Bulletin of the Korean Chemical Society

  • 제32권6호
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  • Pages.1957-1964
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  • 2011
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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A Facile Synthesis of SAPO-34 Molecular Sieves with Microwave Irradiation in Wide Reaction Conditions

  • Jun, Jong-Won (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University) ;
  • Lee, Ji-Sun (Bio-refinerary Research Center, Korea Research Institute of Chemical Technology) ;
  • Seok, Hwi-Young (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University) ;
  • Chang, Jong-San (Bio-refinerary Research Center, Korea Research Institute of Chemical Technology) ;
  • Hwang, Jin-Soo (Bio-refinerary Research Center, Korea Research Institute of Chemical Technology) ;
  • Jhung, Sung-Hwa (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
  • 투고 : 2011.03.03
  • 심사 : 2011.04.30
  • 발행 : 2011.06.20
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초록

Various reaction conditions uding temperature, time and type and concentration of templates have been changed in order to facilely synthesize, especially with microwave (MW) heating, SAPO-34 molecular sieves. SAPO-34 molecular sieve can be synthesized rapidly with microwave irradiation from a gel containing tetraethylammonium hydroxide (TEAOH) as a template. However, other several templating molecules lead to SAPO-5 molecular sieve under microwave irradiation even though SAPO-34 is obtained by conventional electric synthesis from the same reactant gels. Moreover, SAPO-34 can be obtained more easily by increasing the TEAOH or silica concentration or by increasing the reaction temperature. SAPO-34 can be obtained within 5 min in a selected condition (high temperature of 210 $^{\circ}C$) with microwave heating, which may lead to a continuous production of the important material. SAPO-34 synthesized by microwave irradiation is homogeneous and small in size and shows acidity and a stable performance in the dehydration of methanol and 2-butanol to olefins, suggesting potential applications in acid catalysis.

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피인용 문헌

  1. Morphology control of SAPO-34 by microwave synthesis and their performance in the methanol to olefins reaction vol.111, pp.1, 2014, https://doi.org/10.1007/s11144-013-0639-1
  2. Microwave-assisted synthesis of plate-like SAPO-34 nanocrystals with increased catalyst lifetime in the methanol-to-olefin reaction vol.4, pp.12, 2014, https://doi.org/10.1039/C4CY00775A
  3. Methanol conversion to light olefins over surfactant-modified nanosized SAPO-34 vol.118, pp.2, 2016, https://doi.org/10.1007/s11144-016-1023-8
  4. Recent advances of the nano-hierarchical SAPO-34 in the methanol-to-olefin (MTO) reaction and other applications vol.7, pp.21, 2017, https://doi.org/10.1039/C7CY01466J
  5. Effect of the acid-base properties of metal phosphate molecular sieves on the catalytic performances in synthesis of propylene glycol methyl ether from methanol and propylene oxide vol.165, pp.None, 2013, https://doi.org/10.1016/j.micromeso.2012.07.051