조명전기설비학회논문지 (Journal of the Korean Institute of Illuminating and Electrical Installation Engineers)

  • 제25권10호
  • /
  • Pages.116-124
  • /
  • 2011
  • /
  • 1229-4691(pISSN)
  • /
  • 2287-5034(eISSN)
한국조명전기설비학회 (The Korean Institute of IIIuminating and Electrical Installation Engineers)
권호 표지
DOI QR코드

DOI QR Code

플라즈마 리액터 및 오존분해 촉매를 이용한 메탄올 및 에탄올로부터 수소발생특성

Characteristics of Hydrogen Production from Methanol and Ethanol Using Plasma Reactor and Ozone Decomposition Catalyst

  • 구본국 (경남대학교 전기공학과) ;
  • 김영춘 (한국전력공사) ;
  • 장문국 (한국폴리텍 항공대학 항공전기과) ;
  • 김종현 (경남대학교 전기 공학과) ;
  • 박재윤 (경남대학교 전기공학과) ;
  • 한상보 (경남대학교 전기공학과)
  • 투고 : 2011.08.26
  • 심사 : 2011.09.21
  • 발행 : 2011.10.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

In this work, the effect of the initial concentration of methanol and ethanol, and the addition of oxygen molecules were discussed to improve the hydrogen generation using non-thermal plasma reactor effectively. In addition, the effect of ozone decomposition catalyst of manganese dioxide and its quantity was investigated. First, hydrogen concentration increased until an initial concentration of about 40,000[ppm] of methanol and thereafter it was saturated. Henceforth, hydrogen concentration decreased with increasing the oxygen percent on the carrier gas of nitrogen about both substances. Related with the effect of catalyst, it increased upto 60[g], but it was not changed largely after that. Consequently, it is confirmed that the hybrid process using plasma process and catalytic surface chemical reaction is a very promising way to increase the efficiency of hydrogen generation as investigated in this work.

키워드

참고문헌

  1. O. Aubry, C. Met, A. Khacef, J.M. Cormier, "On the use of a non-thermal plasma reactor for ethanol steam reforming", Chem. Eng. Journal, Vol. 106, No. 3, 241-247, 2005. https://doi.org/10.1016/j.cej.2004.12.003
  2. C. Wu, Q. Huang, M. Sui, Y. Yan, F. Wang, "Hydrogen production via catalytic steam reforming of fast pyrolysis bio-oil in a two-stage fixed bed reactor system", Fuel Process. Tech., Vol. 89, No. 12, 1306-1316, 2008. https://doi.org/10.1016/j.fuproc.2008.05.018
  3. Jeppe Rass-Hansen, Roger Johansson, Martin Møller, Claus Hviid Christensen, "Steam reforming of technical bioethanol for hydrogen production", J. Hydrogen Energy, Vol. 33, No. 17, 4547-4554, 2008. https://doi.org/10.1016/j.ijhydene.2008.06.020
  4. Weijie Cai, Fagen Wang, Andre van Veen, Claude Descorme, Yves Schuurman, Wenjie Shen, and Claude Mirodatos, "Hydrogen production from ethanol steam reforming in a micro-channel reactor", J. Hydrogen Energy, Vol. 35, No. 3, 1152-1159, 2010. https://doi.org/10.1016/j.ijhydene.2009.11.104
  5. Hidetoshi Sekiguchi, Yoshihiro Mori, "Steam plasma reforming using microwave discharge", Thin Solid Films, Vol. 435, No. 1-2, 44-48, 2003. https://doi.org/10.1016/S0040-6090(03)00379-1
  6. T. Paulmier, L. Fulcheri, "Use of non-thermal plasma for hydrocarbon reforming", Chem. Eng. Journal, Vol. 106, No. 1, 59-71, 2005. https://doi.org/10.1016/j.cej.2004.09.005
  7. A. Kulcke, B. Blackmon, W.B. Champman, I.K.Kim, and D.J. Nesbitt, "Time-resolved O3 chemical chain reaction kinetics via high-resolution IR laser absorption methods", J. Phys. Chem. A, Vol. 102 (1998) 1965-1972. https://doi.org/10.1021/jp972486k
  8. Sang-Bo Han and Tetsuji Oda, "Decomposition mechanism of trichloroethylene based on by-product distribution in the hybrid barrier discharge plasma process", Plasma Sources Sci. Technol., Vol. 16 (2007) 413-421. https://doi.org/10.1088/0963-0252/16/2/026
  9. R. Rudolph, K-P. Franke, and H. Miessner, "Concentration Dependence of VOC decomposition by Dielectric Barrier Discharges", Plas. Chem. And Plas. Process., Vol. 22, No. 3 (2002) 401-412. https://doi.org/10.1023/A:1015369100161
  10. Atsushi Ogata, Daisuke Ito, Koich Mizuno, "Effect of coexisting components on aromatic decomposition in a packed-bed plasma reactor", Appl. Catal. A, General 236 (2002) 9-15. https://doi.org/10.1016/S0926-860X(02)00280-6
  11. V. Demidiouk, S.I. Moon, J. O. Chae, "Toluene and butyl acetate removal from air by plasma-catalytic system", Catalysis communication 4 (2003) 51-56. https://doi.org/10.1016/S1566-7367(02)00256-X
  12. 丼關昇, "오존나이저에 있어서 오존 생성기구와 금후의 과제" 정전기학회지, 7, 3 (1983) 142-149.
  13. Tochiaki Yamamoto, "VOC decomposition by nonthermal plasma processing - A new approach", J. electrost., 42 (1997) 227-238. https://doi.org/10.1016/S0304-3886(97)00144-7
  14. I. Nagao, M. Nishida, K. Yukimura, S. Kambara, T. Maruyama, "NOx removal using nitrogen gas activated by dielectric barrier discharge at atmospheric pressure", Vacuum, Vol. 65 (2002) 481-487. https://doi.org/10.1016/S0042-207X(01)00460-2
  15. Zoran Falkenstein and John J Coogan, "Microdischarge behaviour in the silent discharge of nitrogen-oxygen and water-air mixtures", J. Phys. D:Appl. Phys., Vol. 30 (1997) 817-825. https://doi.org/10.1088/0022-3727/30/5/015
  16. B. Eliasson, M. Hirth and U. Kogelschatz, "Ozone synthesis from oxygen in dielectric barrier discharges", J. Phys. D:Appl. Phys., Vol. 20 (1987) 1421-1437. https://doi.org/10.1088/0022-3727/20/11/010
  17. 한상보, "플라즈마 프로세스 및 촉매 표면화학반응에 의 한 유기화합물 분해효율 향상에 대한연구", 대한전기학회, Vol. 59, No. 5, 932-938, 2010.