Bulletin of the Korean Chemical Society

  • 제32권6호
  • /
  • Pages.1859-1864
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  • 2011
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Microwave-assisted Preparation, Structures, and Photoluminescent Properties of [Ln(NO3)2(H2O)3(L)2](NO3)(H2O) {Ln=Tb, Eu;L=2-(4-pyridylium)ethanesulfonate, (4-pyH)+-CH2CH2-SO3-}

  • Zheng, Zhen Nu (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus) ;
  • Lee, Soon-W. (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus)
  • 투고 : 2011.03.13
  • 심사 : 2011.04.05
  • 발행 : 2011.06.20
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초록

Two lanthanide complexes, $[Ln(NO_3)_2(H_2O)_3(L)_2](NO_3)(H_2O)$ {Ln = Eu (1), Tb (2); L = 2-(4-pyridylium)-ethanesulfonate, $(4-pyH)^+-CH_2CH_2-SO_3^-)$}, were prepared from lanthanide nitrate and 4-pyridineethanesulfonic acid in $H_2O$ under microwave-heating conditions. Complexes 1 and 2 are isostructural, and the lanthanide metal in both complexes is coordinated to nine oxygen atoms. The pyridyl nitrogen in the ligand is protonated to give a zwitter ion that possesses an $NH^+$ (pyridyl) positive end and an $SO_3^-$ negative end. All O-H and N-H hydrogen atoms participate in hydrogen bonds to generate a two-dimensional (complex 1) or a three-dimensional network (complex 2). Complex 1 exhibits an intense red emission, whereas complex 2 exhibits an intense green emission in the solid state at room temperature.

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피인용 문헌

  1. Novel Lanthanide Coordination Polymers Prepared by Microwave Heating: [Ln(L)3(H2O)2](H2O)3 (Ln = Eu, Tb, Gd; L = trans-(3-py)-CH=CH-COO) vol.33, pp.6, 2011, https://doi.org/10.5012/bkcs.2012.33.6.2017
  2. A Manganese Coordination Polymer and a Palladium Molecular Compound of 3-Pyridinepropionic acid (HL): [MnL2(H2O)2]∞ and trans-[Pd(HL)2Cl vol.34, pp.10, 2011, https://doi.org/10.5012/bkcs.2013.34.10.2947