Bulletin of the Korean Chemical Society

  • 제32권7호
  • /
  • Pages.2351-2357
  • /
  • 2011
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Influence of Preparation Conditions on the Formation of Copper (II) Architectures with Pyrazine-2,3,5-tricarboxylic Acid

  • Wang, Feng-Qin (College of Environment and Chemical Engineering & Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University) ;
  • Lin, Shu (College of Environment and Chemical Engineering & Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University) ;
  • Guo, Ming-Lin (College of Environment and Chemical Engineering & Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University) ;
  • Xu, Jun-Jian (College of Environment and Chemical Engineering & Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University) ;
  • Wang, Xiao-Qing (College of Environment and Chemical Engineering & Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University) ;
  • Zhao, Yong-Nan (College of Materials and Engineering & Key Lab of Hollow Fiber Membrane Materials & Membrane Process, Tianjin Polytechnic University)
  • 투고 : 2011.04.12
  • 심사 : 2011.05.29
  • 발행 : 2011.07.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Three new metal-organic copper(II) complexes, $[Cu(H_2PZTC)_2]_n{\cdot}2nH_2O$ (1), $[Cu(HPZTC){\cdot}2H_2O]_n{\cdot}2nH_2O$ (2), and $Cu_2[(PZHD)(OH)(H_2O)_2]_n$ (3) ($H_3PZTC$ = pyrazine-2,3,5-tricarboxylic acid, $PZHD^{3-}$ = 2-hydroxypyrazine-3,5-dicarboxylate), have been synthesized from $Cu(II)/H_3PZTC$ system under different synthetic conditions, and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermogravimetric analysis. In complexes 1 and 2, $H_3PZTC$ ligands loose one and two protons, which were transformed into $H_2PZTC^-$ anion and $HPZTC^{2-}$ dianion under different preparation condition, respectively. Furthermore, two ligands coordinate with Cu(II) cations in different modes, leading to the formation of the different chain structures. In complex 3, $H_3PZTC$ ligand was converted into a new ligand-PZHD by in situ decarboxylation and hydroxylation under a higher pH value than that for complexes 1 and 2. PZHD ligands link the Cu(II) cations to form a 2D layer structure. These results demonstrate that the preparation conditions, including pH value and reaction temperature etc, play an important role in the construction of complexes based on $H_3PZTC$ ligand.

