Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of Cardo Based Poly(arylene ether)s for Flexible Plastic Substrates and Their Properties

  • Kim, Moon-Ki (Department of Chemistry and Research Institute for Natural Sciences, Hanyang University) ;
  • Kwon, Kyung-Jae (Department of Chemistry and Research Institute for Natural Sciences, Hanyang University) ;
  • Han, Yang-Kyoo (Department of Chemistry and Research Institute for Natural Sciences, Hanyang University)
  • Received : 2011.04.04
  • Accepted : 2011.07.20
  • Published : 2011.09.20
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Abstract

New poly(arylene ether)s (PAEs) with both transparency and heat-resistance were prepared by a polycondensation of FBPODS, an ordered-sequence aromatic dihalide, and cardo typed aromatic diols containing fluorene and/or adamantane moiety and also non-cardo typed 1,5-naphthalene diol. The resulting polymers had their glass transition temperatures ranged from 202 to $247^{\circ}C$. Based on TGA data, they exhibited excellent thermal stabilities, showing 5% weight loss at $434-487^{\circ}C$. They had low thermal expansion coefficients of 58-59 ppm at temperature range of $50-200^{\circ}C$ as well as good mechanical properties with moduli of 1757-2143 MPa. The optical transmittance for the PAE films was over 70% at 550 nm, except for the PAE that contains naphthalene moiety (30% at 550 nm). They also showed water uptake of about 0.68% regardless of their chemical compositions. Therefore, the newly developed PAEs show strong potential as plastic substrates for flexible devices for display, solar cell and e-paper.

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