Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Poly(N,N'-Dichloro-N-ethyl-benzene-1,3-disulfonamide) and N,N,N',N'-Tetrachlorobenzene-1,3-disulfonamide as Efficient Reagents to Direct Oxidative Conversion of Thiols and Disulfide to Sulfonyl Chlorides

  • Veisi, Hojat (Chemistry Department, Payame Noor University) ;
  • Ghorbani-Vaghei, Ramin (Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University) ;
  • Mahmoodi, Jafar (Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University)
  • Received : 2011.07.06
  • Accepted : 2011.08.19
  • Published : 2011.10.20
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Abstract

Poly(N,N'-Dichloro-N-ethyl-benzene-1,3-disulfonamide) (PCBS) and N,N,N',N'-Tetrachlorobenzene-1,3-disulfonamide (TCBDA) were found to be a mild and efficient reagent for the direct oxidative conversion of sulfur compounds to the corresponding arenesulfonyl chlorides in good to excellent yields through the oxidative chlorination. The overall process is simple, practical, and it provides convenient access to a variety of aryl or heteroarylsulfonyl chlorides. The mild reaction conditions and the broad substrate scope render this method attractive, and complementary to existing syntheses of aryl or heteroarylsulfonyl chlorides.

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References

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