Bulletin of the Korean Chemical Society

  • 제32권9호
  • /
  • Pages.3333-3337
  • /
  • 2011
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Mechanochemical Synthesis of ZnMn2O4 and its Electrochemical Properties as an Anode Material for Lithium-ion Batteries

  • Park, Yoon-Soo (Department of Advanced Materials Science and Engineering, Kangwon National University) ;
  • Oh, Hoon (Department of Advanced Materials Science and Engineering, Kangwon National University) ;
  • Lee, Sung-Man (Department of Advanced Materials Science and Engineering, Kangwon National University)
  • 투고 : 2011.06.30
  • 심사 : 2011.07.21
  • 발행 : 2011.09.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

$ZnMn_2O_4$ has been prepared by a mechanochemical process using a mixture of $Mn_2O_3$ and ZnO as starting materials, and investigated as a possible anode material for lithium-ion batteries. The phase evolution and morphologies of the ball-milled and annealed powders are characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy dispersive microanalysis (EDX), respectively. The solid-state reaction for the formation of $ZnMn_2O_4$, under the given experimental conditions, is achieved in a short time (30 min), and the prepared samples exhibit excellent electrochemical performances including an enhanced initial coulombic efficiency, high reversible capacity, and stable capacity retention with cycling.

키워드

참고문헌

  1. Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J. M. Nature 2000, 407, 496. https://doi.org/10.1038/35035045
  2. Lou, X. W.; Deng, D.; Lee, J. Y.; Feng, J.; Archer, L. A. Adv. Mater. 2008, 20, 258. https://doi.org/10.1002/adma.200702412
  3. Bruce, P. G.; Scrosati, B.; Tarascon, J. M. Angew. Chem. Int. Ed. 2008, 47, 2. https://doi.org/10.1002/anie.200790256
  4. Sharma, Y.; Sharma, N.; Rao, G. V. S.; Chowdari, B. V. R. Adv. Funct. Mater. 2007, 17, 2855. https://doi.org/10.1002/adfm.200600997
  5. Pasero, D.; Reeves, N.; West, A. R. J. Power Sources 2005, 141, 156. https://doi.org/10.1016/j.jpowsour.2004.07.037
  6. Reddy, B. M. V.; Yu, T.; Sow, C. H.; Shen, Z. X.; Lim, C. T.; Subba Rao, G. V.; Chowdari, B. V. R. Adv. Funct. Mater. 2007, 17, 272.
  7. Fan, Q.; Whittingham, M. S. Electrochem. Solid-State Lett. 2007, 10, A48. https://doi.org/10.1149/1.2422749
  8. Nam, K. T.; Kim, D. W.; Yoo, P. J.; Chiang, C. Y.; Meethong, N.; Hammon, P. T.; Chiang, Y. M.; Belcher, A. M. Science 2006, 312, 885. https://doi.org/10.1126/science.1122716
  9. Yang, Y.; Zhao, Y.; Xiao, L.; Zhang, L. Electrochem. Commun. 2008, 10, 1117. https://doi.org/10.1016/j.elecom.2008.05.026
  10. Xiao, L.; Yang, Y.; Yin, J.; Li, Q.; Zhang, L. J. Power Sources 2009, 194, 1089. https://doi.org/10.1016/j.jpowsour.2009.06.043
  11. Suryanarayana, C. Prog. Mater. Sci. 2001, 46, 1, and references therein. https://doi.org/10.1016/S0079-6425(99)00010-9
  12. Sharma, V Y.; Sharma, N.; Subba Rao, G. V.; Chowdari, B. V. R. Electrochim. Acta 2008, 53, 2380. https://doi.org/10.1016/j.electacta.2007.09.059
  13. Guo, X.; Lu, X.; Fang, X.; Mao, Y.; Wang, Z.; Chen, L.; Xu, X.; Yang, H.; Liu, Y. Electrochem. Commun. 2010, 12, 847. https://doi.org/10.1016/j.elecom.2010.04.003

피인용 문헌

  1. hollow microspheres as high performance anode materials for lithium ion batteries vol.5, pp.120, 2015, https://doi.org/10.1039/C5RA16667E
  2. Tuning the morphology of ZnMn2O4 lithium ion battery anodes by electrospinning and its effect on electrochemical performance vol.3, pp.8, 2011, https://doi.org/10.1039/c2ra22943a
  3. Heterostructured core–shell ZnMn2O4 nanosheets@carbon nanotubes’ coaxial nanocables: a competitive anode towards high-performance Li-ion batteries vol.26, pp.14, 2011, https://doi.org/10.1088/0957-4484/26/14/145401