키워드

참고문헌

  1. Dybtsev, D. N.; Nuzhdin, A. L.; Chun, H.; Bryliakov, K. P.; Talsi, E. P.; Fedin, V. P.; Kim, K. Angew. Chem., Int. Ed. 2006, 45, 916 https://doi.org/10.1002/anie.200503023
  2. Gao, C. Y.; Liu, S. X.; Xie, L. H.; Sun, C. Y.; Cao, J. F.; Ren, Y. H.; Feng, D.; Su, Z. M. CrystEngComm. 2009, 11, 177. https://doi.org/10.1039/b812097h
  3. Liu, C. M.; Zuo, J. L.; Zhang, D. Q.; Zhu, D. B. CrystEngComm. 2008, 10, 1674. https://doi.org/10.1039/b811524a
  4. Li, C. J.; Peng, M. X.; Leng, J. D.; Yang, M. M.; Lin, Z. J.; Tong, M. L. CrystEngComm. 2008, 10, 1645. https://doi.org/10.1039/b811883n
  5. Chen, B. L.; Wang, L. B.; Zapata, F.; Qian, G. D.; Lobkovsky, E. B. J. Am. Chem. Soc. 2008, 130, 6718. https://doi.org/10.1021/ja802035e
  6. Xue, M.; Liu, Y.; Schaffino, R. M.; Xiang, S. C.; Zhao, X. J.; Zhu, G. S.; Qiu, S. L.; Chen, B. L. Inorg. Chem. 2009, 48, 4649. https://doi.org/10.1021/ic900486r
  7. Li, Y. W.; Yang, R. T. Langmuir 2007, 23, 12937. https://doi.org/10.1021/la702466d
  8. Bauer, C. A.; Timofeeva, T. V.; Settersten, T. B.; Patterson, B. D.; Liu, V. H.; Simmons, B. A.; Allendorf, M. D. J. Am. Chem. Soc. 2007, 129, 7136. https://doi.org/10.1021/ja0700395
  9. Kupplera, R. J.; Timmons, D. J.; Fang, Q. R.; Li, J. R.; Makal, T. A.; Young, M. D.; Yuan, D. Q.; Zhao, D.; Zhuang, W. J.; Zhou, H. C. Coord. Chem. Rev. 2009, 253, 3042. https://doi.org/10.1016/j.ccr.2009.05.019
  10. Ferey, G. Chem. Soc. Rev. 2008, 37, 191. https://doi.org/10.1039/b618320b
  11. Binnemans, K. Chem. Rev. 2009, 109, 4283. https://doi.org/10.1021/cr8003983
  12. Lan, A. J.; Li, K. H.; Wu, H. H.; Olson, D. H.; Emge, T. J.; Ki, W.; Hong, M. C.; Li, J. Angew. Chem. Int. Ed. 2009, 48, 2334. https://doi.org/10.1002/anie.200804853
  13. Chen, J. X.; Ohba, M.; Zhao, D. Y.; Kaneko, W.; Kitagawa, S. Cryst. Growth & Des. 2006, 6, 664. https://doi.org/10.1021/cg050363g
  14. Wang, H.; Wang, Y. Y.; Yang, G. P.; Wang, C. J.; Wen, G. L.; Shi, Q. Z.; Batten, S. R. CrystEngComm. 2008, 10, 1583. https://doi.org/10.1039/b805727c
  15. Zhang, J. P.; Lin, Y. Y.; Zhang, W. X.; Chen, X. M. J. Am. Chem.Soc. 2005, 127, 14162. https://doi.org/10.1021/ja054913a
  16. Pan, L.; Frydel, T.; Sander, M. B.; Huang, X. Y.; Li, J. Inorg. Chem. 2001, 40, 1271. https://doi.org/10.1021/ic001012o
  17. Go, Y. B.; Wang, X. X.; Anokhina, E. V.; Jacobson, A. J. Inorg. Chem. 2005, 44, 8265. https://doi.org/10.1021/ic050644d
  18. Yu, Q.; Zhang, X. Q.; Bian, H. D.; Liang, H.; Zhao, B.; Yan, S. P.; Liao, D. Z. Cryst. Growth & Des. 2008, 8, 1140. https://doi.org/10.1021/cg070022y
  19. Dai, J. C.; Wu, X. T.; Fu, Z. Y.; Cui, C. P.; Hu, S. M.; Du, W. X.; Wu, L. M.; Zhang, H. H.; Sun, R. O. Inorg. Chem. 2002, 41, 1391. https://doi.org/10.1021/ic010794y
  20. Pan, Z. R.; Zheng, H. G.; Wang, T. W.; Song, Y.; Li, Y. Z.; Guo, Z. J.; Batten, S. R. Inorg. Chem. 2008, 47, 9528. https://doi.org/10.1021/ic801221r
  21. Wang, F. Q.; Mu, W. H.; Zheng, X. J.; Li, L. C.; Fang, D. C.; Jin, L. P. Inorg. Chem. 2008, 47, 5225. https://doi.org/10.1021/ic8001916
  22. Wan, Y. H.; Zheng, X. J.; Wang, F. Q.; Zhou, X. Y.; Wang, K. Z.; Jin, L. P. CrystEngComm. 2009, 11, 278. https://doi.org/10.1039/b810964h
  23. Mager, H. I. X.; Berends, W. Recl. Trav. Chim. Pays-Bas 1958, 77, 827.
  24. Weygand, F. Chem. Ber. 1940, 73, 1259. https://doi.org/10.1002/cber.19400731118
  25. Weygand, F.; Bergmann, C. Chem. Ber. 1947, 80, 255. https://doi.org/10.1002/cber.19470800313
  26. Sheldrick, G. M. SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Gottingen: Gottingen, Germany, 1997.
  27. Sheldrick, G. M. SHELXS 97, Program for Crystal Structure Solution, University of Gottingen, Gottingen, Germany, 1997.
  28. Sheldrick, G. M. SHELXL 97, Program for Crystal Structure Refinement, University of Gottingen, Gottingen, Germany, 1997.