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A New and Convenient Method for Reduction of Oximes to Amines with NaBH3CN In the Presence of MoCl5/NaHSO4·H2O System

  • Kouhkan, Mehri (Department of Chemistry, Faculty of Science, Urmia University) ;
  • Zeynizadeh, Behzad (Department of Chemistry, Faculty of Science, Urmia University)
  • Received : 2011.05.16
  • Accepted : 2011.07.21
  • Published : 2011.09.20

Abstract

Various aldoximes and ketoximes were efficiently reduced to their corresponding amines with $NaBH_3CN$ in the presence of $MoCl_5/NaHSO_4{\cdot}H_2O$ system. Reduction reactions were carried out in refluxing EtOH or DMF within 0.3-3.8 h to afford the amines in high to excellent yields.

Keywords

References

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