp. 5927-5932. https://doi.org/10.1039/b809608b
  32. S. Mototani et al., "Performance of Organic Field-Effect Transistors with Poly(3-Hexylthiophene) as the Semiconductor Layer and Poly(4-vinylphenol) Thin Film Untreated and Treated by Hexamethyldisilazane as the Gate Insulator," Jpn. J. Appl. Phys., vol. 47, Jan. 2008, pp. 496-500. https://doi.org/10.1143/JJAP.47.496
  33. S. Kobayashi et al., "Control of Carrier Density by Self-Assembled Monolayers in Organic Field-Effect Transistors," Nat. Mater., vol. 3, Apr. 2004, pp. 317-322. https://doi.org/10.1038/nmat1105
  34. V. Podzorov and M.E. Gershenson, "Photoinduced Charge Transfer across the Interface between Organic Molecular Crystals and Polymers," Phys. Rev. Lett., 2005, vol. 95, 016602:1-4.
  35. Y.-Y. Noh et al., "Highly Sensitive Thin-Film Organic Phototransistors: Effect of Wavelength of Light Source on Device Performance," J. Appl. Phys., vol. 98, Oct. 2005, 074505:1-7.
  36. K.C. Dickey et al., "Improving Organic Thin-Film Transistor Performance through Solvent-Vapor Annealing of Solution-Processable Triethylsilylethynyl Anthradithiophene," Adv. Mater. vol. 18, no. 13, July 2006, pp. 1721-1726. https://doi.org/10.1002/adma.200600188
  37. K.-H. Yim et al., "Controlling Electrical Properties of Conjugated Polymers via a Solution-Based p-Type Doping," Adv. Mater., vol. 20, no. 17, Sept. 2008, pp. 3319-3324. https://doi.org/10.1002/adma.200800735

Cited by

  1. Pressure Control Organic Vapor Deposition Methods for Fabricating Organic Thin-Film Transistors vol.34, pp.6, 2011, https://doi.org/10.4218/etrij.12.0212.0266
  2. Nonvolatile Ferroelectric P(VDF-TrFE) Memory Transistors Based on Inkjet-Printed Organic Semiconductor vol.35, pp.4, 2011, https://doi.org/10.4218/etrij.13.0212.0280
  3. Printed Organic One-Time Programmable ROM Array Using Anti-fuse Capacitor vol.35, pp.4, 2011, https://doi.org/10.4218/etrij.13.1912.0010
  4. Preliminary Works of Contact via Formation of LCD Backplanes Using Silver Printing vol.35, pp.4, 2011, https://doi.org/10.4218/etrij.13.1912.0018
  5. Inkjet-printed organic thin-film transistor and antifuse capacitor for flexible one-time programmable memory applications vol.64, pp.1, 2011, https://doi.org/10.3938/jkps.64.74
  6. Neurons in Polymer: Hardware Neural Units Based on Polymer Memristive Devices and Polymer Transistors vol.61, pp.10, 2014, https://doi.org/10.1109/ted.2014.2346700
  7. Flexible ambipolar organic field-effect transistors with reverse-offset-printed silver electrodes for a complementary inverter vol.27, pp.22, 2011, https://doi.org/10.1088/0957-4484/27/22/225302
  8. Solvent-Free Processable and Photo-Patternable Hybrid Gate Dielectric for Flexible Top-Gate Organic Field-Effect Transistors vol.9, pp.6, 2011, https://doi.org/10.1021/acsami.6b14500
  9. 무용매 공정과 직접 패턴이 가능한 실세스퀴옥산 탑 게이트 유기 트랜지스터용 게이트 유전체 vol.54, pp.5, 2011, https://doi.org/10.12772/tse.2017.54.344
  10. Interface studies of well-controlled polymer bilayers and field-effect transistors prepared by a mixed-solvent method vol.8, pp.21, 2011, https://doi.org/10.1039/c7ra13143g
  11. Adhesive Ion‐Gel as Gate Insulator of Electrolyte‐Gated Transistors vol.7, pp.13, 2020, https://doi.org/10.1002/celc.202000305
  12. Electrically programmable multilevel nonvolatile memories based on solution-processed organic floating-gate transistors vol.118, pp.10, 2011, https://doi.org/10.1063/5.0034709
  13. Enhanced performance of solution-processable floating-gate organic phototransistor memory for organic image sensor applications vol.14, pp.4, 2021, https://doi.org/10.35848/1882-0786/abee9e