Journal of Korea Technical Association of The Pulp and Paper Industry (펄프종이기술)

Korea Technical Association of the Pulp and Paper Industry (한국펄프종이공학회)
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Improvement on Dyeability of Hanji with Natural Dyes Using a (3-chloro-2-hydroxypropyl) Trimethyl Ammonium Chloride

양이온화 처리 한지의 천연염색성

  • Yoo, Seung-Il (Dept. of Wood and Paper Science, Chungbuk National University) ;
  • Oh, Ui-Myeong (Dept. of Wood and Paper Science, Chungbuk National University) ;
  • Min, Yu-Ri (Dept. of Wood and Paper Science, Chungbuk National University) ;
  • Choi, Tae-Ho (Dept. of Wood and Paper Science, Chungbuk National University)
  • 유승일 (충북대학교 목재.종이과학과) ;
  • 오의명 (충북대학교 목재.종이과학과) ;
  • 민유리 (충북대학교 목재.종이과학과) ;
  • 최태호 (충북대학교 목재.종이과학과)
  • Received : 2011.09.06
  • Accepted : 2011.09.16
  • Published : 2011.09.30
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Abstract

We carried out cationization of Dak pulp (paper mulberry bast fiber pulp) which is raw material of Hanji (Traditional Korean Paper) using a (3-chloro-2-hydroxypropyl) trimethyl ammonium chloride to improve dyeability during a dyeing of Hanji with Gardenia (Gardenia jasminoides) and smoke tree (Cotinus coggygria). Fiber specific charge densities were determined using polyelectrolyte titration method and K/S values of dyed Hanji was calculated by Kubelka-Munk equation. As the result, fiber specific charge density increased with degree of cationization. Colors of Hanji dyed with Gardenia did not vary significantly with degree of cationization, but cationized Hanji dyed with smoke tree showed a large increase of a* value and reddish yellow color. After-mordanting did not decrease K/S value of dyes with cationized Hanji. K/S values of dyed Hanji decreased with increasing dyeing temperature. For smoke tree, the cationization impair lightfastness of dyed Hanji without mordant. After-mordanting with copper acetate or iron chloride improved lightfastness of dyed Hanji.

Keywords

References

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