Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Microwave-assisted Preparation, Structures, and Photoluminescent Properties of [Ln(NO3)2(H2O)3(L)2](NO3)(H2O) {Ln=Tb, Eu;L=2-(4-pyridylium)ethanesulfonate, (4-pyH)+-CH2CH2-SO3-}

  • Zheng, Zhen Nu (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus) ;
  • Lee, Soon-W. (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus)
  • Received : 2011.03.13
  • Accepted : 2011.04.05
  • Published : 2011.06.20
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Abstract

Two lanthanide complexes, $[Ln(NO_3)_2(H_2O)_3(L)_2](NO_3)(H_2O)$ {Ln = Eu (1), Tb (2); L = 2-(4-pyridylium)-ethanesulfonate, $(4-pyH)^+-CH_2CH_2-SO_3^-)$}, were prepared from lanthanide nitrate and 4-pyridineethanesulfonic acid in $H_2O$ under microwave-heating conditions. Complexes 1 and 2 are isostructural, and the lanthanide metal in both complexes is coordinated to nine oxygen atoms. The pyridyl nitrogen in the ligand is protonated to give a zwitter ion that possesses an $NH^+$ (pyridyl) positive end and an $SO_3^-$ negative end. All O-H and N-H hydrogen atoms participate in hydrogen bonds to generate a two-dimensional (complex 1) or a three-dimensional network (complex 2). Complex 1 exhibits an intense red emission, whereas complex 2 exhibits an intense green emission in the solid state at room temperature.

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