Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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A Facile Synthesis of SAPO-34 Molecular Sieves with Microwave Irradiation in Wide Reaction Conditions

  • Jun, Jong-Won (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University) ;
  • Lee, Ji-Sun (Bio-refinerary Research Center, Korea Research Institute of Chemical Technology) ;
  • Seok, Hwi-Young (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University) ;
  • Chang, Jong-San (Bio-refinerary Research Center, Korea Research Institute of Chemical Technology) ;
  • Hwang, Jin-Soo (Bio-refinerary Research Center, Korea Research Institute of Chemical Technology) ;
  • Jhung, Sung-Hwa (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
  • Received : 2011.03.03
  • Accepted : 2011.04.30
  • Published : 2011.06.20
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Abstract

Various reaction conditions uding temperature, time and type and concentration of templates have been changed in order to facilely synthesize, especially with microwave (MW) heating, SAPO-34 molecular sieves. SAPO-34 molecular sieve can be synthesized rapidly with microwave irradiation from a gel containing tetraethylammonium hydroxide (TEAOH) as a template. However, other several templating molecules lead to SAPO-5 molecular sieve under microwave irradiation even though SAPO-34 is obtained by conventional electric synthesis from the same reactant gels. Moreover, SAPO-34 can be obtained more easily by increasing the TEAOH or silica concentration or by increasing the reaction temperature. SAPO-34 can be obtained within 5 min in a selected condition (high temperature of 210 $^{\circ}C$) with microwave heating, which may lead to a continuous production of the important material. SAPO-34 synthesized by microwave irradiation is homogeneous and small in size and shows acidity and a stable performance in the dehydration of methanol and 2-butanol to olefins, suggesting potential applications in acid catalysis.

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References

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